Olefin metathesis in nano-sized systems
Beilstein Journal of Organic Chemistry, 2011 The interplay between olefin metathesis and dendrimers and other nano systems is addressed in this mini review mostly based on the authors’ own contributions over the last decade.
Didier Astruc +7 more
doaj +1 more source
Construction of ion bonds in gel-free polydiene-based ionomers without compromising molecular weight
Polymer Testing, 2022 Rubber-based ionomers have attracted extensive research interest from academy and industry attributing to their distinct physical mechanical properties.
Song Yue +3 more
doaj +1 more source
Synthesis of Telechelic Polyisoprene via Ring-Opening Metathesis Polymerization in the Presence of Chain Transfer Agent [PDF]
, 2010 Telechelic polyisoprene was synthesized via the ring-opening metathesis polymerization (ROMP) of 1,5-dimethyl-1,5-cyclooctadiene (DMCOD) in the presence of cis-1,4-diacetoxy-2-butene as a chain transfer agent (CTA).
Grubbs, Robert H., Thomas, Renee M.
core +2 more sources
Relevance of cis- and trans-dichloride Ru intermediates in Grubbs-II olefin metathesis catalysis (H(2)IMesCl(2)Ru=CHR) [PDF]
, 2008 Using density functional theory with the B3LYP and M06 functionals, we show conclusively that the (H2IMes)(Cl)2Ru olefin metathesis mechanism is bottom-bound with the chlorides remaining trans throughout the reaction, thus attempts to effect diastereo ...
Benitez, Diego +2 more
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Synthesis of Tetrasubstituted Alkenes via Metathesis
Molecules, 2012 Fully substituted olefin generation via metathesis is presented. Catalyst development, optimization of reaction conditions and substrate screening are included.
Seung-Mann Paek
doaj +1 more source
Monotelechelic Poly(oxa)norbornenes by Ring-Opening Metathesis Polymerization Using Direct End-Capping and Cross-Metathesis [PDF]
, 2010 Two different methodologies for the synthesis of monotelechelic poly(oxa)norbornenes prepared by living ring-opening metathesis polymerization (ROMP) are presented.
Grubbs, Robert H., Matson, John B.
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DFT Investigation into the Role of Conventional and Ionic Liquids as Solvents in Olefin Metathesis
International Journal of Electrochemical Science, 2013 The effects of conventional and ionic liquids on the metathesis of olefin have been investigated by means of quantum chemical calculations to establish the factors favouring the metathesis of olefin in ionic liquid. The results suggest that ionic liquids
Priya A. Thomas +2 more
doaj +1 more source
Conformations of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis [PDF]
, 2009 The structure of ruthenium-based olefin metathesis catalyst 3 and model π-complex 5 in solution and in the solid state are reported. The N-tolyl ligands, due to their lower symmetry than the traditional N-mesityl substituents, complicate this analysis ...
Benitez, Diego +6 more
core +3 more sources
Probing the Electronic Structure of Spectator Oxo Ligands by 17O NMR Spectroscopy
CHIMIA, 2020 Spectator oxo ligands are ubiquitous in catalysis, in particular in olefin epoxidation and olefin metathesis. Here we use computationally derived 17O NMR parameters to probe the electronic structure of spectator oxo ligands in these two reactions.
Christopher P. Gordon +1 more
doaj +1 more source
Tandem ring-closing metathesis reaction with a ruthenium catalyst containing a N-heterocyclic ligand [PDF]
, 2001 The highly active catalyst 2 was used in tandem RCM to make molecules with various ring systems containing α,β-unsaturated carbonyl ...
Choi, Tae-Lim, Grubbs, Robert H.
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