Results 131 to 140 of about 20,886 (238)

Group 8 metallocenes as single-source precursors for the synthesis of light-element-stabilized FCC phases under extreme conditions. [PDF]

Sci Technol Adv Mater
Niwa K, Nakashima K, Kimura Y, Gaida NA, Sasaki T, Hasegawa M.   +5 more
europepmc   +1 more source

Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism

Chemistry – A European Journal, EarlyView.
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew, Daisy E. Cruz‐Milette, Douglas Turnbull, Paul G. Hayes   +3 more
wiley   +1 more source

Synthesis of sterically shielded piperidine nitroxides via acid-catalyzed heterocyclization of β-aminoketone derivatives with ketones. [PDF]

Beilstein J Org Chem
Gulman MM, Glazachev YI, Dobrynin SA.
europepmc   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

Chemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Asymmetric Decarboxylative Protonation and Deuteration of Cyanoacetic Acids Using an Organometallic Proton Shuttle. [PDF]

J Am Chem Soc
Zheng WF, Wu G, Hou M, Li K, Qi X, Huang Z.   +5 more
europepmc   +1 more source

VOCs Adsorption and Exchange Properties in Bispidine‐Based Mn(II) 1D CPs Made of Orthogonally Oriented Linear Chains

Chemistry – A European Journal, EarlyView.
Combining the chiral bispidine ligand L1 with MnCl2 affords coordination polymers (CPs) with an unusual topology for this family of compounds, consisting of orthogonally packed ribbon‐like one‐dimensional (1D) chains. Their behavior was investigated through single‐crystal‐to‐single‐crystal exchange with aromatic volatile organic compounds (VOCs) and ...
Meriem Goudjil, Martina Lippi, Sara Camorali, Chiara Pelosi, Alessandro Sayed, Luca Bernazzani, Patrizia Rossi, Paola Paoli, Massimo Cametti   +8 more
wiley   +1 more source

Stereoselective additions to alkenylphosphonium salts for the synthesis of P-stereogenic compounds. [PDF]

Chem Sci
Chen XB, Padín D, Feringa BL.
europepmc   +1 more source

Stepwise Synthesis of Tetrabenzotriazaporphyrins (TBTAPs) and Their Open 2‐ and 3‐Ring Fragments

Chemistry – A European Journal, EarlyView.
Unexpected reaction pathways to porphyrin‐phthalocyanine hybrids are uncovered by the synthesis of “half‐macrocycle” fragments and subsequent macrocyclization. Rather than the expected 2:2 “ABBA” product, the 3:1 “ABBB” hybrid is isolated as the only macrocyclic product.
Jacob Gretton, Ala Alturk, Sonia Remiro‐Buenamañana, Alejandro Díaz‐Moscoso, Amirah A. Aldawsari, Maha S. Albayaa, Isabelle Chambrier, David L. Hughes, Simon J. Coles, Graham J. Tizzard, Andrew N. Cammidge   +10 more
wiley   +1 more source

Nickel-Catalyzed Enantioconvergent Arylation of Unactivated Cyclic Electrophiles: Asymmetric Synthesis of 3-Substituted Pyrrolidines. [PDF]

Angew Chem Int Ed Engl
Wong THM, Tong X, Fu GC.
europepmc   +1 more source

Relay Approach: A Convergent Synthesis of Key Fragments en route to (+)‐Neosorangicin A

Chemistry – A European Journal, EarlyView.
A selective synthesis of three key fragments of the antibiotically active (+)‐neosorangicin A is reported, providing a foundation for its convergent total synthesis and proof of strategy via a relay approach. ABSTRACT Herein, we report the synthesis of the three key fragments of the macrolide antibiotic (+)‐neosorangicin A, a compound exhibiting potent
Marvin Wenninger, Maxim Munt, Le Chang, Rositsa Stoykova, Roberto Ojcius, Oliver Spieß, Dieter Schinzer   +6 more
wiley   +1 more source