Estudos de reações de transesterificação com lipases imobilizadas e determinação de coeficiente de difusão de ésteres em organo-gel / [PDF]
, 1999 Tese (Doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.As lipases de Chromobacterium viscosum, Pseudomonas sp, Microbial e Lipolase, imobilizadas em organo-gel (MBG) de hexano foram usadas como ...
João, Jair Juarez
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Regioselective carbon–carbon bond formation of 5,5,5-trifluoro-1-phenylpent-3-en-1-yne
Beilstein Journal of Organic Chemistry, 2013 The regioselective carbon–carbon bond formation was studied using 5,5,5-trifluoro-1-phenylpent-3-en-1-yne as a model substrate, and predominant acceptance of electrophiles β to a CF3 group as well as a deuterium trap experiment of the lithiated species ...
Motoki Naka +2 more
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Three step synthesis of single diastereoisomers of the vicinal trifluoro motif
Beilstein Journal of Organic Chemistry, 2009 A three step route to single diastereoisomers of the vicinal trifluoromethyl motif is described. The route starts from either syn- or anti-α,β-epoxy alcohols and takes a direct approach in that each of the three steps introduces a fluorine atom in a ...
Vincent A. Brunet +2 more
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Electrochemical Properties of Nonflammable Organo-Fluorine Compounds for Lithium Ion Batteries [PDF]
, 2010 Electrochemical behavior of organo-fluorine compounds with high oxidation stability has been investigated. Oxidation currents of fluorine compound-containing EC/DEC solutions were much smaller than those of EC/DEC and EC/DEC/PC at the higher potentials ...
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Diastereoselectivity in the Staudinger reaction of pentafluorosulfanylaldimines and ketimines
Beilstein Journal of Organic Chemistry, 2013 β-Lactams were diastereoselectively formed by the reaction of SF5-containing aldimines, or an SF5-containing ketimine, with benzyloxyketene in a conrotatory ring closure process. Imine formation and cyclization were possible in spite of the acidification
Alexander Penger +3 more
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New methodology for the synthesis of fluorinated aromatics [PDF]
, 1990 This thesis is concerned with new methodology for the introduction of fluorine atoms, and trifluoromethyl groups into aromatic systems and the following approaches have been adopted: (i) The possibility of selective cleavage of the aryl-silicon bond of ...
Rock, Michael Harold
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Chemical diffusion of fluorine in jadeite melt at high pressure [PDF]
, 1984 The chemical diffusion of fluorine in jadeite melt has been investigated from 10 to 15 kbars and 1200 to 1400°C using diffusion couples of Jadeite melt and fluorine-bearing jadeite melt (6.3 wt.% F). The diffusion profile data indicate that the diffusion
Scarfe, Christopher M. +1 more
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Crystal design using multipolar electrostatic interactions: A concept study for organic electronics
Beilstein Journal of Organic Chemistry, 2013 Using a simple synthetic protocol, heterohexacene analogues with a quadrupolar distribution of partial charges are readily available. In contrast to most other acenes, these compounds crystallize with a slipped-stack, brickwork-like packing which is ...
Peer Kirsch +2 more
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Development of Novel Fluorine-18 Labeled PET Radioligands for Monoamine Oxidase B (MAO-B) [PDF]
, 2013 Monoamine oxidases (MAO-A and MAO-B) are important enzymes regulating the levels of monoaminergic neurotransmitters. Selective and irreversible MAO-B inhibitors such as L-deprenyl and rasagiline are clinically used for the treatment of psychiatric and ...
Nag, Sangram
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Chemistry of some model compounds related to fluorinated polymers [PDF]
, 1993 The work described in this thesis is concerned with three areas which are the generation of stable carbocations from saturated model compounds related to poly- vinylidenefluoride, the development of synthetic routes to fluoro-organo-phosphazenes with ...
Odello, Paolo
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