Results 171 to 180 of about 20,886 (238)

Organorhodium and Iridium-Containing Derivatives of the 48-Tungsto-8-phosphate Wheel: Synthesis, Characterization, and Catalytic Activity. [PDF]

Inorg Chem
Mougharbel AS, Bhattacharya S, Sarkar A, Bons AJ, D'hondt T, Jaensch H, Kortz U.   +6 more
europepmc   +1 more source

Synthesis and characterization of amphiphilic nitroxide 1,1,3,3–tetraethylisoindoline–2–oxyl–5–sodium sulfonate (TEIOSNa)

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract The synthesis and characterization of an amphiphilic nitroxide to be used as a controlling agent in a nitroxide‐mediated living radical polymerization in aqueous dispersion media is presented. In the first stage of nitroxide synthesis (phthalimide protection), two reaction methods were employed: traditional and microwave.
Enrique García‐Leal, Martha Eugenia Albores Velasco, René O. Vargas, Rubén Mil‐Martínez   +3 more
wiley   +1 more source

A general aqueous synthetic strategy towards 1-benzylTHIQs enabled by umpolung hydrazone. [PDF]

Chem Sci
Kaur M, Chen EFW, Salgado JM, Cheng R, Li CJ.   +4 more
europepmc   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Remote Migratory Reductive Arylation of Unactivated Alkenes Enabled by Electrochemical Nickel Catalysis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley   +1 more source

Nitrogen‐Site Isomerism Unlocks Exciton Dissociation in Vinylene‐Linked COF‐Based Photocatalysts

EcoEnergy, EarlyView.
Two regioisomeric vinylene‐linked covalent organic frameworks (COFs) constructed from diazine units with different nitrogen positions are developed for photocatalytic hydrogen evolution reaction (HER). Although structurally similar, the isomeric COFs exhibit distinct electron distribution and charge‐separation behaviors, leading to a more than twofold ...
Ming Wang, Zhongliang Wen, Chengbo Zhang, Wei Wang, Yaling Li, Xiaofang Su, Rached Ousji, Yanqiong Luo, Muhammad Imran Anwar, Rengui Li, Yanan Gao   +10 more
wiley   +1 more source

Smart Functional Hydrogels: Emerging Platforms for Thermal and Electrochemical Energy Harvesting and Conversion Systems

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The hydrogel exhibits versatile functions, including efficient thermogalvanic conversion under a temperature difference, and acting as a cooling layer/forming a thermally conductive nanoactive composite for thermovoltaic conversion. Additionally, its self‐healing and self‐powered flexibility play a key role in energy storage systems. The growing demand 
Eunah Kang
wiley   +1 more source

From Olefin Coordination to Rh─N Bond Formation and Oxidative Addition: pH Effects in Rhodium α‐Methyl‐β‐Amidoitaconate Complexes

European Journal of Inorganic Chemistry, EarlyView.
The coordination of α‐methyl‐β‐amidoitaconate at Rh(I) diphosphine complexes is studied using a combination of high‐field and low‐field flow NMR spectroscopy and X‐ray analysis. In the presence of basic or acidic additives, the formation of neutral Rh(I) or Rh(III) complexes occurs.
Neeraja M. Kaimal, Thomas Osterland, Hans‐Joachim Drexler, Torsten Beweries   +3 more
wiley   +1 more source

Exploring the Anticancer Activity of Ruthenium(II)–Arene and Copper(I) Complexes Bearing N‐Heterocyclic Carbene Ligands Containing Azido, Pyridinium, and Ethisterone‐Derived Triazole Groups

European Journal of Inorganic Chemistry, EarlyView.
A versatile library of backbone‐functionalized N‐heterocyclic carbene (NHC) ligands was developed and efficiently converted into Cu(I) and Ru(II) NHC complexes, demonstrating that ligand functionalization strongly modulates anticancer activity, with Cu(I)–NHC species showing potent and selective antiproliferative effects against ovarian and breast ...
Alessia Schiavo, Chiara Tupini, Nicola Demitri, Ilaria Lampronti, Thomas Scattolin   +4 more
wiley   +1 more source

3DOpt: Benchmark for Automated Design of 3D Molecular Structures across the Periodic Table. [PDF]

J Chem Inf Model
Costamagna M, Thomas M, Foscato M, Jensen VR.   +3 more
europepmc   +1 more source