Results 141 to 150 of about 57,464 (334)

Hidden Diradical: Conformational Switch for Solvatochromic NIR Emission With Unity Quantum Yield in Thiele's Hydrocarbon

open access: yesAngewandte Chemie, EarlyView.
Halogen substitution controls a conformational switch between a folded closed‐shell and a flat singlet‐diradical conformer in an air‐stable Thiele‐diradical. This conformational switch allows for near‐unity photoluminescence quantum yield with a large Stokes shift, solvatochromism, and a long‐lived excited state.
Matteo Bevilacqua   +11 more
wiley   +2 more sources

New Boron(III) Blue Emitters for All‐Solution Processed OLEDs: Molecular Design Assisted by Theoretical Modeling

open access: green, 2019
Cristian A. M. Salla   +9 more
openalex   +2 more sources

Precise Tailoring of Charge Transport Characteristics in Zr and Hf Doped Indium Tin Oxide Thin Film Transistors

open access: yesAdvanced Electronic Materials, EarlyView.
Zirconium, hafnium, and mixed zirconium/hafnium doped indium tin oxide thin films are accessible by atomic layer deposition. The amorphous functional films are about 8 nm thick and show a high interdiffusion of all elements. Their transistor characteristics can be modulated depending on the amount of Zr and Hf oxide phases incorporated in these thin ...
Marie Isabelle Büschges   +5 more
wiley   +1 more source

Tellurophene‐Induced Triplet–Singlet Spin‐Flip Acceleration: An Advanced Design for Narrowband Organoboron Emitters with Fast Reverse Intersystem Crossing

open access: yesAngewandte Chemie, EarlyView.
Linking an auxiliary dibenzo[b,d]tellurophene unit markedly accelerates exciton spin conversion in multi‐resonance‐type thermally activated delayed fluorescence emitters. Owing to the heavy‐atom effect of tellurium, the corresponding OLEDs retain remarkably high external electroluminescence quantum efficiencies exceeding 25% even at an exceptionally ...
Peiyuan Yang   +3 more
wiley   +2 more sources

Beyond Silicon: Toward Sustainable, NIR‐II, and Conformable Organic Photodiodes

open access: yesAdvanced Energy Materials, EarlyView.
In this perspective, a strategic shift in organic photodetector (OPD) research is proposed: instead of the incremental advances in silicon's stronghold arena, the most impactful future for OPDs lies in addressing silicon's intrinsic limitations, i.e., detection in the longer wavelength range above silicon's coverage (>1100 nm, termed as near infrared ...
Hrisheekesh Thachoth Chandran   +7 more
wiley   +1 more source

Host‐Guest Doping Enables Room Temperature Phosphorescence from Triarylboranes

open access: yesAngewandte Chemie, EarlyView.
While pure triarylboranes show RTP in annealed PMMA films, they do not in crystalline form, contrary to our previous report. However, crystalline host‐guest triarylborane systems show persistent afterglow up to 8 s even at 1 ppb guest loading. Computations identify triplet‐triplet energy transfer as the mechanism governing this efficient RTP.
Zhu Wu   +4 more
wiley   +2 more sources

Substrate‐Selective Temperature‐Controlled Synthesis of Thiophene Derivatives at Interfaces

open access: yesAngewandte Chemie, EarlyView.
The deposition of a dithiophene derivative on Ag(111) at room temperature followed by annealing gives rise to molecular wires, whereas the adsorption of the same precursor on a hot substrate affords the formation of benzotrithiophene species. Abstract The temperature‐controlled transformation of organic molecules at interfaces is an incipient yet ...
Elena Pérez‐Elvira   +16 more
wiley   +2 more sources

Symmetric “Double Spiro” Wide Energy Gap Hosts for Blue Phosphorescent OLED Devices

open access: green, 2021
Jie Ma   +8 more
openalex   +2 more sources

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