Results 11 to 20 of about 4,393 (185)

A Review on Olefin Metathesis Reactions as a Green Method for the Synthesis of Organic Compounds

open access: yesJournal of Chemistry, 2021
Olefin metathesis is a metal-mediated C-C bond exchange by which the two fragments within the olefin precursor are redistributed as a result of breaking the double bond to obtain a new product. Currently, most of the synthetic organic compounds, polymers,
Atitegeb Abera Tsedalu
doaj   +1 more source

Research progress in preparation technology of hydroxyl-terminated butadiene liquid rubber

open access: yesHecheng xiangjiao gongye, 2023
The performance characteristics and application fields of hydroxy-terminated polybuta-diene (HTPB) liquid rubber were summarized, the preparation methods and characteristics of HTPB were reviewed with 32 references, and various me-thods were summarized ...
LIU Sheng-nan1,2, AI Chun-jin1,2, ZHANG Ding-jun1,2, LI Dong1,2
doaj   +1 more source

"Progress in preparation of end-group functionalized liquid rubber

open access: yesHecheng xiangjiao gongye, 2022
The preparation of end-group functionalized liquid rubber by olefin metathesis method had the advantages of controllable molecular weight, easy introduction of multiple functional groups and milder reaction conditions.
ZHANG Yi-kai, LI Wei-tian, ZHANG Hua-qiang, RAN Fen, GONG Guang-bi
doaj   +1 more source

Ruthenium Olefin Metathesis Catalysts Featuring N-Heterocyclic Carbene Ligands Tagged with Isonicotinic and 4-(Dimethylamino)benzoic Acid Rests: Evaluation of a Modular Synthetic Strategy

open access: yesMolecules, 2021
A modular and flexible strategy towards the synthesis of N-heterocyclic carbene (NHC) ligands bearing Brønsted base tags has been proposed and then adopted in the preparation of two tagged NHC ligands bearing rests of isonicotinic and 4-(dimethylamino ...
Stefan Czarnocki   +4 more
doaj   +1 more source

Heterogeneous catalysts for olefin metathesis

open access: yesCatalysis Communications, 2023
Over the past 30 years, many strategies have been developed to immobilize well-defined metathesis catalysts on solid supports. The use of heterogeneous catalysis resulted in increased purity of the product and the possibility of recycling the catalyst ...
Natalia Barteczko   +2 more
doaj   +1 more source

Latent olefin metathesis catalysts [PDF]

open access: yesChemical Society Reviews, 2009
Olefin metathesis is a versatile synthetic tool for the redistribution of alkylidene fragments at carbon-carbon double bonds. This field, and more specifically the development of task-specific, latent catalysts, attracts emerging industrial and academic interest.
Monsaert, Stijn   +4 more
openaire   +3 more sources

A study on selective transformation of norbornadiene into fluorinated cyclopentane-fused isoxazolines

open access: yesBeilstein Journal of Organic Chemistry, 2021
This work presents an examination of the selective functionalization of norbornadiene through nitrile oxide 1,3-dipolar cycloaddition/ring-opening metathesis (ROM)/cross-metathesis (CM) protocols. Functionalization of commercially available norbornadiene
Zsanett Benke   +2 more
doaj   +1 more source

The allylic chalcogen effect in olefin metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2010
Olefin metathesis has emerged as a powerful tool in organic synthesis. The activating effect of an allylic hydroxy group in metathesis has been known for more than 10 years, and many organic chemists have taken advantage of this positive influence for ...
Yuya A. Lin, Benjamin G. Davis
doaj   +1 more source

Highly efficient conversion of plant oil to bio-aviation fuel and valuable chemicals by combination of enzymatic transesterification, olefin cross-metathesis, and hydrotreating

open access: yesBiotechnology for Biofuels, 2018
Background The production of fuels and chemicals from renewable resources is increasingly important due to the environmental concern and depletion of fossil fuel. Despite the fast technical development in the production of aviation fuels, there are still
Meng Wang   +3 more
doaj   +1 more source

NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis

open access: yesMolecules, 2016
The catalytic properties of olefin metathesis ruthenium complexes bearing N-heterocyclic carbene ligands with stereogenic centers on the backbone are described. Differences in catalytic behavior depending on the backbone configurations of symmetrical and
Veronica Paradiso   +2 more
doaj   +1 more source

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