Results 11 to 20 of about 62,479 (238)

Designing organometallic compounds for catalysis and therapy [PDF]

open access: yes, 2012
Bioorganometallic chemistry is a rapidly developing area of research. In recent years organometallic compounds have provided a rich platform for the design of effective catalysts, e.g. for olefin metathesis and transfer hydrogenation.
Abraha Habtemariam   +188 more
core   +1 more source

Organometallic Chemistry in Non-Classical Environments

open access: yesCHIMIA, 2011
A summary of our on-going research on organometallic chemistry is provided with an emphasis on the function, reactivity and mechanisms of organometallic compounds in water, ionic liquids and in living systems.
Paul J. Dyson
doaj   +1 more source

Cu-mediated enantioselective C–H alkynylation of ferrocenes with chiral BINOL ligands

open access: yesNature Communications, 2023
A wide range of Cu(II)-catalyzed C–H activation reactions have been realized since 2006, however, whether a C–H metalation mechanism similar to Pd(II)-catalyzed C–H activation reaction is operating remains an open question.
Xin Kuang   +6 more
doaj   +1 more source

Recent Advances in the Synthetic and Mechanistic Aspects of the Ruthenium-catalyzed Carbon-heteroatom Bond Forming Reactions of Alkenes and Alkynes [PDF]

open access: yes, 2011
The group’s recent advances in catalytic carbon-to-heteroatom bond forming reactions of alkenes and alkynes are described. For the C–O bond formation reaction, a well-defined bifunctional ruthenium-amido catalyst has been successfully employed for the ...
Yi, Chae S.
core   +2 more sources

New trends for metal complexes with anticancer activity [PDF]

open access: yes, 2008
Medicinal inorganic chemistry can exploit the unique properties of metal ions for the design of new drugs. This has, for instance, led to the clinical application of chemotherapeutic agents for cancer treatment, such as cisplatin. The use of cisplatin is,
Ang   +56 more
core   +1 more source

Química organometálica de superfície aplicada à preparação de catalisadores heterogêneos bem definidos Surface organometallic chemistry applied to the preparation of well defined heterogeneous catalysts

open access: yesQuímica Nova, 2002
The study of the reactions of organometallic complexes with the surfaces of inorganic oxides, zeolites and metals constitutes the basis of Surface Organometallic Chemistry (SOMC).
Silvana I. Wolke, Regina Buffon
doaj   +1 more source

Dioxygen Activation by Internally Aromatic Metallacycle: Crystallographic Structure and Mechanistic Investigations

open access: yesiScience, 2020
Summary: Mononuclear metal-peroxo species are invoked as the key intermediates in metalloenzymatic or synthetic catalysis. However, either transience or sluggishness reactivity of synthetic analogs of metal-peroxo species impedes our understanding of ...
Zhihong Deng   +7 more
doaj   +1 more source

Current applications and future potential for bioinorganic chemistry in the development of anticancer drugs [PDF]

open access: yes, 2009
This review illustrates notable recent progress in the field of medicinal bioinorganic chemistry as many new approaches to the design of innovative metal-based anticancer drugs are emerging.
Aird   +75 more
core   +1 more source

Chirality Induction in Bioorganometallic Conjugates

open access: yesInorganics, 2018
Considerable attention has been given to the research field of bioorganometallic chemistry, which is a hybrid chemistry field between biology and organometallic chemistry.
Toshiyuki Moriuchi   +2 more
doaj   +1 more source

Pyrinap ligands for enantioselective syntheses of amines

open access: yesNature Communications, 2021
Chiral amines find use as chiral ligands, resolving reagents and versatile building blocks as well as in pharmaceuticals and agrochemicals. Here, the authors developed Pyrinap ligands for the copper-catalyzed enantioselective A3-coupling of terminal ...
Qi Liu   +6 more
doaj   +1 more source

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