Results 151 to 160 of about 9,480 (297)

Tribochemical Surface Modification of Silicon

open access: yesChemistry – A European Journal, EarlyView.
Mechanical scribing activates silicon surfaces by generating reactive sites that spontaneously graft alcohol‐, thiol‐, and alkyne‐terminated molecules under ambient conditions. Within 10 s, high‐coverage, electroactive organic layers form without light, heat, or applied voltage, offering a rapid tribochemical route to functional silicon interfaces for ...
Abdulrahman O. Abdulrahman   +6 more
wiley   +1 more source

Redox‐Switchable Optical and Magnetic Properties in a Self‐Assembled Hexanuclear Ni(II) Double‐Decker Complex

open access: yesChemistry – A European Journal, EarlyView.
A triangular double‐decker Ni6 complex self‐assembles from Ni(II), TMEDA, and a triphenylene tris dioxolene non‐innocent ligand, with two face‐to‐face tris‐semiquinone decks held by a strong covalent C─C interaction. This rigid scaffold delivers four reversible ligand‐centered redox events: oxidation switches on an intense near‐infrared band and ...
Aristide Colin   +12 more
wiley   +1 more source

Molecular Modification Strategies for CO2 Electroreduction to C2+ Products: Classifications, Mechanisms, Advances, and Perspectives

open access: yesEcoEnergy, EarlyView.
This review comprehensively outlines molecular modification strategies for steering CO2 electroreduction toward C2+ products, including the classification of diverse molecular structures, elucidation of their roles in microenvironment regulation, dissection of C–C coupling pathway engineering, and forward‐looking perspectives on machine learning and ...
Lingling Peng, Hanwen Liu, Tianyou Peng
wiley   +1 more source

Bioaccessibility of Organochlorine Pesticides in Contaminated Soil: A Poultry-Informed In Vitro Gastrointestinal Model. [PDF]

open access: yesBiology (Basel)
Akhatzhanova A   +6 more
europepmc   +1 more source

Multidimensional Engineering Enabling Rate‐Matched C−N Coupling for Efficient Organonitrogen Electrosynthesis

open access: yesEcoEnergy, EarlyView.
This review introduces rate matching as a unifying design principle for efficient electrochemical C−N coupling and highlights multidimensional engineering of catalysts, interfaces, and reactors to synchronize the generation of carbon‐ and nitrogen‐containing intermediates, balance their surface coverages, maximize C−N bond formation, and enable ...
Kaixing Cai   +4 more
wiley   +1 more source

Dynamic Reconstruction of Atomically Dispersed Copper Catalysts for CO2 Reduction: From In Situ Observations to Rational Design

open access: yesEcoEnergy, EarlyView.
Dynamic reconstruction transforms atomically dispersed Cu catalysts into authentic working‐state active phases during CO2 electroreduction. By integrating operando characterization, multiscale simulations, and AI‐assisted predictive modeling, this review establishes a framework for understanding, predicting, and rationally engineering catalyst ...
Jin Liu, Yue‐Wen Fang
wiley   +1 more source

Gradient p‐p Orbital Hybridization in Bismuth‐Doped Crystalline Carbon Nitride for Dual‐Functional Carbon‐to‐Carbon Valorization

open access: yesEcoEnergy, EarlyView.
Schematic illustration comparing the charge transfer dynamics and catalytic reaction over the (left) pristine carbon nitride and (right) Bi‐doped carbon nitride photocatalysts. In the pristine system, random charge diffusion and rapid recombination limit catalytic efficiency. In contrast, the Bi‐doped system establishes a robust internal electric field
Joel Jie Foo   +5 more
wiley   +1 more source

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