Results 11 to 20 of about 10,092 (232)

Halide exchanged Hoveyda-type complexes in olefin metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2010
The aims of this contribution are to present a straightforward synthesis of 2nd generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic ...
Julia Wappel   +6 more
doaj   +2 more sources

Olefin metathesis catalysts embedded in β-barrel proteins: creating artificial metalloproteins for olefin metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2018
This review summarizes the recent progress of Grubbs–Hoveyda (GH) type olefin metathesis catalysts incorporated into the robust fold of β-barrel proteins.
Daniel F. Sauer   +4 more
doaj   +2 more sources

The allylic chalcogen effect in olefin metathesis

open access: yesBeilstein Journal of Organic Chemistry, 2010
Olefin metathesis has emerged as a powerful tool in organic synthesis. The activating effect of an allylic hydroxy group in metathesis has been known for more than 10 years, and many organic chemists have taken advantage of this positive influence for ...
Yuya A. Lin, Benjamin G. Davis
doaj   +2 more sources

Latent olefin metathesis catalysts [PDF]

open access: yesChemical Society Reviews, 2009
Olefin metathesis is a versatile synthetic tool for the redistribution of alkylidene fragments at carbon-carbon double bonds. This field, and more specifically the development of task-specific, latent catalysts, attracts emerging industrial and academic interest.
Monsaert, Stijn   +4 more
openaire   +4 more sources

Photolithographic Olefin Metathesis Polymerization [PDF]

open access: yesJournal of the American Chemical Society, 2013
Patterning functional materials is a central challenge across many fields of science. The ability to lithographically fabricate micro- and nanostructures has been one of the most impactful technological breakthroughs of the last century. In part due to the complexity of the chemical processes in photoresists, there is a limited variety of materials ...
Weitekamp, Raymond A.   +2 more
openaire   +4 more sources

Olefin-Surface Interactions: A Key Activity Parameter in Silica-Supported Olefin Metathesis Catalysts. [PDF]

open access: yesJACS Au, 2022
Molecularly defined and classical heterogenous Mo-based metathesis catalysts are shown to display dis-tinct and unexpected reactivity patterns for the metathesis of long-chain α-olefins at low temperatures (< 100 °C). Namely, catalysts based on supported
Berkson ZJ   +7 more
europepmc   +3 more sources

A Review on Olefin Metathesis Reactions as a Green Method for the Synthesis of Organic Compounds

open access: yesJournal of Chemistry, 2021
Olefin metathesis is a metal-mediated C-C bond exchange by which the two fragments within the olefin precursor are redistributed as a result of breaking the double bond to obtain a new product. Currently, most of the synthetic organic compounds, polymers,
Atitegeb Abera Tsedalu
doaj   +1 more source

Research progress in preparation technology of hydroxyl-terminated butadiene liquid rubber

open access: yesHecheng xiangjiao gongye, 2023
The performance characteristics and application fields of hydroxy-terminated polybuta-diene (HTPB) liquid rubber were summarized, the preparation methods and characteristics of HTPB were reviewed with 32 references, and various me-thods were summarized ...
LIU Sheng-nan1,2, AI Chun-jin1,2, ZHANG Ding-jun1,2, LI Dong1,2
doaj   +1 more source

"Progress in preparation of end-group functionalized liquid rubber

open access: yesHecheng xiangjiao gongye, 2022
The preparation of end-group functionalized liquid rubber by olefin metathesis method had the advantages of controllable molecular weight, easy introduction of multiple functional groups and milder reaction conditions.
ZHANG Yi-kai, LI Wei-tian, ZHANG Hua-qiang, RAN Fen, GONG Guang-bi
doaj   +1 more source

Ruthenium Olefin Metathesis Catalysts Featuring N-Heterocyclic Carbene Ligands Tagged with Isonicotinic and 4-(Dimethylamino)benzoic Acid Rests: Evaluation of a Modular Synthetic Strategy

open access: yesMolecules, 2021
A modular and flexible strategy towards the synthesis of N-heterocyclic carbene (NHC) ligands bearing Brønsted base tags has been proposed and then adopted in the preparation of two tagged NHC ligands bearing rests of isonicotinic and 4-(dimethylamino ...
Stefan Czarnocki   +4 more
doaj   +1 more source

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