Results 51 to 60 of about 17,166 (245)

Synthesis of novel styrene-olefin triblock copolymer via living anionic polymerization [PDF]

open access: yesPolyolefins Journal
Innovative strides in polymer synthesis have led to the successful living anionic polymerization of styrene-olefin triblock copolymers, yielding varying molecular weights and a remarkably narrow dispersity (Đ) in cyclohexane solvent at 45°C, initiated by
Mohammad Jozaghkar, Farshid Ziaee
doaj   +1 more source

Mesoporous Carbon Thin Films with Large Mesopores as Model Material for Electrochemical Applications

open access: yesAdvanced Functional Materials, EarlyView.
Mesoporous carbon thin films possessing 70 nm mesopores are prepared on titanium substrates by soft templating of resol resins with a self‐synthesized poly(ethylene oxide)‐block‐poly(hexyl acrylate) block copolymer. A strategy to avoid corrosion of the metal substrate is presented, and the films are extensively characterized in terms of morphology ...
Lysander Q. Wagner   +9 more
wiley   +1 more source

Synthesis of High-Molecular-Weight Branched Polyethylene Using a Hybrid “Sandwich” Pyridine-Imine Ni(II) Catalyst

open access: yesFrontiers in Chemistry, 2022
Most pyridine-imine Ni(II) and Pd(II) catalysts tend to yield low-molecular-weight polyethylene and ethylene-based copolymers in olefin insertion polymerization, as the unilateral axial steric structure of such complexes often cannot provide effective ...
You Ge   +7 more
doaj   +1 more source

Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers [PDF]

open access: yes, 2009
Various macromonomers (MMs) were efficiently synthesized through the copper-catalyzed “click” coupling of a norbornene moiety to the chain end of poly(methylacrylate), poly(t-butylacrylate), and polystyrene that were prepared using atom transfer radical ...
Grubbs, Robert H.   +2 more
core   +1 more source

Well-defined silica-supported olefin metathesis catalysts [PDF]

open access: yes, 2009
Two triethoxysilyl-functionalized N-heterocyclic carbene ligands have been synthesized and used to prepare the corresponding second-generation ruthenium olefin metathesis catalysts.
Allen, Daryl P.   +2 more
core   +1 more source

Olefin polymerization catalysts

open access: yesPolimery, 2002
Polyolefins, which are products of polymerisation of unsaturated hydrocarbons of the olefin series, have a molecular weight in the range from several thousands to several millions. Depending on the type of monomer and method and mechanism of polymerisation the resulting polyolefins may differ in their structure and molecular weight. They can be used in
openaire   +1 more source

Electron–Matter Interactions During Electron Beam Nanopatterning

open access: yesAdvanced Functional Materials, EarlyView.
This article reviews the electron–matter interactions important to nanopatterning with electron beam lithography (EBL). Electron–matter interactions, including secondary electron generation routes, polymer radiolysis, and electron beam induced charging, are discussed.
Camila Faccini de Lima   +2 more
wiley   +1 more source

DFT Modeling of Coordination Polymerization of Polar Olefin Monomers by Molecular Metal Complexes

open access: yesInorganics
Introducing polar functional groups into polyolefin chains through polar olefin monomer coordination (co)polymerization can directly and significantly improve the surface properties of polymer materials and expand their application range.
Yanan Zhao, Zhenli Zhang, Yi Luo
doaj   +1 more source

Copolymerization of ethylene with α-olefins over highly active supported Ziegler-Natta catalyst with vanadium active component [PDF]

open access: yesPolyolefins Journal, 2019
The new highly active supported vanadium-magnesium catalyst (VMC) has been studied in α-olefin (1-butene, 1-hexene)/ ethylene copolymerization in the presence of hydrogen.
Zenghui Zhao   +6 more
doaj   +1 more source

Vinylic Addition Polynorbornene in Catalysis [PDF]

open access: yes, 2019
Vinylic addition polynorbornenes (VA-PNB) result from the insertion polymerization of norbornene or specific norbornene derivatives catalyzed by transition metal com- plexes. The VA-PNB skeleton is completely aliphatic and keeps the bicyclic structure of
Albéniz Jiménez, Ana Carmen   +1 more
core   +2 more sources

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