Results 51 to 60 of about 86,737 (136)
Prins fluorination cyclisations: Preparation of 4-fluoro-pyran and -piperidine heterocycles
The Prins reaction was investigated using BF3·OEt2 as a Lewis acid. It has been recently demonstrated, that if BF3·OEt2 is used in stoichiometric amounts then these reactions generate fluorinated products where the BF3·OEt2 contributes fluoride ion to ...
Guillaume G. Launay +2 more
doaj +1 more source
A Review on Green Synthetic Approaches in the Development of Quinoline Analogues
This review highlights recent advances in environmentally friendly approaches, including metal‐free systems, solvent‐free approaches, microwave, and ultrasonic‐assisted techniques, organo‐ and biocatalysis, ionic liquids, nanoparticle catalysis, electrochemical, and photocatalytic strategies for the synthesis of quinoline scaffolds.
Demis Zelelew +3 more
wiley +1 more source
Chemistry of some model compounds related to fluorinated polymers [PDF]
The work described in this thesis is concerned with three areas which are the generation of stable carbocations from saturated model compounds related to poly- vinylidenefluoride, the development of synthetic routes to fluoro-organo-phosphazenes with ...
Odello, Paolo
core
Borylation of Aryl Halides Induced by Visible Light Under Open‐To‐Air Environment
Borylation of aryl halides was successfully achieved by a sustainable protocol which involved a purely organic confined medium, visible light as energy source under an open‐to‐air environment. Experimental and computational investigations evidenced that the reaction occurred through the formation of a ground–state complex generated by hydrogen bonding.
Jorge C. Herrera‐Luna +5 more
wiley +1 more source
Organo-sulfur phosphorus chemistry
P-organo-substituted dithiadiphosphetane disulfides have been prepared by the reaction of ferrocene and arenes with P4S10. Reaction of these compounds and Lawesson's reagent with alkenes, 2,3-dimethylbutadiene and other compounds gave organo-sulfur ...
Mark R. StJ. Foreman (7167302)
core +3 more sources
Reaction of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithiethane with N-vinyl compounds
The reaction of hexafluorothioacetone dimer (2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithiethane, 1) with vinylamides leads to the rapid formation of [2 + 2] cycloadducts: 4-amino-2,2-bis(trifluoromethyl)thietanes.
Viacheslav A. Petrov, Will Marshall
doaj +1 more source
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
The synthesis of 5-nitro-1-(trifluoromethyl)-3H-1λ3,2-benziodaoxol-3-one (3), a hypervalent-iodine-based electrophilic trifluoromethylating reagent, is described.
Nico Santschi +4 more
doaj +1 more source
One-pot cross-enyne metathesis (CEYM)–Diels–Alder reaction of gem-difluoropropargylic alkynes
Propargylic difluorides 1 were used as starting substrates in a combination of cross-enyne metathesis and Diels–Alder reactions. Thus, the reaction of 1 with ethylene in the presence of 2nd generation Hoveyda–Grubbs catalyst generates a diene moiety ...
Santos Fustero +5 more
doaj +1 more source
Next Generation Organofluorine Containing Blockbuster Drugs [PDF]
The role of organo-fluorine compounds in modern health, food and energy related industries is widelyappreciated. The unique properties that fluorine imparts to organic molecules, stemming from its high electronegativity and stability when bound to ...
Hiroki Moriwaki +26 more
core +1 more source

