Results 161 to 170 of about 20,886 (238)

Enabling Cross‐Coupling Reactivity of α‐Pentafluorosulfanyl Compounds with a Thermally Stable Organozinc α‐SF5 Reagent

Chemistry – A European Journal, EarlyView.
This work describes the first example of a thermally stable α‐SF5 organometallic reagent, which allows for extensive downstream functionalization by allylation and acylation reactions under copper catalysis, as well as palladium‐catalyzed Negishi‐type cross‐coupling conditions up to 96% yield. In silico analysis shines initial light on the requirements
Lujie Xu, David Rombach
wiley   +1 more source

Metalloids: Semi as Metals yet Full of Antimicrobial Potential. [PDF]

ChemMedChem
Böhm K, Nasim MJ, Jacob C.
europepmc   +1 more source

Isolable ArInH2: Double Hydroindation Agent

Chemistry – A European Journal, EarlyView.
Stable crystalline monomeric indium dihydride ArInH2 was isolated and completely characterized using effective support of the P,C,P‐pincer ligand (Ar = 2,6‐(tBu2PO)2C6H3). It serves as unparalleled hydroindation agent, thereby extending the family of known hydrometallation process relying on heavy p‐block metals.
Adam Hochmal, Zdeňka Růžičková, Aleš Růžička, Roman Jambor, Milan Erben, Libor Dostál   +5 more
wiley   +1 more source

Cobalt-Catalyzed Three-Component Reductive Coupling of Aldehydes, Allenes, and Aryl Halides. [PDF]

Org Lett
Sieber JD, Togoh M, Azad S, McHenry T, Sanders M.   +4 more
europepmc   +1 more source

Organometallic Compounds [PDF]

Nature, 1966
openaire   +1 more source

Photochemical and Thermal Activation of a Diarylbismuth Azide

Chemistry – A European Journal, EarlyView.
We report the synthesis and characterization of a novel diarylbismuth azide and its divergent reactivity upon thermal or photochemical activation. These findings contribute expanding the reactivity landscape of heavy pnictogen compounds and sets the basis for further investigations. ABSTRACT Azides are widely employed in synthesis as convenient nitrene
Giacomo Pugliese, Oliver Pichl, Gregor Schnakenburg, Peter Vöhringer, Luis I. Domenianni, Alessandro Bismuto   +5 more
wiley   +1 more source

Mannich reaction with organozinc reagents in continuous flow: experimental and computational studies. [PDF]

RSC Adv
Fraile-González L, Sánchez-González Á, Peña LF, López E.   +3 more
europepmc   +1 more source

Infrared Irradiation‐Assisted Pd‐Catalyzed C(sp3)─H Arylation and Tandem Cyclization of Ortho‐Tolualdehydes

Chemistry – A European Journal, EarlyView.
A rapid and efficient protocol for the synthesis of 2‐benzylbenzaldehydes and anthracenes is reported, based on the infrared (IR) irradiation‐assisted Pd‐catalyzed C(sp3)─H arylation and the tandem C(sp3)─H arylation/electrophilic aromatic cyclization of ortho‐tolualdehydes with aryl iodides via a transient directing group (TGD) strategy.
Matteo Renato Martina, Ambra Maria Fiore, Angela Punzi, Gianluigi Albano, Roberta Ragni, Pietro Cotugno, Gianluca Maria Farinola   +6 more
wiley   +1 more source

Two in one: a facile modular approach for the assembly of pnictogen-rich heteroleptic organometallic complexes. [PDF]

Chem Sci
Mondal B, Riesinger C, Scheer M.
europepmc   +1 more source

Self‐Immolative Poly(Benzyl Ether)s: Design Principles and Controlled Depolymerization

Chemistry – A European Journal, EarlyView.
Unzipping to Sustainability: This Concept article explores the thermodynamic design of quinone‐methide (QM)‐based poly(benzyl ether)s (PBEs). It explains how a low ceiling temperature (Tc), QM stability, and an entropic gain drive rapid depolymerization (“unzipping”) of PBEs into monomers.
Ji Woo Kim, Yewon Kang, Hyungwoo Kim
wiley   +1 more source