Results 31 to 40 of about 20,271 (220)

The Backbone of Success of P,N-Hybrid Ligands: Some Recent Developments

open access: yesMolecules, 2022
Organophosphorus ligands are an invaluable family of compounds that continue to underpin important roles in disciplines such as coordination chemistry and catalysis.
Martin B. Smith
doaj   +1 more source

Multicomponent reactions: A simple and efficient route to heterocyclic phosphonates

open access: yesBeilstein Journal of Organic Chemistry, 2016
Multicomponent reactions (MCRs) are one of the most important processes for the preparation of highly functionalized organic compounds in modern synthetic chemistry. As shown in this review, they play an important role in organophosphorus chemistry where
Mohammad Haji
doaj   +1 more source

Organophosphorus Chemistry: Synthesis of New Phosphonic Acid Derivatives Bearing a Triazole Moiety

open access: yesChemistry Proceedings, 2022
A series of new 1,2,3-triazolylphosphonates were synthesized through multicomponent alkyne-azide 1,3-dipolar cycloaddition catalyzed by copper nanoparticles on activated carbon.
Esteban Bjerg   +4 more
doaj   +1 more source

Complexation of lithium and sodium cations with B-phosphorylate ethers, modelling terminal groups of organophosphorus podands. An experimental and theoretical study [PDF]

open access: yes, 1992
The organophosphorus compounds o-Ph2P(O)C6H4OCH3 and Ph2P(O)C2H4OCH3, which are analogs of podands' terminal groups, have been synthesized. The thermodynamic characteristics of their complexation with LiNCS and NaNCS in acetonitrile were obtained by ...
Baulin, V.E.   +5 more
core   +3 more sources

Solvent and solvation effects on reactivities and mechanisms of phospho group transfers from phosphate and phosphinate esters to nucleophiles

open access: yesFrontiers in Chemistry, 2023
Organophosphorus esters fulfil many industrial, agricultural, and household roles. Nature has deployed phosphates and their related anhydrides as energy carriers and reservoirs, as constituents of genetic materials in the form of DNA and RNA, and as ...
Ikenna Onyido   +3 more
doaj   +1 more source

Multicomponent Synthesis of Potentially Biologically Active Heterocycles Containing a Phosphonate or a Phosphine Oxide Moiety

open access: yesActa Chimica Slovenica, 2022
Several multicomponent synthetic approaches were elaborated for plenty of novel nitrogen or oxygen heterocycles containing a phosphonate or a phosphine oxide moiety.
Nóra Popovics-Tóth, Erika Bálint
doaj   +1 more source

Synthesis and characterisation of ferrocenyl-phosphonic and -arsonic [PDF]

open access: yes, 2001
The ferrocene-derived acids FcCH₂CH₂E(O)(OH)₂ [4, E=P; 10, E=As; Fc=Fe(η₅-C₅H₅)(η⁵-C₅H₄)] have been synthesized by the reaction of FcCH₂CH₂Br with either P(OEt)₃ followed by hydrolysis, or with sodium arsenite followed by acidification.
Alley, Steven R., Henderson, William
core   +2 more sources

Stoichiometric and Catalytic Synthesis of Alkynylphosphines

open access: yesMolecules, 2012
Alkynylphosphines or their borane complexes are available either through C–P bond forming reactions or through modification of the phosphorus or the alkynyl function of various alkynyl phosphorus derivatives.
Annie-Claude Gaumont   +3 more
doaj   +1 more source

NEW PHOSPHORUS COMPOUNDS K[PCL3(X)] (X= SCN, CN): PREPARATION AND DFT AND SPECTROSCOPIC STUDIES [PDF]

open access: yes, 2016
Indexación: Web of Science. Scielo.Two new phosphorus complexes, potassium trichlorothiocyanophosphate (III) (PTCTCP; K[PCl3(SCN)]) and potassium trichlorocyanophosphate (III) (PTCCP; K[PCl3(CN)]) were synthesized from the reaction of KSCN and KCN ...
GERLI–CANDIA, LORENA   +4 more
core   +3 more sources

First DMAP-mediated direct conversion of Morita–Baylis–Hillman alcohols into γ-ketoallylphosphonates: Synthesis of γ-aminoallylphosphonates

open access: yesBeilstein Journal of Organic Chemistry, 2016
An efficient synthesis of a series of γ-ketoallylphosphonates through a direct conversion of both primary and secondary Morita–Baylis–Hillman (MBH) alcohols by trialkyl phosphites with or without DMAP, used as additive, and under solvent-free conditions,
Marwa Ayadi   +3 more
doaj   +1 more source

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