Results 111 to 120 of about 20,841 (234)

Enhancing the Catalytic Activity of Pd Nanocatalysts for Anion Exchange Membrane Direct Ethanol Fuel Cells by Functionalizing Vulcan XC-72 with Cu Organometallic Compounds. [PDF]

open access: yesACS Appl Nano Mater
Meléndez-González PC   +7 more
europepmc   +1 more source

A Ruthenium‐(Ph‐BPE) Catalyst for Asymmetric Alkynylation of Fluoral: Enantioselection From 1 of 12 Fluxional Stereogenic‐at‐Ruthenium Complexes

open access: yesAngewandte Chemie International Edition, EarlyView.
The first enantioselective alkynylations of aqueous fluoral are described. These processes are catalyzed by an iodide‐bound ruthenium‐(Ph‐BPE)‐catalyst; an octahedral metal complex that can exist as 12 diastereomeric‐at‐metal isomers. Calculations reveal that 2 of 12 stereoisomeric complexes account for 99.9% of the Boltzmann population and that ...
Weijia Shen   +6 more
wiley   +1 more source

Evaluation of the Efficiency of a Biobased Reactive Plasticizer on the Morphology and Properties of Sustainable Flexible Films Based on Poly(Lactic Acid) (PLA) Produced by Blown Film Extrusion

open access: yesJournal of Applied Polymer Science, EarlyView.
A comparative investigation of two epoxy additives derived from cardanol (NC513 and NC514s) for production of films based on poly (lactic acid) (PLA), acetyl tributyl citrate (ATBC), and poly (butylene adipate‐co‐terephthalate) (PBAT) clarified their distinct roles, with NC513 mainly acting as a plasticizer, reducing viscosity and enhancing ductility ...
Norma Mallegni   +3 more
wiley   +1 more source

Additives Enhancing Biodegradability in Plastics and Potential Implications for Textiles: A Mechanistic Review

open access: yesJournal of Applied Polymer Science, EarlyView.
Mechanistic insights from additive‐assisted plastic degradation guide the design of environmentally adaptive textile fibers. Functional additives enhance oxidative, hydrolytic, enzymatic, and microbial degradation pathways. Translating these strategies requires control of fiber architecture, additive distribution, and environmental interactions ...
Julia Cunniffe   +2 more
wiley   +1 more source

Boosting Electron‐Hole Charge Separation in CO2 Photoreduction through Fluoroporphyrin‐Linked Nickel(II)‐Acetylide Frameworks

open access: yesCarbon Energy, EarlyView.
A NiII‐acetylide framework, H2TFPP‐Ni‐AF, demonstrates outstanding photocatalytic CO2 reduction performance: 13.16 mmol h−1 g−1 of CO with 97.9% selectivity. Synergistic interactions, including d‐p orbital hybridization within NiII‐bis(acetylide) moieties ( − C ≡ C−NiII(PBu3)2 − C ≡ C − ) and the efficient charge transport afforded by π‐conjugated ...
Lifen Chen   +6 more
wiley   +1 more source

Carbon‐Doped Amorphous Gallium Oxide Forms a Heterojunction With Water to Improve the Electrocatalytic Oxygen Evolution Reaction

open access: yesCarbon Energy, EarlyView.
A dynamic catalyst–H2O heterojunction (CWH) forms on ACG during OER, with periodic bubble evolution modulating band bending and interfacial charge transfer. Electron–radical coupling drives the generation of •OH/•O2− species, converting Ga2O3 into GaOOH, whereas surface CO32− from C doping stabilizes the interface, suppressing catalyst dissolution and ...
Ruijie Dai   +6 more
wiley   +1 more source

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