Efficient mechanochemical synthesis of new fluorinated Schiff bases: a solvent-free, alternative to conventional method with mercury adsorption properties [PDF]
BMC ChemistryThe development of sustainable synthetic techniques is of critical importance in modern chemistry. This paper describes a mechanochemical approach to the synthesis of novel fluorinated Schiff bases via ball milling, which provides a fast, high-yield, and
Mirza T. Baig +7 more
doaj +2 more sources
Correction to "A Novel Fluorine Mass Balance Method for Improved Characterization and Quantification of Extractable (Organo)fluorine in Drinking Water". [PDF]
Environ Sci Technol LettHe Z +3 more
europepmc +2 more sources
4,4′-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))-bis(2,3,5,6-tetrafluoropyridine)
Molbank, 2023 The title compound was synthesized in near-quantitative yield using nucleophilic aromatic substitution of 4,4′-(hexafluoroisopropylidene)diphenol (BPAF) with perfluoropyridine (PFP). The purity and structure were determined by NMR (1H, 13C, 19F), GC–EIMS,
Katelyn D. Thompson +3 more
doaj +1 more source
4-(4-(2-Bromoethyl)phenoxy)-2,3,5,6-tetrafluoropyridine
Molbank, 2023 The title compound was synthesized in near quantitative yields via initial nucleophilic aromatic substitution of pentafluoropyridine (PFP) with 4-(2-bromoethyl)phenol as a versatile precursor for ionic liquids (ILs).
Tiffany H. Li +4 more
doaj +1 more source
Flavin Catalysts in Organic Synthesis
Angewandte Chemie, EarlyView.Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley +2 more sources
Direct electrophilic N-trifluoromethylthiolation of amines with trifluoromethanesulfenamide
Beilstein Journal of Organic Chemistry, 2013 The CF3SN moiety is a substituent with interesting properties. However, there is no easy synthetic access to molecules bearing this group. The trifluoromethanesulfenamide is a new reagent for the electrophilic trifluoromethylthiolation which reacts ...
Sébastien Alazet +2 more
doaj +1 more source
Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3
Beilstein Journal of Organic Chemistry, 2013 A Cu-mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3 was developed for the first time. This method offers a convenient and economical approach to various trifluoroethyl-containing compounds.
Xueliang Jiang, Feng-Ling Qing
doaj +1 more source
A one-pot synthesis of 3-trifluoromethyl-2-isoxazolines from trifluoromethyl aldoxime
Beilstein Journal of Organic Chemistry, 2013 Functionalized 3-trifluoromethyl-2-isoxazolines and 3-trifluoromethylisoxazoles were easily prepared from trifluoromethyl aldoxime 2 under mild conditions by using DIB as oxidant.
Raoni S. B. Gonçalves +4 more
doaj +1 more source
Modulating NHC catalysis with fluorine
Beilstein Journal of Organic Chemistry, 2013 Fluorination often confers a range of advantages in modulating the conformation and reactivity of small molecule organocatalysts. By strategically introducing fluorine substituents, as part of a β-fluoroamine motif, in a triazolium pre-catalyst, it was ...
Yannick P. Rey, Ryan Gilmour
doaj +1 more source
Stereoselectively fluorinated N-heterocycles: a brief survey
Beilstein Journal of Organic Chemistry, 2013 The stereoselective incorporation of fluorine atoms into N-heterocycles can lead to dramatic changes in the molecules’ physical and chemical properties.
Xiang-Guo Hu, Luke Hunter
doaj +1 more source