A series of bio-organometallic-hydrazones of the general formula [{(η5-C5H4)-C(R)=N–N(H)-C6H4-4-SO2NH2}]MLn(MLn = Re(CO)3, Mn(CO)3, FeCp; R=H, CH3) were prepared by reaction of formyl/acetyl organometallic precursors with 4-hydrazino-benzenesulphonamide.
Jeremie Brichet +3 more
doaj +1 more source
Novel Tetrazine Organometallic Complexes for Nonlinear Optical Switching: a Combined Density Functional Theory and Experimental Study [PDF]
Over the past decade, mono- and bi- and oligonuclear organometallic complexes have been deal of great interest by material chemists and engineers due to their remarkable nonlinear optical (NLO), magnetic and electric properties. [1] They were furthermore
Mendes, Paulo J.
core
Fe-Si binary compounds have been fabricated by focused electron beam induced deposition by the alternating use of iron pentacarbonyl, Fe(CO)5, and neopentasilane, Si5H12 as precursor gases.
F. Porrati +5 more
core +1 more source
On the existence of collective interactions reinforcing the metal-ligand bond in organometallic compounds. [PDF]
Poater J +4 more
europepmc +1 more source
Reply to: On the existence of collective interactions reinforcing the metal-ligand bond in organometallic compounds. [PDF]
Šadek V +5 more
europepmc +1 more source
In many Pd‐catalyzed cross‐couplings, catalyst performance has been found to be limited by catalyst activation. Methylnaphthyl (MeNAP) palladium trifluoroacetate dimers are presented as easy‐to‐store and easy‐to‐handle precursors, which rapidly activate under reaction conditions, even when only weakly coordinating, non‐reducing nucleophiles are present.
Sourav Manna +6 more
wiley +1 more source
Understanding β-Hydride Eliminations from Heteroatom Functional Groups [PDF]
Using density functional theory, we investigated detailed aspects of the quintessential organometallic process, β-hydride elimination (BHE). In general, we find that most BHE processes from alkyl functional group β-atoms are facile, while BHE processes ...
Goddard, William A. III +1 more
core +1 more source
Characterization of selected organometallic compounds by electrospray ionization- and matrix-assisted laser desorption/ionization-mass spectrometry using different types of instruments: Possibilities and limitations. [PDF]
Fleissner S +3 more
europepmc +1 more source
Zur Chemie der siliciumorganischen Verbindungen
After briefly outlining the history of the chemistry of organo-silicon compounds this paper reports the formation of cyclic siliconmethylene compounds.
G. Fritz
doaj +1 more source
Dirhenium Carbonyl Complexes Bearing 2-Vinylpyridine, Morpholine and 1-Methylimidazole Ligands [PDF]
Treatment of the labile compound [Re2(CO)8(MeCN)2] with 2-vinylpyridine in refluxing benzene affords exclusively the new compound [Re2(CO)8(μ-η1:η2-NC5H4CHCH2)] (1) in 39% yield in which the μ-η1:η2-vinylpyridine ligand is coordinated to one Re atom ...
Ahmed, Faruque +7 more
core +1 more source

