Results 211 to 220 of about 78,326 (288)

Photoinduced Generation of (Boryl)Silyl and (Chloro)Silyl Radicals: Access to Trisubstituted Silylboranes and Chlorosilanes

Angewandte Chemie, Volume 138, Issue 13, 23 March 2026.
A versatile photoinduced hydro(boryl)silylation and hydro(chloro)silylation of alkenes to construct trisubstituted silylboranes and chlorosilanes was achieved through in situ generation of (boryl)silyl radicals or (chloro)silyl radicals. This mild methodology affords high chemoselectivity and broad functional group tolerance to enable direct access to ...
Mone Suzuki, Yuki Nagashima
wiley   +2 more sources

A Platinum (II) Polyyne Oligomers Donor for Efficient Ternary Organic Solar Cells

Solar RRL, Volume 10, Issue 6, 29 March 2026.
Platinum (II) polyyne oligomers P5 are used as a donor in a ternary organic solar cell. The average power conversion efficiency of 16% surpasses the international record for [Pt] (II) polyyne oligomers. PC71BM speeds up the rise time for electron transfer and slows down the recombination time.
Abdel Aziz Wayzani, Léo Boivin, Romuald Herbinet, Muriel Durandetti, Paul‐Ludovic Karsenti, Fabrice Muller, Christophe Sinturel, Loïc Le Pluart, Pierre D. Harvey, Ganesh D. Sharma, Cyprien Lemouchi   +10 more
wiley   +1 more source

Solvent-controlled, chemodivergent oxidative anionic Fries rearrangement of <i>O</i>-aryl carbamates under aerobic conditions. [PDF]

Chem Sci
Gnavi R, De Nardi F, Meazzo C, Ghinato S, Grimaldi E, Maranzana A, Prandi C, Blangetti M.   +7 more
europepmc   +1 more source

Organometallic Compound [PDF]

, 2020
openaire   +1 more source

On-surface synthesis platform for highly branched oligomers based on sequential C-C coupling and C-H activation of carbenes. [PDF]

Nat Commun
Cao Y, Mieres-Perez J, Rowen JF, Raut AH, Schweer P, Bao A, Sander W, Sanchez-Garcia E, Morgenstern K.   +8 more
europepmc   +1 more source

Inorganic Cobalt Sandwich Complex [(η⁵-P₅)Co(η³-P₃)]^. [PDF]

J Am Chem Soc
Trabitsch K, Ziegler CGP, Prock L, Balázs G, Schwedtmann K, García-Padilla E, Meurer F, Snabilié DD, de Bruin B, Weigand JJ, Wolf R.   +10 more
europepmc   +1 more source

Isolation and reactivity of sodium benzyl cations. [PDF]

Nat Commun
Kundu S, Raj K, Andrews AP, Rajeshkumar T, Maron L, Venugopal A.   +5 more
europepmc   +1 more source

Metal‐Free Scission of the NO+ Triple Bond

Angewandte Chemie International Edition, Volume 65, Issue 13, 23 March 2026.
Breaking bonds: The reaction between NO[Al(ORF)4] (RF = C(CF3)3) and the diphosphane PNPtBu (2,6‐bis(di‐tert‐butylphosphino‐methyl)pyridine) leads to the direct and complete cleavage of the NO+ triple bond, one of the strongest chemical bonds known. The mechanism of this reaction was studied using quantum chemical calculations and NMR spectroscopic ...
Julie Willrett, Harald Scherer, Burkhard Butschke, Ingo Krossing   +3 more
wiley   +1 more source

Coordination-Induced Spin Modulation: Overcoming Spin Blocking in C-H Methylation with High-Spin Ferrous Complexes. [PDF]

ACS Catal
Zhang T, Pecoraro MV, Chirik PJ.
europepmc   +1 more source

Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross‐Coupling

Angewandte Chemie, Volume 138, Issue 12, 16 March 2026.
Reductive cross‐couplings enable efficient C–C bond formation but are limited by the heterogeneity of Zn or costly reagents like TDAE. We report arylhydrazines as inexpensive, convenient reductants for Ni‐catalyzed sp2–sp3 coupling of aryl halides and secondary alkyl iodides. Mechanistic studies support hydrazine‐mediated NiII reduction for a NiI/NiIII
Nils Kurig, David A. Cagan, Kaid C. Harper, Yu Kawamata, Donna G. Blackmond, Phil S. Baran   +5 more
wiley   +2 more sources