Modulating NHC catalysis with fluorine
Beilstein Journal of Organic Chemistry, 2013 Fluorination often confers a range of advantages in modulating the conformation and reactivity of small molecule organocatalysts. By strategically introducing fluorine substituents, as part of a β-fluoroamine motif, in a triazolium pre-catalyst, it was ...
Ryan Gilmour
exaly +2 more sources
DNA-Binding Properties of Iridium(III) Complexes Encompassing Design, Function and Biophysical Assessments. [PDF]
ChemphyschemThis review describes the biophysical techniques used to investigate DNA‐binding phenomena and the progress made so far in the application of iridium(III) complexes for this purpose. Ir(III) complexes offer myriad opportunities in the design and study of DNA‐binding agents and discussed examples are contextualised with complementary studies in ...
Alkhaibari IS, Buurma NJ, Pope SJA.
europepmc +2 more sources
Efficient mechanochemical synthesis of new fluorinated Schiff bases: a solvent-free, alternative to conventional method with mercury adsorption properties [PDF]
BMC ChemistryThe development of sustainable synthetic techniques is of critical importance in modern chemistry. This paper describes a mechanochemical approach to the synthesis of novel fluorinated Schiff bases via ball milling, which provides a fast, high-yield, and
Mirza T. Baig +7 more
doaj +2 more sources
Correction to "A Novel Fluorine Mass Balance Method for Improved Characterization and Quantification of Extractable (Organo)fluorine in Drinking Water". [PDF]
Environ Sci Technol LettHe Z +3 more
europepmc +2 more sources
4,4′-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))-bis(2,3,5,6-tetrafluoropyridine)
Molbank, 2023 The title compound was synthesized in near-quantitative yield using nucleophilic aromatic substitution of 4,4′-(hexafluoroisopropylidene)diphenol (BPAF) with perfluoropyridine (PFP). The purity and structure were determined by NMR (1H, 13C, 19F), GC–EIMS,
Katelyn D. Thompson +3 more
doaj +1 more source
Chemical diffusion of fluorine in melts in the system Na2OAl2O3SiO2 [PDF]
, 1985 The volatilization of fluorine from three melts in the system Na2OAl2O3SiO2 has been investigated at 1 atm pressure and 1200–1400°C. The melts chosen have base compositions corresponding to albite, jadeite and a peraluminous melt with 75 mole % SiO2 ...
Scarfe, Christopher M. +1 more
core +1 more source
4-(4-(2-Bromoethyl)phenoxy)-2,3,5,6-tetrafluoropyridine
Molbank, 2023 The title compound was synthesized in near quantitative yields via initial nucleophilic aromatic substitution of pentafluoropyridine (PFP) with 4-(2-bromoethyl)phenol as a versatile precursor for ionic liquids (ILs).
Tiffany H. Li +4 more
doaj +1 more source
The effect of fluorine on viscosities in the system Na2O-Al2O3-SiO2: implications for phonolites, trachytes and rhyolites [PDF]
, 1985 The effect of fluorine on melt viscosities of five compositions in the system Na2O-Al2O3- SiO2h as been investigateda t one atmospherea nd 1000-1600'Cb y concentric-cylinder viscometry.
Scarfe, Christopher M. +2 more
core +1 more source
, 2006 This paper investigates how fluorine implantation can be used to suppress boron diffusion in the base of a double polysilicon silicon bipolar transistor and hence deliver a record fT of 110 GHz.
Messina, A. +8 more
core +2 more sources
Direct electrophilic N-trifluoromethylthiolation of amines with trifluoromethanesulfenamide
Beilstein Journal of Organic Chemistry, 2013 The CF3SN moiety is a substituent with interesting properties. However, there is no easy synthetic access to molecules bearing this group. The trifluoromethanesulfenamide is a new reagent for the electrophilic trifluoromethylthiolation which reacts ...
Sébastien Alazet +2 more
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