Results 61 to 70 of about 2,771,586 (165)

Rapid Dehydroxytrifluoromethoxylation of Alcohols

iScience, 2018
Summary: The CF3O functional group is a unique fluorinated group that has received a great deal of attention in medicinal chemistry and agrochemistry. However, trifluoromethoxylation of substrates remains a challenging task.
Wei Zhang, Jia Chen, Jin-Hong Lin, Ji-Chang Xiao, Yu-Cheng Gu   +4 more
doaj   +1 more source

Photocatalytic Synthesis and Palladium‐Catalyzed Functionalizations of Hydrofluoroolefin (HFO‐1234ze)‐Based Vinyl Iodides

Advanced Synthesis &Catalysis, Volume 368, Issue 18, 19 September 2026.
An inexpensive industrial refrigerant, HFO‐1234ze, is transformed into a versatile fluoroalkyl building block via a scalable, solvent‐free protocol. Utilizing the metal‐free photocatalyst 4CzIPN, efficient visible‐light‐induced radical addition to alkynes reveals distinct, substrate‐dependent stereoselectivities.
Bálint Varga, Péter Szalai, Klára Aradi, Bálint Nagy, András Kotschy, Zoltán Novák   +5 more
wiley   +1 more source

Two decades of fluorine chemistry in Cergy

Comptes Rendus. Chimie
The development of chiral fluorinated biomolecules such as amino acids, peptides and pseudopeptides is attracting considerable interest at the frontiers of organic synthesis and biological chemistry.
Pytkowicz, Julien, Chaume, Grégory, Lensen, Nathalie, Chelain, Evelyne, Brigaud, Thierry   +4 more
doaj   +1 more source

Fluorinated building blocks [PDF]

, 2000
Julian A Cooper This work describes the functionalisation of carbon-hydrogen bonds in saturated hydrocarbons via free radical addition to fluorinated alkenes. For example, hexafluoropropene can be added to produce a mono-adduct:- A range of fluoroalkenes
Cooper, Julian A.
core  

Unique Reactivity of Fluorinated Molecules with Transition Metals

CHIMIA, 2014
Organofluorine and organometallic chemistry by themselves constitute two potent areas in organic synthesis. Thus, the combination of both offers many chemical possibilities and represents a powerful tool for the design and development of new ...
Silvia Catalán, Sócrates B. Munoz, Santos Fustero   +2 more
doaj   +1 more source

Facilitating the transmetalation step with aryl-zincates in nickel-catalyzed enantioselective arylation of secondary benzylic halides

Nature Communications, 2019
Fluoroalkyl groups are widely found in pharmaceutical products. Here, the authors report a highly enantioselective nickel-catalyzed cross coupling method for the construction of fluoromethylated stereogenic centers via a highly reactive zincate species ...
Weichen Huang, Mei Hu, Xiaolong Wan, Qilong Shen   +3 more
doaj   +1 more source

Silica Coating Enhances the PFAS Photocatalytic Properties of Boron Nitride

CleanMat, Volume 3, Issue 3, Page 226-236, September 2026.
A coating of 6 wt% SiO2 effectively covered the edges of BN, which lowered BN hydrolysis and increased PFOA photodegradation. ABSTRACT Boron nitride (BN) has recently emerged as a promising material capable of breaking down toxic perfluorooctanoic acid (PFOA) and other per‐ and polyfluoroalkyl substances (PFAS) through photocatalysis. However, chemical
Youngkun Chung, Bo Wang, Gunhak Oh, Kiheon Hong, Welman C. Elias, Juan A. Donoso, Kimberly Heck, Michael S. Wong   +7 more
wiley   +1 more source

Synthesis of α,α‐Difluoroketones via Zinc‐Mediated Cross‐Electrophile Coupling of gem‐Difluoroenol Sulfonates and N‐(acyloxy)phthalimides

ChemistryOpen, Volume 15, Issue 9, September 2026.
A zinc‐mediated catalyst‐free cross‐electrophile couplingbetween gem‐difluoroenol sulfonates and N‐(acyloxy) phthalimides accesses structurally diverse α,α‐difluoroketones. It exhibits broad radical compatibility, reliable gram‐scale performance, and enables construction of elaborate fluorinated amino acid and glycosyl derivatives.
Jing Zhao, Li Yang, Xiaohong Wang, Baojian Xiong, Xinmin Li, Huan Yang   +5 more
wiley   +1 more source

Fluoroalkyl Amino Reagents (FARs): A General Approach towards the Synthesis of Heterocyclic Compounds Bearing Emergent Fluorinated Substituents

Molecules, 2017
Fluorinated heterocycles are important building blocks in pharmaceutical, agrochemical and material sciences. Therefore, organofluorine chemistry has witnessed high interest in the development of efficient methods for the introduction of emergent ...
Bruno Commare, Etienne Schmitt, Fallia Aribi, Armen Panossian, Jean-Pierre Vors, Sergiy Pazenok, Frédéric R. Leroux   +6 more
doaj   +1 more source

Restoration ecology in conflict along the Colorado front range

Restoration Ecology, Volume 34, Issue 7, September 2026.
Abstract Introduction Cheatgrass (Bromus tectorum) is a challenge to restoration in western North America. It attracts the attention of academic and government research scientists, weed managers, and chemical companies. Attempts to control it cause conflicts among these groups.
G. Robert Brakenridge, Tim R. Seastedt
wiley   +1 more source