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Organometallic chemistry [PDF]
Transition metal organometallic chemistry is a rapidly expanding field, which has an important relationship to industrial problems of petrochemical catalysis. This thesis describes studies of fundamental organometallic reaction processes, such as C-H and C-C bond formation and cleavage, and investigations of the structure and bonding of organometallic
Bernd F. Straub +3 more
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Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry
Metal–organic frameworks (MOFs) are emerging porous materials with highly tunable structures developed in the 1990s, while organometallic chemistry is of fundamental importance for catalytic transformation in the academic and industrial world for many ...
Fan Chen +6 more
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Alkali-Metal Mediation: Diversity of Applications in Main-Group Organometallic Chemistry. [PDF]
Organolithium compounds have been at the forefront of synthetic chemistry for over a century, as they mediate the synthesis of myriads of compounds that are utilised worldwide in academic and industrial settings.
Gentner TX, Mulvey RE.
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Olefin metathesis: what have we learned about homogeneous and heterogeneous catalysts from surface organometallic chemistry? [PDF]
Since its early days, olefin metathesis has been in the focus of scientific discussions and technology development. While heterogeneous olefin metathesis catalysts based on supported group 6 metal oxides have been used for decades in the petrochemical ...
Copéret C +6 more
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Organometallic Chemistry within the Structured Environment Provided by the Macrocyclic Cores of Carbaporphyrins and Related Systems [PDF]
The unique environment within the core of carbaporphyrinoid systems provides a platform to explore unusual organometallic chemistry. The ability of these structures to form stable organometallic derivatives was first demonstrated for N-confused ...
Timothy D. Lash
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The selective conversion of light alkanes (C2–C6 saturated hydrocarbons) to the corresponding alkene is an appealing strategy for the petrochemical industry in view of the availability of these feedstocks, in particular with the emergence of Shale gas ...
Docherty SR +3 more
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Editorial for “Organometallic Chemistry” Section, in Journal Molecules [PDF]
It is a great pleasure to assume the role of Editor-in-Chief for the “Organometallic Chemistry” Section of Molecules (https://www [...]
Michal Szostak
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Organometallic Neptunium Chemistry [PDF]
Fifty years have passed since the foundation of organometallic neptunium chemistry, and yet only a handful of complexes have been reported, and even fewer have been fully characterized. Yet, increasingly, combined synthetic/spectroscopic/computational studies are demonstrating how covalently bonding, soft, carbocyclic organometallic ligands provide an ...
Polly L. Arnold +2 more
openaire +3 more sources
This chapter focuses on the organometallic chemistry of the f-elements, which is very different from that of the d-transition metals. This is mainly due to the predominantly ionic nature of the bonding and the lack of two-electron redox chemistry for the f-elements. The chapter begins with examples of homoleptic σ-bonded alkyls and aryls and then moves
H. C. Aspinall
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Recent advancements on the use of 2-methyltetrahydrofuran in organometallic chemistry. [PDF]
Since the introduction of 2-methyltetrahydrofuran as an useful alternative to the classical tetrahydrofuran, there has been a continuous interest in the synthetic community operating at academic and industrial towards it.
Monticelli S +8 more
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