Results 51 to 60 of about 82,213 (177)

Photochemical and Thermal Activation of a Diarylbismuth Azide

open access: yesChemistry – A European Journal, EarlyView.
We report the synthesis and characterization of a novel diarylbismuth azide and its divergent reactivity upon thermal or photochemical activation. These findings contribute expanding the reactivity landscape of heavy pnictogen compounds and sets the basis for further investigations. ABSTRACT Azides are widely employed in synthesis as convenient nitrene
Giacomo Pugliese   +5 more
wiley   +1 more source

N‐Boron‐Functionalized Anionic N‐Heterocyclic Carbenes (NBA‐NHCs)—A Case Study

open access: yesChemistry – A European Journal, EarlyView.
The synthesis and characterization of a new family of N‐boron‐functionalized anionic N‐heterocyclic carbenes (NBA‐NHCs), IiPrB(CN)3−, IiPr(C2F5)BF2−, IMesB(CN)3−, and IMes(C2F5)BF2−, is reported. ABSTRACT The synthesis and characterization of a new family of N‐boron‐functionalized anionic NHCs (NBA‐NHCs), IiPrB(CN)3− (5), IiPr(C2F5)BF2− (6), IMesB(CN)3−
Sophie Mann   +3 more
wiley   +1 more source

Crystal structure landscape of conformationally flexible organo-fluorine compounds

open access: yesCrystEngComm, 2016
The crystal structure landscape of an unsubstituted benzanilide was generated and a number of hypothetical structures were accessed with experimentally obtained crystal structures of mono-, di-, tetra- and penta-fluorobenzanilides.
Pradip Kumar Mondal, Deepak Chopra
openaire   +2 more sources

The influence of the C-N⁺ ----- F-C charge dipole interaction in fluoro organic chemistry [PDF]

open access: yes, 2009
Chapter 1 introduces the discovery of elemental fluorine by H. Moissan and some uses of inorganic fluoride. Organo fluoro compounds and their place in pharmaceuticals and agrochemicals are also introduced.
Gooseman, Natalie Elizabeth Jane
core   +2 more sources

Investigation of Electro‐Oxidation and Ozonation for Removal of Organics in Wastewater Derived From Recycling Process for Lithium‐Ion Batteries

open access: yesCleanMat, EarlyView.
To develop recycling processes for lithium‐ion batteries, wastewater treatment for the removal of organic compounds originating from the electrolyte was investigated using electro‐oxidation and ozonation. Based on the results, this paper proposes a process which combines these two methods to remove alcohols derived from the solvent and additives ...
Takumi Yasuda, Tetsuya Uda
wiley   +1 more source

Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide

open access: yesBeilstein Journal of Organic Chemistry, 2013
The trifluoromethylation of aryl iodides catalyzed by copper(I) salt with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide and Zn dust was accomplished.
Yuzo Nakamura   +6 more
doaj   +1 more source

Electroconductive MXene‐Thin‐Film‐Composite Membranes for Coupled Osmotic Concentration and PFAS Mineralization

open access: yesSmall, EarlyView.
An electroconductive MXene‐TFC membrane integrates osmotic dewatering with anodic oxidation to concentrate and mineralize PFOA at the membrane interface. The coupled AO‐PRO configuration accelerates degradation kinetics, achieves 99% rejection and up to 93% TOC removal, and lowers specific energy demand, offering a compact route for PFAS destruction ...
Afrouz Yousefi   +9 more
wiley   +1 more source

Merging Biocatalysis and Chemocatalysis in Flow: State‐of‐the‐Art and Future Directions for Sustainable Synthesis

open access: yesAngewandte Chemie, Volume 138, Issue 25, 15 June 2026.
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis   +2 more
wiley   +2 more sources

Organocatalytic asymmetric fluorination of α-chloroaldehydes involving kinetic resolution

open access: yesBeilstein Journal of Organic Chemistry, 2014
In a previous study it was shown that the enantioselective α-fluorination of racemic α-chloroaldehydes with a chiral organocatalyst yielded the corresponding α-chloro-α-fluoroaldehydes with high enantioselectivity.
Kazutaka Shibatomi   +5 more
doaj   +1 more source

Home - About - Disclaimer - Privacy