Results 141 to 150 of about 84,401 (336)
Synthesis and Reactivity of Extremely Electron‐Poor Au(III) Complexes Bearing OTf− or NTf2− Ligands
A new family of electron‐poor Au(III) cations bearing bistriflimide or triflate ligands is reported. These cations can undergo direct C─H metalation with simple arenes to give mono‐aryl cations. Subsequent addition of simple halide sources allows for reductive elimination of aryl halides, formally from Ar─H and X−. ABSTRACT The synthesis and structural
Lachlan Barwise +6 more
wiley +1 more source
Metal complexes of weakly coordinating anions. Precursors of strong cationic organometallic Lewis acids [PDF]
Beck, Wolfgang, Sünkel, Karlheinz
core +1 more source
Complex [Dy2(hynad)2(dbm)4] was prepared by the employment of the anionic N–O‐based bridging and chelating N‐hydroxy‐1,8‐naphthalimide ligand, featuring a {Dy2(µ‐OR)2}4+ core and exhibiting zero‐field SMM behavior with a Ueff value of 171 K and double‐S‐shaped hysteresis loops, open up to 3.5 K.
Alexandros S. Armenis +6 more
wiley +1 more source
A phosphorescent iridium(III) complex has been prepared with a 6‐hydrazinonicotinic acid (HYNIC) ligand tethered to a lysine‐ureido‐glutamatic acid pharmacophore, which binds to an enzyme, called prostate‐specific membrane antigen (PSMA), which is overexpressed in prostate cancer.
La'El Kimchi +6 more
wiley +1 more source
Organometallic Compounds of Copper(II) derived from some Dicarboxylic Acids
Mamta Singh, RAM NAYAN
openalex +2 more sources
Machine‐learning potentials are increasingly taking on the exploratory tasks of homogeneous catalysis, enabling rapid conformer sampling and reaction‐space mapping. However, when selectivity depends on subtle electronic effects, electronic‐structure methods remain essential.
Maxime Ferrer +3 more
wiley +1 more source

