Results 31 to 40 of about 4,393 (185)
DFT Investigation into the Role of Conventional and Ionic Liquids as Solvents in Olefin Metathesis
International Journal of Electrochemical Science, 2013 The effects of conventional and ionic liquids on the metathesis of olefin have been investigated by means of quantum chemical calculations to establish the factors favouring the metathesis of olefin in ionic liquid. The results suggest that ionic liquids
Priya A. Thomas +2 more
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Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands
Beilstein Journal of Organic Chemistry, 2018 An overview on the catalytic properties of ruthenium complexes for olefin metathesis bearing monodentate unsymmetrical N-heterocyclic diaminocarbene ligands is provided. The non-symmetric nature of these NHC architectures strongly influences activity and
Veronica Paradiso +2 more
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Halide exchanged Hoveyda-type complexes in olefin metathesis
Beilstein Journal of Organic Chemistry, 2010 The aims of this contribution are to present a straightforward synthesis of 2nd generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic ...
Julia Wappel +6 more
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International Journal of Technology, 2017 Oleic acid, one of the major components of palm oil, has attracted much interest in modern oleochemistry. The internal olefin group in oleic acid is a useful functional group in the transformation of a fatty acid to other functional chemicals and ...
Robby Roswanda +2 more
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Photolithographic Olefin Metathesis Polymerization
Journal of the American Chemical Society, 2013 Patterning functional materials is a central challenge across many fields of science. The ability to lithographically fabricate micro- and nanostructures has been one of the most impactful technological breakthroughs of the last century. In part due to the complexity of the chemical processes in photoresists, there is a limited variety of materials ...
Weitekamp, Raymond A. +2 more
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Beilstein Journal of Organic Chemistry, 2007 BackgroundTandem olefin metathesis sequences are known to be versatile for the generation of natural product scaffolds and have also been used for ring opening of strained carbo- and heterocycles.
Wolfgang Maison +2 more
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Aqueous olefin metathesis: recent developments and applications
Beilstein Journal of Organic Chemistry, 2019 Olefin metathesis is one of the most powerful C–C double-bond-forming reactions. Metathesis reactions have had a tremendous impact in organic synthesis, enabling a variety of applications in polymer chemistry, drug discovery and chemical biology ...
Valerio Sabatino, Thomas R. Ward
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Synthesis of Pentacycloundecane (PCUD) Based Spiro-Pyrano-Cage Framework via Ring-Closing Metathesis
Molbank, 2023 Here, we demonstrate a short synthetic route to pyrano cage systems containing pentacycloundecane units by employing ring-closing metathesis (RCM) as a key step.
Sambasivarao Kotha +2 more
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Beilstein Journal of Organic Chemistry, 2019 This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials.
Patrycja Żak, Cezary Pietraszuk
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The intriguing modeling of cis–trans selectivity in ruthenium-catalyzed olefin metathesis
Beilstein Journal of Organic Chemistry, 2011 In this study we have investigated computationally the origin of the cis–trans selectivity in the Ru-catalyzed cross metathesis (CM) of a prototype monosubstituted olefin, i.e., propene.
Naeimeh Bahri-Laleh +2 more
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