Results 11 to 20 of about 10,092 (232)
Halide exchanged Hoveyda-type complexes in olefin metathesis
The aims of this contribution are to present a straightforward synthesis of 2nd generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic ...
Julia Wappel +6 more
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This review summarizes the recent progress of Grubbs–Hoveyda (GH) type olefin metathesis catalysts incorporated into the robust fold of β-barrel proteins.
Daniel F. Sauer +4 more
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The allylic chalcogen effect in olefin metathesis
Olefin metathesis has emerged as a powerful tool in organic synthesis. The activating effect of an allylic hydroxy group in metathesis has been known for more than 10 years, and many organic chemists have taken advantage of this positive influence for ...
Yuya A. Lin, Benjamin G. Davis
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Latent olefin metathesis catalysts [PDF]
Olefin metathesis is a versatile synthetic tool for the redistribution of alkylidene fragments at carbon-carbon double bonds. This field, and more specifically the development of task-specific, latent catalysts, attracts emerging industrial and academic interest.
Monsaert, Stijn +4 more
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Photolithographic Olefin Metathesis Polymerization [PDF]
Patterning functional materials is a central challenge across many fields of science. The ability to lithographically fabricate micro- and nanostructures has been one of the most impactful technological breakthroughs of the last century. In part due to the complexity of the chemical processes in photoresists, there is a limited variety of materials ...
Weitekamp, Raymond A. +2 more
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Olefin-Surface Interactions: A Key Activity Parameter in Silica-Supported Olefin Metathesis Catalysts. [PDF]
Molecularly defined and classical heterogenous Mo-based metathesis catalysts are shown to display dis-tinct and unexpected reactivity patterns for the metathesis of long-chain α-olefins at low temperatures (< 100 °C). Namely, catalysts based on supported
Berkson ZJ +7 more
europepmc +3 more sources
A Review on Olefin Metathesis Reactions as a Green Method for the Synthesis of Organic Compounds
Olefin metathesis is a metal-mediated C-C bond exchange by which the two fragments within the olefin precursor are redistributed as a result of breaking the double bond to obtain a new product. Currently, most of the synthetic organic compounds, polymers,
Atitegeb Abera Tsedalu
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Research progress in preparation technology of hydroxyl-terminated butadiene liquid rubber
The performance characteristics and application fields of hydroxy-terminated polybuta-diene (HTPB) liquid rubber were summarized, the preparation methods and characteristics of HTPB were reviewed with 32 references, and various me-thods were summarized ...
LIU Sheng-nan1,2, AI Chun-jin1,2, ZHANG Ding-jun1,2, LI Dong1,2
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"Progress in preparation of end-group functionalized liquid rubber
The preparation of end-group functionalized liquid rubber by olefin metathesis method had the advantages of controllable molecular weight, easy introduction of multiple functional groups and milder reaction conditions.
ZHANG Yi-kai, LI Wei-tian, ZHANG Hua-qiang, RAN Fen, GONG Guang-bi
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A modular and flexible strategy towards the synthesis of N-heterocyclic carbene (NHC) ligands bearing Brønsted base tags has been proposed and then adopted in the preparation of two tagged NHC ligands bearing rests of isonicotinic and 4-(dimethylamino ...
Stefan Czarnocki +4 more
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