Results 31 to 40 of about 4,190 (237)

A Simple and Versatile Approach for the Low‐Temperature Synthesis of Transition Metal Phosphide Nanoparticles from Metal Chloride Complexes and P(SiMe3)3

open access: yesAdvanced Materials, Volume 35, Issue 49, December 7, 2023., 2023
Metal phosphide nanoparticles are prepared under mild conditions following a synthetic approach involving the reaction of metal chloride complexes with tris(trimethylsilyl)phosphine. The formation of Si–Cl bonds in the by‐product SiClMe3 acts as a driving force for the reaction.
Alexandre Sodreau   +10 more
wiley   +1 more source

Anaerobic dissimilatory phosphite oxidation, an extremely efficient concept of microbial electron economy

open access: yesEnvironmental Microbiology, Volume 25, Issue 11, Page 2068-2074, November 2023., 2023
Anaerobic oxidation of phosphite is a very economic way to supply bacteria with both ATP and electrons for assimilation of CO2 into cell material at high growth yields. Abstract Phosphite is a stable phosphorus compound that, together with phosphate, made up a substantial part of the total phosphorus content of the prebiotic Earth's crust. Oxidation of
Zhuqing Mao   +4 more
wiley   +1 more source

Structural basis of the chiral selectivity of Pseudomonas cepacia lipase [PDF]

open access: yes, 1998
To investigate the enantioselectivity of Pseudomonas cepacia lipase, inhibition studies were performed with SC- and RC-(RP,SP)-1,2-dialkylcarbamoylglycero-3-O-p-nitrophenyl alkylphosphonates of different alkyl chain lengths. P.
Dijkstra, Bauke W.,   +4 more
core   +2 more sources

Steric Control over the Threading of Pyrophosphonates with One or Two Cyanostar Macrocycles during Pseudorotaxane Formation

open access: yesChemistry – A European Journal, Volume 29, Issue 41, July 20, 2023., 2023
Control over the binding stoichiometry and the threading kinetics is achieved in pseudorotaxanes comprising the anion‐binding cyanostar macrocycle and organic pyrophosphonates with fine‐tuned steric bulk. The approach allowed the selective assembly of [3]pseudorotaxanes and [2]pseudorotaxanes, and it provided insights that are valuable for future work ...
Julian Vogel   +4 more
wiley   +1 more source

Diphosphoryl‐functionalized Polyoxometalates: Structurally and Electronically Tunable Hybrid Molecular Materials

open access: yesAngewandte Chemie, Volume 135, Issue 23, June 5, 2023., 2023
The synthesis and characterization of a new class of hybrid diphosphoryl Wells–Dawson polyoxometalate (POM) is described. The covalent tethering of diphosphoryl compounds to the inorganic cluster gives redox‐active materials with enhanced hydrolytic stability compared to the corresponding phosphonate analogues.
Sharad S. Amin   +11 more
wiley   +1 more source

Respuesta del perifiton de agua dulce al glifosato grado-técnico y dos formulados comerciales [PDF]

open access: yes, 2019
El glifosato es el herbicida más utilizado a nivel mundial. Puede llegar a los cuerpos de agua y afectar a las comunidades microbianas. Comparamos los efectos del glifosato grado técnico y dos formulados comerciales sobre una comunidad periférica de agua
Gonzalez, Daniela   +4 more
core   +1 more source

Widespread known and novel phosphonate utilization pathways in marine bacteria revealed by functional screening and metagenomic analyses [PDF]

open access: yes, 2010
Phosphonates (Pn), compounds with a direct C–P bond instead of the more common C–O–P ester bond, constitute a significant fraction of marine dissolved organic phosphorus and recent evidence suggests that they may be an alternative source of P for marine ...
Altschul   +66 more
core   +1 more source

Diversity and abundance of phosphonate biosynthetic genes in nature [PDF]

open access: yes, 2013
Phosphonates, molecules containing direct carbon–phosphorus bonds, compose a structurally diverse class of natural products with interesting and useful biological properties.
Circello, Benjamin   +7 more
core   +1 more source

An HD domain phosphohydrolase active site tailored for oxetanocin-A biosynthesis [PDF]

open access: yes, 2016
HD domain phosphohydrolase enzymes are characterized by a conserved set of histidine and aspartate residues that coordinate an active site metallocenter. Despite the important roles these enzymes play in nucleotide metabolism and signal transduction, few
Drennan, Catherine L.   +4 more
core   +1 more source

Nickel(II) 3,4;9,10-Perylenediimide bis-Phosphonate Pentahydrate: A Metal−Organic Ferromagnetic Dye [PDF]

open access: yes, 2012
The new metal−organic compound nickel(II) 3,4;9,10- perylenediimide bis-phosphonate pentahydrate, i.e. Ni2[(PDI-BP)- (H2O)2]·3H2O (1), has been synthesized and its structural and magnetic properties have been studied.
Bauer, EM   +6 more
core   +1 more source

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