Esterase 2 as a Fluorescent Biosensor for the Detection of Organophosphorus Compounds: Docking and Electronic Insights from Molecular Dynamics [PDF]
Organophosphorus compounds (OP) are mainly used in agriculture as pesticides. Unfortunately, each year many rural workers die intoxicated by those compounds. Sometimes the diagnosis of the exact molecule that caused the intoxication can be tardy. In this
Tanos C.C., França +2 more
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The α-amidoalkylating properties of 1-(N-acylamino)alkyltriarylphosphonium salts with weakened Cα-P+ bond strength are discussed and examined.
Jakub Adamek +4 more
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‘User-friendly’ primary phosphines and an arsine: synthesis and characterization of new air-stable ligands incorporating the ferrocenyl group [PDF]
Reaction of FcCH₂CH₂P(O)(OH)₂ or FcCH₂P(O)(OH)(OEt) [Fc=Fe(η⁵-C₅H₄)(η⁵-C₅H₅)] with excess CH₂N₂ followed by reduction with Me₃SiCl–LiAlH₄ gives the air-stable primary phosphines FcCH₂CH₂PH₂ and the previously reported analogue FcCH₂PH₂ in high yields ...
Alley, Steven R., Henderson, William
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Zero-field NMR J-Spectroscopy of Organophosphorus Compounds [PDF]
In this paper, we report the results of theoretical and experimental studies on basic organophosphorus compounds using zero-field NMR, where spin dynamics are investigated in the absence of a magnetic field with the dominant heteronuclear J-coupling. We
Piotr, Put +3 more
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The Backbone of Success of P,N-Hybrid Ligands: Some Recent Developments
Organophosphorus ligands are an invaluable family of compounds that continue to underpin important roles in disciplines such as coordination chemistry and catalysis.
Martin B. Smith
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Organophosphorus Chemistry: Synthesis of New Phosphonic Acid Derivatives Bearing a Triazole Moiety
A series of new 1,2,3-triazolylphosphonates were synthesized through multicomponent alkyne-azide 1,3-dipolar cycloaddition catalyzed by copper nanoparticles on activated carbon.
Esteban Bjerg +4 more
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Multicomponent reactions: A simple and efficient route to heterocyclic phosphonates
Multicomponent reactions (MCRs) are one of the most important processes for the preparation of highly functionalized organic compounds in modern synthetic chemistry. As shown in this review, they play an important role in organophosphorus chemistry where
Mohammad Haji
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Organophosphorus esters fulfil many industrial, agricultural, and household roles. Nature has deployed phosphates and their related anhydrides as energy carriers and reservoirs, as constituents of genetic materials in the form of DNA and RNA, and as ...
Ikenna Onyido +3 more
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Gene Expression Modifications by Temperature-Toxicants Interactions in Caenorhabditis elegans [PDF]
Although organophosphorus pesticides (OP) share a common mode of action, there is increased awareness that they elicit a diverse range of gene expression responses.
Vinuela Rodriguez, A. +14 more
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Stoichiometric and Catalytic Synthesis of Alkynylphosphines
Alkynylphosphines or their borane complexes are available either through C–P bond forming reactions or through modification of the phosphorus or the alkynyl function of various alkynyl phosphorus derivatives.
Annie-Claude Gaumont +3 more
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