Concentration Effect over Thermoresponse Derived from Organometallic Compounds of Functionalized Poly(N-isopropylacrylamide-co-dopamine Methacrylamide). [PDF]
Polymers (Basel), 2021 Moral-Zamorano M +7 more
europepmc +1 more source
Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2
Angewandte Chemie, EarlyView.By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin +3 more
wiley +2 more sources
Angewandte Chemie, EarlyView.N‐heterocyclic carbenes (NHCs) function as “molecular scissors,” cleaving otherwise inert Sb═Sb bonds in distibenes to generate monomeric, zwitterionic stibinide species. These intermediates act as efficient stibinidene transfer reagents, granting access to a rare terminal cobalt–stibinidene complex.
Daniel Meleschko +7 more
wiley +2 more sources
Structural Aspects of Reactive Organometallic Compounds
CHIMIA, 1999 The structural chemistry and catalytic activity of palladium complexes with chiral or prochiral ligands and substrates has been investigated using a suite of techniques.
Silvia Schaffner +3 more
doaj +1 more source
Borylcyclopropanes: Synthetic Strategies and Applications
Angewandte Chemie, EarlyView.Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
Electric Field Enhancements and Hot Spots in Amorphous Carbon Materials
Small StructuresAmorphous carbon (a‐C) represents a broad and technologically relevant class of carbonaceous materials whose rich morphological diversity, characterized by nanoporosity and defective networks, endows them with unique electrical, chemical, and optical ...
Pablo Grobas Illobre +5 more
doaj +1 more source
Reactive force field simulations of silicon clusters
Advances in Physics: X, 2019 The fast and continuous growth of multidisciplinary approaches, consisting of the combination of various experimental techniques and computational methods tuned on purpose to depict and predict material properties and performance, is motivated by the ...
Giovanni Barcaro +3 more
doaj +1 more source
Remapping the Synthetic Landscape of α‐Tertiary Alkylamines via Dual‐Functional Catechol
Angewandte Chemie, EarlyView.A three‐component assembly strategy has been developed for the modular synthesis of hindered α‐tertiary aliphatic amines from readily available precursors through unlocking the dual role of catechol. The practicality of this methodology has been demonstrated in over 90 examples, including compounds that are otherwise difficult to access, along with ...
Chen‐Yan Cai, Yuzuru Kanda, Tian Qin
wiley +2 more sources
Bypassing the Resistance Mechanisms of the Tumor Ecosystem by Targeting the Endoplasmic Reticulum Stress Pathway Using Ruthenium- and Osmium-Based Organometallic Compounds: An Exciting Long-Term Collaboration with Dr. Michel Pfeffer. [PDF]
Molecules, 2021 Gaiddon C +9 more
europepmc +1 more source
Angewandte Chemie, EarlyView.A heterogeneous photocatalytic system has been developed that enables the dehydrogenative decarbonylation of primary alcohols under visible light using highly dispersed oxidic iron sites supported on aryl‐modified graphitic carbon nitride (Fe@f–gC3N4).
Jun Hu +11 more
wiley +2 more sources