Mechanically Robust Mesoporous UiO‐66‐NH2/Nanofibrous Aerogel for Organophosphonates Detoxification [PDF]
There is a critical need for novel composite materials for high‐performance chemical filtration and detoxification of organophosphonates (OPs) and other harmful compounds found in nerve agents, pesticides, and industrial processes.
Mai O. Abdelmigeed +6 more
doaj +4 more sources
Limitations of the molybdenum blue method for phosphate quantification in the presence of organophosphonates. [PDF]
Organophosphonates (OPs) are widely used as chelating agents in domestic and industrial applications. While regarded as hardly biodegradable, OPs can undergo abiotic transformation with phosphate (PO43−) as a main transformation product.
Guo R +3 more
europepmc +2 more sources
The Synthesis and Evaluation of Diethyl Benzylphosphonates as Potential Antimicrobial Agents [PDF]
The impact of substituent at phenyl ring of diethyl benzylphosphonate derivatives on cytotoxic activity was studied. The organophosphonates were obtained based on developed palladium-catalyzed α, β-homodiarylation of vinyl esters protocol.
Anna Brodzka +8 more
doaj +2 more sources
Reversible Diels–Alder Reactions with a Fluorescent Dye on the Surface of Magnetite Nanoparticles [PDF]
Diels–Alder reactions on the surface of nanoparticles allow a thermoreversible functionalization of the nanosized building blocks. We report the synthesis of well-defined magnetite nanoparticles by thermal decomposition reaction and their ...
Siyang He, Guido Kickelbick
doaj +3 more sources
Short Naphthalene Organophosphonate Linkers to Microporous Frameworks [PDF]
Abstract We report two novel 3D porous metal‐organophosphonate metal organic frameworks (MOFs) [{Cu(4, 4’‐bpy) 0.5 (1,4‐NDPA‐H 2 )] ( 1 ), [{Cu 2 (4,4’‐bpy)
Aysun Bulut +8 more
openaire +6 more sources
Biodegradation of Organophosphonates by Aspergillus Specie
The utilization of organophosphonates as sole source of phosphorus by Aspergillusniger was studied. Aspergillusniger was found to utilize the phosphorus in diethylethylphosphonate, 2aminoethylphosphonate and potassium hydrogen phosphate for its growth ...
F. Adelowo +4 more
semanticscholar +2 more sources
Organophosphorus flame retardants in children’s car seats: Implications for vehicle air quality [PDF]
Flame retardants (FRs) are used in many consumer products for fire safety reasons. Their use in children’s car seats may result in children’s and vehicle occupants’ exposure to these compounds including inhalation exposure through poor vehicle air ...
Zhu Jiping, Das Dharani
doaj +1 more source
Semiconductive microporous hydrogen-bonded organophosphonic acid frameworks [PDF]
Abstract Herein, we report a semiconductive, proton-conductive, microporous hydrogen-bonded organic framework (HOF) derived from phenylphosphonic acid and 5,10,15,20‐tetrakis[ p ‐phenylphosphonic acid] porphyrin (GTUB5).
Patrik Tholen +12 more
openaire +5 more sources
Metal organophosphonates have been explored in energy-related fields due to their high chemical and thermal stability as a type of uniformly precursor, but only few of pristine metal organophosphonate are directly used for oxygen evolution reaction (OER)
Juan-Juan Hou +4 more
doaj +1 more source
Structure of HI-6*sarin-acetylcholinesterase determined by X-ray crystallography and molecular dynamics simulation: reactivator mechanism and design. [PDF]
Organophosphonates such as isopropyl metylphosphonofluoridate (sarin) are extremely toxic as they phosphonylate the catalytic serine residue of acetylcholinesterase (AChE), an enzyme essential to humans and other species.
Fredrik Ekström +5 more
doaj +1 more source

