Results 61 to 70 of about 63,731 (192)
Two‐Stage, Sequential Aryne Carboiodanation Enabled by Mesomeric Priming
Advanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.Two‐stage, sequential insertion of arynes into the carbon–iodine(III) bond of benziodoxole (BX) compounds is achieved by judicious choice of the BX/aryne pair in the first step, generating a mesomerically activated aryl‐BX primed for a second, discrete aryne insertion. This metal‐free strategy enables programed access to biaryl‐BXs and modular entry to
Shunya Morohashi +3 more
wiley +1 more source
Reaction of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithiethane with N-vinyl compounds
Beilstein Journal of Organic Chemistry, 2013 The reaction of hexafluorothioacetone dimer (2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithiethane, 1) with vinylamides leads to the rapid formation of [2 + 2] cycloadducts: 4-amino-2,2-bis(trifluoromethyl)thietanes.
Viacheslav A. Petrov, Will Marshall
doaj +1 more source
Addressing Bottlenecks to Achieve High‐Energy Sodium‐Ion Cells Using Tin Anodes
Advanced Energy Materials, Volume 16, Issue 17, 6 May 2026.The challenges in coupling high voltage cathode with Sn‐alloying anode or in anode‐free cell, using glyme based electrolytes to realize high energy Na‐ion cells are reported. Surface protection strategy such as SnO coating on Sn or trapping the parasitic species from poisoning the anode, helps improving the cyclability, with ∼100% capacity retention ...
Parth Desai +11 more
wiley +1 more source
Beilstein Journal of Organic Chemistry, 2014 The synthesis of 5-nitro-1-(trifluoromethyl)-3H-1λ3,2-benziodaoxol-3-one (3), a hypervalent-iodine-based electrophilic trifluoromethylating reagent, is described.
Nico Santschi +4 more
doaj +1 more source
New methodology for the synthesis of fluorinated aromatics [PDF]
, 1990 This thesis is concerned with new methodology for the introduction of fluorine atoms, and trifluoromethyl groups into aromatic systems and the following approaches have been adopted: (i) The possibility of selective cleavage of the aryl-silicon bond of ...
Rock, Michael Harold
core
One-pot cross-enyne metathesis (CEYM)–Diels–Alder reaction of gem-difluoropropargylic alkynes
Beilstein Journal of Organic Chemistry, 2013 Propargylic difluorides 1 were used as starting substrates in a combination of cross-enyne metathesis and Diels–Alder reactions. Thus, the reaction of 1 with ethylene in the presence of 2nd generation Hoveyda–Grubbs catalyst generates a diene moiety ...
Santos Fustero +5 more
doaj +1 more source
Estudos de reações de transesterificação com lipases imobilizadas e determinação de coeficiente de difusão de ésteres em organo-gel / [PDF]
, 1999 Tese (Doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.As lipases de Chromobacterium viscosum, Pseudomonas sp, Microbial e Lipolase, imobilizadas em organo-gel (MBG) de hexano foram usadas como ...
João, Jair Juarez
core
Beilstein Journal of Organic Chemistry, 2013 The cross-coupling reactions of 2,2-difluoro-1-iodoethenyl tosylate (2) with 2 equiv of boronic acids in the presence of catalytic amounts of Pd(OAc)2 and Na2CO3 afforded the mono-coupled products 3 and 5 in high yields.
Ju Hee Kim, Su Jeong Choi, In Howa Jeong
doaj +1 more source
Beilstein Journal of Organic Chemistry, 2014 Diethyl 2-fluoromalonate ester is utilised as a building block for the synthesis of 2-fluoro-2-arylacetic acid and fluorooxindole derivatives by a strategy involving nucleophilic aromatic substitution reactions with ortho-fluoronitrobenzene substrates ...
Antal Harsanyi +3 more
doaj +1 more source