Results 31 to 40 of about 61,363 (222)

Olefin metathesis catalysts embedded in β-barrel proteins: creating artificial metalloproteins for olefin metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2018
This review summarizes the recent progress of Grubbs–Hoveyda (GH) type olefin metathesis catalysts incorporated into the robust fold of β-barrel proteins.
Daniel F. Sauer   +4 more
doaj   +1 more source

NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis

open access: yesMolecules, 2016
The catalytic properties of olefin metathesis ruthenium complexes bearing N-heterocyclic carbene ligands with stereogenic centers on the backbone are described. Differences in catalytic behavior depending on the backbone configurations of symmetrical and
Veronica Paradiso   +2 more
doaj   +1 more source

Olefin metathesis in nano-sized systems

open access: yesBeilstein Journal of Organic Chemistry, 2011
The interplay between olefin metathesis and dendrimers and other nano systems is addressed in this mini review mostly based on the authors’ own contributions over the last decade.
Didier Astruc   +7 more
doaj   +1 more source

OBSERVAÇÃO DE HOMODÍMERO DO TIPO BIS-1,3-BENZODIOXONA SINTETIZADO VIA METÁTESE DE OLEFINAS DA PIPERINA CATALISADA POR PRÉ-CATALISADORES DE RU(II) NÃO COMERCIAIS

open access: yesQuímica Nova, 2022
LN-1 and LN-2 are two Ru(II) complexes coordinated to the phosphine and amines simultaneously, each with two chlorides. PPh3 is the phosphine and the amine is piperidine (LN-1) and perhydroazepine (LN-2).
Kerlane A. Fernandes   +6 more
doaj   +1 more source

‐Enantioselective Olefin Metathesis

open access: yes, 2023
International audienceAsymmetric Olefin Metathesis (AOM) represents a highly versatile synthetic tool to lead relevant chiral building blocks with excellent enantiopurity.
Jakub Talcik   +14 more
core   +1 more source

Diazene-Catalyzed Oxidative Alkyl Halide-Olefin Metathesis [PDF]

open access: yes, 2023
The first platform for oxidative alkyl halide-olefin metathesis is described. The procedure employs diazenes as catalysts, which effect cyclization of alkenyl alkyl halides to generate cyclic olefins. Mechanistically, the diazene catalyst is converted to
Tristan, Lambert   +2 more
core   +2 more sources

Site‐Specific Protein Bioconjugation Through Cellular Incorporation of Noncanonical Amino Acids

open access: yesAngewandte Chemie, EarlyView.
Genetic code expansion (GCE) enables site‐specific installation of noncanonical amino acids containing bioorthogonal conjugation handles, allowing precise, homogeneous protein modification. This review examines the principles of orthogonal translation, surveys the chemistries available for chemoselective labeling, and highlights emerging multi‐site ...
Rahul Sarkar   +2 more
wiley   +2 more sources

Synthesis of Tetrasubstituted Alkenes via Metathesis

open access: yesMolecules, 2012
Fully substituted olefin generation via metathesis is presented. Catalyst development, optimization of reaction conditions and substrate screening are included.
Seung-Mann Paek
doaj   +1 more source

Construction of ion bonds in gel-free polydiene-based ionomers without compromising molecular weight

open access: yesPolymer Testing, 2022
Rubber-based ionomers have attracted extensive research interest from academy and industry attributing to their distinct physical mechanical properties.
Song Yue   +3 more
doaj   +1 more source

Ruthenium-based Grubbs-type catalysts and their applications in modern organic synthesis [PDF]

open access: yesRSC Advances
Grubbs catalysts, a class of Ru-based complexes, have revolutionized modern organic synthesis by enabling efficient and selective carbon–carbon bond-forming reactions, particularly olefin metathesis. Since their introduction, these catalysts have evolved
Shivani Soni   +3 more
doaj   +1 more source

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