Results 31 to 40 of about 3,500 (175)
Chelating and Bridging Roles of 2-(2-Pyridyl)benzimidazole and Bis(diphenylphosphino)acetylene in Stabilizing a Cyclic Tetranuclear Platinum(II) Complex. [PDF]
, 2019 The reaction of complex [Pt(Me)(DMSO)(pbz)], 1, (pbz = 2-(2-pyridyl)benzimidazolate) with [PtMe(Cl)(DMSO)2], B, followed by addition of bis(diphenylphosphino)acetylene (dppac), gave the novel tetranuclear platinum complex [Pt4Me4(μ-dppac)2(pbz)2Cl2], 2 ...
Abu-Omar, Mahdi M +6 more
core
European Journal of Inorganic Chemistry, Volume 28, Issue 24, August 29, 2025.A free radical chain reaction occurs for the oxidation of PhPtII(NCN) by diiodine in benzene (NCN = [2,6‐bis{(dimethylamino)methyl}phenyl‐N,C,N]−). Initiation provides [PhPtIII(NCN)]• from PhPtII(NCN)(η1‐I2), followed by formation of binuclear species [PhPt(NCN)Pt–I···I–PtPh(NCN)I]• that undergo internal electron transfer to form cis‐PhPtIV(NCN)I2 and ...
Allan J. Canty +2 more
wiley +1 more source
Single‐Molecule Multi‐Channel Conductance Assisted by Through‐Space Conjugation
SmartMat, Volume 6, Issue 3, June 2025.Through‐space (TS) conjugation has been recognized as an effective charge transport channel in molecular electronics. In‐depth understanding of functions and mechanisms of TS channels in multi‐channel circuits is of high importance. This review introduces advances in charge transport systems from a molecular topology perspective, focusing on multi ...
Shaoxin Song +4 more
wiley +1 more source
Chemistry – A European Journal, Volume 31, Issue 26, May 8, 2025.Macro‐cycling into the near‐infrared: By incorporating two cyclometallated Pt(II) units into opposite sides of a molecular rectangle, the formation of near‐infrared‐emitting excited states that span the two units is promoted in solution, compared to the corresponding, acyclic, tweezer‐like complexes. A degree of molecular reorganization is nevertheless
Rebecca J. Salthouse +4 more
wiley +1 more source
Cyclometalated Iminophosphorane Gold(III) and Platinum(II) Complexes. A Highly Permeable Cationic Platinum(II) Compound with Promising Anticancer Properties [PDF]
, 2015 New organometallic gold(III) and platinum(II) complexes containing iminophosphorane ligands are described. Most of them are more cytotoxic to a number of human cancer cell lines than cisplatin.
Bermejo, Marival +10 more
core +2 more sources
Rational Design of Palladium and Platinum Chemosensors for Bio‐Applications
Advanced Sensor Research, Volume 4, Issue 2, February 2025.Precious group 10 d‐block metals, particularly palladium, and platinum, are widely utilized in various industries. However, their widespread use comes at a cost with potentially adverse effects to human health and the environment. This review which surveys the chemosensing mechanism and practical applications of palladium and platinum sensor probes ...
Daniel Nnaemaka Tritton +5 more
wiley +1 more source
European Journal of Inorganic Chemistry, Volume 27, Issue 26, September 11, 2024.Mobility of diiodine (I2) over the pincer plane is elucidated by DFT for the interaction of I2 with Pt(NCN)I (NCN=2,6‐bis(dimethylamino)methyl)}phenyl‐N,C,N]−) in dichloromethane. A ′I ⋅ Pt ⋅ I−I′ three‐centred transition state across the Pt−I bond enables movement of I2 from a ′Pt−I ⋅ ⋅ ⋅ I2′ motif to a ′Pt(η1‐I2)′ motif, and transient interaction ...
Allan J. Canty, Gerard van Koten
wiley +1 more source
Organoplatinum‐Mediated Synthesis of Cyclic pi‐Conjugated Molecules [PDF]
, 2014 Considerable interest has been recently focused on hoop‐shaped π‐conjugated molecules because of their great potentials in molecular electronics. In particular, cycloparaphenylenes (CPPs), consist of para‐linked phenylene unit in a cyclic manner, have ...
Yamago, Shigeru
core
Supramolecular Coordination Complexes as Optical Biosensors [PDF]
, 2021 In recent years, luminescent supramolecular coordination complexes (SCCs), including 2D-metallacycles and 3D-metallacages have been utilised for biomolecular analysis.
Dey, N, Haynes, CJE
core
Polymer Engineering &Science, Volume 64, Issue 6, Page 2476-2490, June 2024.A cogent formulation study is described to optimize direct ink writing 3D printing with the right Ink gel kinetics and curing for large‐scale DIW manufacturing. The thermal, thermo‐mechanical, dielectric stability properties of DIW 3D printed parts are reported.
G. M. Fazley Elahee +6 more
wiley +1 more source