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Organometallic chemistry [PDF]

open access: yesBeilstein Journal of Organic Chemistry, 2016
Transition metal organometallic chemistry is a rapidly expanding field, which has an important relationship to industrial problems of petrochemical catalysis. This thesis describes studies of fundamental organometallic reaction processes, such as C-H and C-C bond formation and cleavage, and investigations of the structure and bonding of organometallic
Bernd F. Straub   +3 more
doaj   +5 more sources

Metal–Organic Frameworks as Versatile Platforms for Organometallic Chemistry

open access: yesInorganics, 2021
Metal–organic frameworks (MOFs) are emerging porous materials with highly tunable structures developed in the 1990s, while organometallic chemistry is of fundamental importance for catalytic transformation in the academic and industrial world for many ...
Fan Chen   +6 more
doaj   +1 more source

Guanidinates as Alternative Ligands for Organometallic Complexes

open access: yesMolecules, 2022
For decades, ligands such as phosphanes or cyclopentadienyl ring derivatives have dominated Coordination and Organometallic Chemistry. At the same time, alternative compounds have emerged that could compete either for a more practical and accessible ...
Fernando Carrillo-Hermosilla   +3 more
doaj   +1 more source

Carbon Ligands: From Fundamental Aspects to Applications

open access: yesMolecules, 2021
Ligand design is at the forefront of many advances in various areas of chemistry such as organometallic chemistry, functional materials, and homogeneous catalysis [...]
Yves Canac
doaj   +1 more source

Organometallic Neptunium Chemistry [PDF]

open access: yesChemical Reviews, 2017
Fifty years have passed since the foundation of organometallic neptunium chemistry, and yet only a handful of complexes have been reported, and even fewer have been fully characterized. Yet, increasingly, combined synthetic/spectroscopic/computational studies are demonstrating how covalently bonding, soft, carbocyclic organometallic ligands provide an ...
Polly L. Arnold   +2 more
openaire   +2 more sources

Organometallic Chemistry within the Structured Environment Provided by the Macrocyclic Cores of Carbaporphyrins and Related Systems

open access: yesMolecules, 2023
The unique environment within the core of carbaporphyrinoid systems provides a platform to explore unusual organometallic chemistry. The ability of these structures to form stable organometallic derivatives was first demonstrated for N-confused ...
Timothy D. Lash
doaj   +1 more source

Thermal Decomposition of Epoxy Resin Under SF6 Atmosphere [PDF]

open access: yesMATEC Web of Conferences, 2022
The latent fault diagnosis of GIS equipment relies on the electrothermal corrosion information of the decomposition products of SF6. The thermal decomposition of epoxy resin under atmosphere (SF6-Epoxy) is essential to reveal the relationship between ...
Yang Ren   +6 more
doaj   +1 more source

Non-Covalent Interactions in Coordination and Organometallic Chemistry

open access: yesCrystals, 2020
The problem of non-covalent interactions in coordination and organometallic compounds is a hot topic in modern chemistry, material science, crystal engineering and related fields of knowledge.
Alexander S. Novikov
doaj   +1 more source

Towards a Paradigm Shift in Polar Organometallic Chemistry

open access: yesCHIMIA, 2020
Core tools of synthetic chemistry, polar organometallic reagents (typified by organolithium and Grignard reagents) are used worldwide for constructing compounds, especially aromatic compounds, which are ubiquitous in organic chemistry and thus in ...
Eva Hevia
doaj   +1 more source

Cobalt(III)-catalyzed asymmetric ring-opening of 7-oxabenzonorbornadienes via indole C–H functionalization

open access: yesNature Communications, 2023
Asymmetric ring-opening (ARO) reactions, which can help quickly build molecular complexity, have not been extensively shown via β-oxygen elimination. Here, the authors report a cobalt(III)-catalyzed ARO reaction, providing mechanistic insights and the ...
Yang Zheng   +4 more
doaj   +1 more source

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