Synthesis of novel styrene-olefin triblock copolymer via living anionic polymerization [PDF]
Innovative strides in polymer synthesis have led to the successful living anionic polymerization of styrene-olefin triblock copolymers, yielding varying molecular weights and a remarkably narrow dispersity (Đ) in cyclohexane solvent at 45°C, initiated by
Mohammad Jozaghkar, Farshid Ziaee
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Mesoporous Carbon Thin Films with Large Mesopores as Model Material for Electrochemical Applications
Mesoporous carbon thin films possessing 70 nm mesopores are prepared on titanium substrates by soft templating of resol resins with a self‐synthesized poly(ethylene oxide)‐block‐poly(hexyl acrylate) block copolymer. A strategy to avoid corrosion of the metal substrate is presented, and the films are extensively characterized in terms of morphology ...
Lysander Q. Wagner +9 more
wiley +1 more source
Most pyridine-imine Ni(II) and Pd(II) catalysts tend to yield low-molecular-weight polyethylene and ethylene-based copolymers in olefin insertion polymerization, as the unilateral axial steric structure of such complexes often cannot provide effective ...
You Ge +7 more
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Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers [PDF]
Various macromonomers (MMs) were efficiently synthesized through the copper-catalyzed “click” coupling of a norbornene moiety to the chain end of poly(methylacrylate), poly(t-butylacrylate), and polystyrene that were prepared using atom transfer radical ...
Grubbs, Robert H. +2 more
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Well-defined silica-supported olefin metathesis catalysts [PDF]
Two triethoxysilyl-functionalized N-heterocyclic carbene ligands have been synthesized and used to prepare the corresponding second-generation ruthenium olefin metathesis catalysts.
Allen, Daryl P. +2 more
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Olefin polymerization catalysts
Polyolefins, which are products of polymerisation of unsaturated hydrocarbons of the olefin series, have a molecular weight in the range from several thousands to several millions. Depending on the type of monomer and method and mechanism of polymerisation the resulting polyolefins may differ in their structure and molecular weight. They can be used in
openaire +1 more source
Electron–Matter Interactions During Electron Beam Nanopatterning
This article reviews the electron–matter interactions important to nanopatterning with electron beam lithography (EBL). Electron–matter interactions, including secondary electron generation routes, polymer radiolysis, and electron beam induced charging, are discussed.
Camila Faccini de Lima +2 more
wiley +1 more source
DFT Modeling of Coordination Polymerization of Polar Olefin Monomers by Molecular Metal Complexes
Introducing polar functional groups into polyolefin chains through polar olefin monomer coordination (co)polymerization can directly and significantly improve the surface properties of polymer materials and expand their application range.
Yanan Zhao, Zhenli Zhang, Yi Luo
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Copolymerization of ethylene with α-olefins over highly active supported Ziegler-Natta catalyst with vanadium active component [PDF]
The new highly active supported vanadium-magnesium catalyst (VMC) has been studied in α-olefin (1-butene, 1-hexene)/ ethylene copolymerization in the presence of hydrogen.
Zenghui Zhao +6 more
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Vinylic Addition Polynorbornene in Catalysis [PDF]
Vinylic addition polynorbornenes (VA-PNB) result from the insertion polymerization of norbornene or specific norbornene derivatives catalyzed by transition metal com- plexes. The VA-PNB skeleton is completely aliphatic and keeps the bicyclic structure of
Albéniz Jiménez, Ana Carmen +1 more
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