O2‐Mediated Cu‐Catalyzed Dehydrogenative Sulfilimination of Tyrosines and Bioactive Phenols
We report herein the mild O2‐mediated Cu‐catalyzed dehydrogenative sulfilimination of diverse bioactive phenols with simple sulfenamides. The bioconjugation of unmodified native peptides, in particular at their tyrosine units with the dehydrogenative phenochalcogenazination reaction, has attracted much attention lately due to potential click type ...
Fang Xiao, Frederic W. Patureau
wiley +1 more source
Isolation and reactivity of sodium benzyl cations. [PDF]
Kundu S +5 more
europepmc +1 more source
The enantioselective synthesis of naphthocoumarin adducts via a tandem organocatalytic 1,4‐addition/decarboxylation delivers excellent control over a newly forged stereocenter and yields configurationally stable synclinal atropisomers. The process features broad substrate scope and scalability, and its structural and mechanistic foundations are ...
M. Chiara Cabua +10 more
wiley +1 more source
Inorganic Cobalt Sandwich Complex [(η<sup>5</sup>-P<sub>5</sub>)Co(η<sup>3</sup>-P<sub>3</sub>)]. [PDF]
Trabitsch K +10 more
europepmc +1 more source
Design, Synthesis, and Structural Analysis of Binaphthyl‐Based Chiral Benzindenes
This work explores the synthetic endeavors in constructing the first‐of‐a‐kind axially chiral benz[f]indenes as potential chiral ligands. The overall synthetic pathway spans across 9 steps with 15.9% overall yield. Challenges in constructing modified analogs as well as metal complexes are discussed. Chiral benzindenes are an unexplored structural motif
Marko Gobin, Nikola Topolovčan
wiley +1 more source
Electronic spectroscopy and spin-orbit coupling of organometallic compounds
Houari Brahim +2 more
openalex +1 more source
Ferrocenyl ferroptosis inducers as an emerging class of anticancer agents: a mini review. [PDF]
Klarek M, Gautam A, Kowalski K.
europepmc +1 more source
Dearomatization with Axial‐to‐Central Chirality Conversion
Atropisomers are exciting synthetic targets with unique properties, which find applications in many fields of chemistry. However, considering them as substrates is not very frequent, notably in the context of dearomatization reaction. We wish to discuss the different strategies for the dearomatization of aromatic atropisomers with axial‐to‐central ...
Morgane Mando +3 more
wiley +1 more source
Coordination-Induced Spin Modulation: Overcoming Spin Blocking in C-H Methylation with High-Spin Ferrous Complexes. [PDF]
Zhang T, Pecoraro MV, Chirik PJ.
europepmc +1 more source
Magnetic hysteresis in 1D organometallic lanthanide chain compounds containing 4,4'-bipyridine. [PDF]
Castellanos E +3 more
europepmc +1 more source

