The para-substituent effect and pH-dependence of the organometallic Baeyer–Villiger oxidation of rhenium–carbon bonds [PDF]
, 2012 We studied the Baeyer–Villiger (BV) type oxidation of phenylrhenium trioxide (PTO) by H2O2 in the aqueous phase using Quantum Mechanics (density functional theory with the M06 functional) focusing on how the solution pH and the para-substituent affect ...
Bischof, Steven M. +5 more
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The contrasting activity of iodido versus chlorido ruthenium and osmium arene azo- and imino-pyridine anticancer complexes : control of cell selectivity, cross-resistance, p53 dependence, and apoptosis pathway [PDF]
, 2013 Organometallic half-sandwich complexes [M(p-cymene)(azo/imino-pyridine)X]+ where M = RuII or OsII and X ═ Cl or I, exhibit potent antiproliferative activity toward a range of cancer cells.
Romero-Canelón, Isolda +2 more
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Anti-colorectal cancer activity of an organometallic osmium arene azopyridine complex [PDF]
, 2011 This first in vivo antitumour activity for an organometallic osmium arene complex, [Os(eta(6)-p-cym)(4-(2-pyridylazo)-N,N-dimethylaniline)I]PF(6), is reported. The complex delays the growth of HCT116 human colon cancer xenografts in mice, with negligible
Cooper, Patricia A. +6 more
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Kinetics of Intramolecular Chemical Exchange by Initial Growth Rates of Spin Saturation Transfer Difference Experiments (SSTD NMR) [PDF]
, 2015 We report here the Initial Growth Rates SSTD NMR method, as a new powerful tool to obtain the kinetic parameters of intramolecular chemical exchange in challenging small organic and organometallic ...
Angulo +40 more
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Rhodapentalenes: Pincer Complexes with Internal Aromaticity
iScience, 2019 Summary: Pincer complexes are a remarkably versatile family benefited from their stability, diversity, and tunability. Many of them contain aromatic organic rings at the periphery, and aromaticity plays an important role in their stability and properties,
Qingde Zhuo +7 more
doaj +1 more source
Zigzag-shaped nickel nanowires via organometallic template-free route [PDF]
, 2013 In this manuscript, the formation of nickel nanowires (average size: several tens to hundreds of μm long and 1.0-1.5 μm wide) at low temperature is found to be driven by dewetting of liquid organometallic precursors during spin coating process and by ...
András Paszternák +28 more
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Catalytic Activity of bis-Phosphine Ruthenium(II)-Arene Compounds
CHIMIA, 2008 This overview presents recent work on the coordination chemistry and catalytic activity of bis-phosphine ruthenium(II)-arene complexes, [RuCl(PPh3)(PR3)(?6-arene)]+, carried out in the Laboratory of Organometallic and Medicinal Chemistry at the
Adrian B. Chaplin
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iScience, 2021 Summary: We study the interaction between amyloid β (Aβ) peptides and Cu and Zn metal ions by using soft X-ray absorption spectroscopy. The spectral features of the peptides and Cu are simultaneously characterized by recording spectra at the N K-edge and
Jinghui Luo +5 more
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Cp2TiCl/D2O/Mn, a formidable reagent for the deuteration of organic compounds [PDF]
, 2016 Cp2TiCl/D2O/Mn is an efficient combination, sustainable and cheap reagent that mediates the D-atom transfer from D2O to different functional groups and can contribute to the synthesis of new deuterated organic compounds under friendly experimental ...
Rodríguez-García, Ignacio +1 more
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Editorial for “Organometallic Chemistry” Section, in Journal Molecules
Molecules, 2020 It is a great pleasure to assume the role of Editor-in-Chief for the “Organometallic Chemistry” Section of Molecules (https://www [...]
Michal Szostak
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