Results 31 to 40 of about 1,262 (179)
The formation of triplet Ni(II) complexes by activation of bromoalkenes with alkyl‐ or boryl Ni(I) is key to control the outcome of the reductive cross‐coupling of bromoalkanes precluding the formation of alkylboronates. We present a mechanistic study on the Ni‐catalyzed cross‐coupling reaction of bromoalkanes with diboron compounds as reductants.
Diego J. Cárdenas
wiley +1 more source
Silyl Rearrangements in Gold‐Catalyzed Transformations
The synergy between the exceptional ability of gold catalysts to activate unsaturated substrates and the inherent tendency of organosilicon reagents to undergo silyl‐group rearrangements has unlocked a range of novel transformations, enabling access to otherwise challenging molecular architectures.
Patricia García‐Martínez +1 more
wiley +1 more source
La configuración del ethos poético de Orfeo en cuatro variantes del mito
El mito de Orfeo posee una potencia narrativa que generó que su relato se cuente una y otra vez y que lo convirtió en un hito importante para la cultura occidental desde la antigüedad hasta nuestros días.
Ileana Kleinman
doaj +1 more source
A bulky fluorinated bis(phosphonite) ligand enables a 24‐electron Pt0–Pt0 complex featuring the shortest unsupported PtPt bond reported. Energy Decomposition Analysis (EDA), Natural Orbitals for Chemical Valence (NOCV), Noncovalent Interaction analysis (NCI), and Atoms‐in‐Molecules theory (AIM) uncover how steric and electronic effects stabilize this ...
María M. Alcaide +3 more
wiley +1 more source
(Re)considering Robert Henryson’s Orpheus and Eurydice as a Dream Vision
This study aims to reconsider the Scottish poet Robert Henryson’s retelling of the myth of Orpheus in his Orpheus and Eurydice (c. 1470) as a late example of medieval dream vision genre. There are two prominent versions of the myth in the medieval world:
Seher Aktarer
doaj
En este trabajo ofrecemos un acercamiento al viaje que el Orfeó Català realizó a París, como parte de la excursión artística a París y Londres en junio de 1914.
Virginia Sánchez Rodríguez
doaj +1 more source
Electrochemical N‐hydroxyphthalimide Catalyzed Addition of α‐Alkoxy Radicals to Oxime Ethers
N‐hydroxyphthalimide (NHPI) serves as an electrocatalyst that enables selective hydrogen atom transfer from alkyl alcohols under mild electrochemical conditions. In contrast with the well‐known electrochemical oxidation to their corresponding aldehydes or ketones, α‐alkoxy radicals were successfully coupled with oximes promoting a carbon‐carbon bond ...
Rodrigo G. Enríquez +4 more
wiley +1 more source
Director de la publicación: García Gil, José ...
Antonio, Muñoz Molina +1 more
openaire +2 more sources
Cyclopropenes in Photochemical Reactions
The photochemical side of cyclopropenes. Cyclopropenes are valuable synthetic tools in organic chemistry. In particular, this review focuses on the photochemistry of cyclopropenes. The reactivity of cyclopropenes excited by irradiation is discussed showing their unique potential for organic synthesis.
David Suárez‐García +2 more
wiley +1 more source
Proper selection of a modified guanidinato ligand allows for the selective catalytic dehydroborylation of terminal alkynes by an air‐stable aluminum complex. A plausible reaction pathway is suggested based on DFT studies, where the auxiliary substituent of the guanidinato ligand actively participates in the activation of the σ CH bond.
Carlos Ginés +6 more
wiley +1 more source

