Results 51 to 60 of about 887 (144)
A Direct Method to Prepare Zwitterionic Organotrifluoroborates: Ammonium and Sulfonium Derivatives
European Journal of Organic Chemistry, Volume 29, Issue 18, 14 May 2026.Organotrifluoroborates find applications in synthesis, diagnostics, and theranostics. This study outlines a one‐step reaction for producing ammonium and sulfonium trifluoroborate zwitterion derivatives. This method achieves satisfactory yields without the need for expensive reagents.
Vanessa Re +6 more
wiley +1 more source
Beilstein Journal of Organic Chemistry, 2013 The cross-coupling reactions of 2,2-difluoro-1-iodoethenyl tosylate (2) with 2 equiv of boronic acids in the presence of catalytic amounts of Pd(OAc)2 and Na2CO3 afforded the mono-coupled products 3 and 5 in high yields.
Ju Hee Kim, Su Jeong Choi, In Howa Jeong
doaj +1 more source
Two‐Stage, Sequential Aryne Carboiodanation Enabled by Mesomeric Priming
Advanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.Two‐stage, sequential insertion of arynes into the carbon–iodine(III) bond of benziodoxole (BX) compounds is achieved by judicious choice of the BX/aryne pair in the first step, generating a mesomerically activated aryl‐BX primed for a second, discrete aryne insertion. This metal‐free strategy enables programed access to biaryl‐BXs and modular entry to
Shunya Morohashi +3 more
wiley +1 more source
Beilstein Journal of Organic Chemistry, 2014 Diethyl 2-fluoromalonate ester is utilised as a building block for the synthesis of 2-fluoro-2-arylacetic acid and fluorooxindole derivatives by a strategy involving nucleophilic aromatic substitution reactions with ortho-fluoronitrobenzene substrates ...
Antal Harsanyi +3 more
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Addressing Bottlenecks to Achieve High‐Energy Sodium‐Ion Cells Using Tin Anodes
Advanced Energy Materials, Volume 16, Issue 17, 6 May 2026.The challenges in coupling high voltage cathode with Sn‐alloying anode or in anode‐free cell, using glyme based electrolytes to realize high energy Na‐ion cells are reported. Surface protection strategy such as SnO coating on Sn or trapping the parasitic species from poisoning the anode, helps improving the cyclability, with ∼100% capacity retention ...
Parth Desai +11 more
wiley +1 more source
Regioselective carbon–carbon bond formation of 5,5,5-trifluoro-1-phenylpent-3-en-1-yne
Beilstein Journal of Organic Chemistry, 2013 The regioselective carbon–carbon bond formation was studied using 5,5,5-trifluoro-1-phenylpent-3-en-1-yne as a model substrate, and predominant acceptance of electrophiles β to a CF3 group as well as a deuterium trap experiment of the lithiated species ...
Motoki Naka +2 more
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Three step synthesis of single diastereoisomers of the vicinal trifluoro motif
Beilstein Journal of Organic Chemistry, 2009 A three step route to single diastereoisomers of the vicinal trifluoromethyl motif is described. The route starts from either syn- or anti-α,β-epoxy alcohols and takes a direct approach in that each of the three steps introduces a fluorine atom in a ...
Vincent A. Brunet +2 more
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Crystal design using multipolar electrostatic interactions: A concept study for organic electronics
Beilstein Journal of Organic Chemistry, 2013 Using a simple synthetic protocol, heterohexacene analogues with a quadrupolar distribution of partial charges are readily available. In contrast to most other acenes, these compounds crystallize with a slipped-stack, brickwork-like packing which is ...
Peer Kirsch +2 more
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Diastereoselectivity in the Staudinger reaction of pentafluorosulfanylaldimines and ketimines
Beilstein Journal of Organic Chemistry, 2013 β-Lactams were diastereoselectively formed by the reaction of SF5-containing aldimines, or an SF5-containing ketimine, with benzyloxyketene in a conrotatory ring closure process. Imine formation and cyclization were possible in spite of the acidification
Alexander Penger +3 more
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The preferred conformation of erythro- and threo-1,2-difluorocyclododecanes
Beilstein Journal of Organic Chemistry, 2012 Cyclododecane adopts a square-like structure with corner and edge CH2 groups. In this study erythro- and threo-1,2-difluorocyclododecanes were prepared to explore whether the two vicinal C–F bonds, with different relative configurations, preferably ...
Yi Wang +4 more
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