Results 161 to 170 of about 201,093 (287)

Arene Incorporation and Ring Expansion in the Thermal Decomposition of a Divanadium(III) Complex With Four Bridging Methyl Groups

open access: yesChemistry – A European Journal, EarlyView.
Thermolysis of [{VCp*(µ‐CH3)2}2] (Cp* = η5‐C5Me5) in hexane leads to a tetranuclear cube‐type methylidene complex [{VCp*(µ3‐CH2)}4], while in benzenic solvents C6H5R produces the formal insertion of a CH fragment into the six‐membered aromatic ring of a solvent molecule to give trovacene derivatives with η7‐cycloheptatrienyl ligands [VCp*(η7‐C7H6R ...
Adrián Calvo‐Molina   +5 more
wiley   +1 more source

ZNRD2 Mediated Nucleoprotein Aggregation Impairs Respiratory Syncytial Virus Replication. [PDF]

open access: yesAdv Sci (Weinh)
Zhou H   +8 more
europepmc   +1 more source

Next Generation Hosts for Protein Recognition, Assembly and More

open access: yesChemistry – A European Journal, EarlyView.
The original design of synthetic receptors for proteins was based on macrocycles with a hydrophobic core and a polar/charged periphery. This design, geared towards protein recognition, facilitates receptor self‐assembly. Macrocycle oligomerization, in turn, contributes to protein assembly as evidenced in many cocrystal structures.
Peter B. Crowley
wiley   +1 more source

Self‐assembly and Lateral Cobalt Coordination of a Fivefold Symmetric Cyanostar Macrocycle on an Au(111) Surface

open access: yesChemistry – A European Journal, EarlyView.
Herein, we report the first example of the formation of a close‐packed, regular 2D monolayer of a fivefold symmetric cyanostar macrocycle on an Au(111) surface under ultra‐high vacuum and the structural modification of such self‐assembled architecture upon cobalt atom deposition.
Lenka Černá   +11 more
wiley   +1 more source

Bis(trifluoromethyl)disulfide and the EtP4 Phosphazene Base—Formation of a Bench‐Stable [EtP4SCF3]+[SCF3]− Salt

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of a bench‐stable trifluoromethylthiolate‐substituted phosphazenium salt is reported. Reaction of bis(trifluoromethyl)disulfide with the EtP4 phosphazene base furnishes this salt in quantitative yield. The compound features a unique trifluoromethylthiolate‐iminium motif and allows for functionalization of both trifluoromethylthiolate ...
Lukas Hartmann   +6 more
wiley   +1 more source

mSumireF a Monomeric Violet Fluorescent Protein. [PDF]

open access: yesACS Bio Med Chem Au
Kress J   +5 more
europepmc   +1 more source

Planar Chirality Controls Diastereotopicity in [2.2]Paracyclophanyl Cyclopropenes

open access: yesChemistry – A European Journal, EarlyView.
In this work, we report the synthesis of [2.2]paracyclophane‐substituted cyclopropenes via rhodium‐catalyzed cyclopropenation using a pCp‐derived carbene precursor. The planar chiral framework induces diastereotopic differentiation of otherwise equivalent alkyl substituents, which is reflected in their 1H NMR spectra.
Tilman Köhler   +3 more
wiley   +1 more source

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