Results 271 to 280 of about 84,401 (336)

O2‐Mediated Cu‐Catalyzed Dehydrogenative Sulfilimination of Tyrosines and Bioactive Phenols

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
We report herein the mild O2‐mediated Cu‐catalyzed dehydrogenative sulfilimination of diverse bioactive phenols with simple sulfenamides. The bioconjugation of unmodified native peptides, in particular at their tyrosine units with the dehydrogenative phenochalcogenazination reaction, has attracted much attention lately due to potential click type ...
Fang Xiao, Frederic W. Patureau
wiley   +1 more source

Isolation and reactivity of sodium benzyl cations. [PDF]

open access: yesNat Commun
Kundu S   +5 more
europepmc   +1 more source

Catalytic Enantioselective Synthesis of Conformationally Stable C(sp2)−C(sp3) Naphthocoumarin Atropisomers

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
The enantioselective synthesis of naphthocoumarin adducts via a tandem organocatalytic 1,4‐addition/decarboxylation delivers excellent control over a newly forged stereocenter and yields configurationally stable synclinal atropisomers. The process features broad substrate scope and scalability, and its structural and mechanistic foundations are ...
M. Chiara Cabua   +10 more
wiley   +1 more source

Inorganic Cobalt Sandwich Complex [(η<sup>5</sup>-P<sub>5</sub>)Co(η<sup>3</sup>-P<sub>3</sub>)]. [PDF]

open access: yesJ Am Chem Soc
Trabitsch K   +10 more
europepmc   +1 more source

Design, Synthesis, and Structural Analysis of Binaphthyl‐Based Chiral Benzindenes

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
This work explores the synthetic endeavors in constructing the first‐of‐a‐kind axially chiral benz[f]indenes as potential chiral ligands. The overall synthetic pathway spans across 9 steps with 15.9% overall yield. Challenges in constructing modified analogs as well as metal complexes are discussed. Chiral benzindenes are an unexplored structural motif
Marko Gobin, Nikola Topolovčan
wiley   +1 more source

Dearomatization with Axial‐to‐Central Chirality Conversion

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 17, 5 May 2026.
Atropisomers are exciting synthetic targets with unique properties, which find applications in many fields of chemistry. However, considering them as substrates is not very frequent, notably in the context of dearomatization reaction. We wish to discuss the different strategies for the dearomatization of aromatic atropisomers with axial‐to‐central ...
Morgane Mando   +3 more
wiley   +1 more source

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