Results 61 to 70 of about 1,540 (187)

Copper catalyzed cross-coupling reactions of diaryl ditellurides with potassium aryltrifluoroborate salts [PDF]

open access: yes, 2009
We present here results of the cross-coupling reaction of diaryl ditellurides with potassium aryltrifluoroborate salts using a catalytic amount of Cu(OAc)2 and bypiridine in DMSO/H2O under air atmosphere.
ALVES, Diego   +5 more
core   +2 more sources

Halogen, Chalcogen, Pnictogen, and Tetrel Bonding in Non‐Covalent Organocatalysis: An Update

open access: yesAngewandte Chemie International Edition, Volume 63, Issue 31, July 29, 2024.
Recent developments on the use of non‐transient non‐covalent interactions based on elements of groups 14–17 in organic synthesis and organocatalysis are discussed. While halogen and chalcogen bonding are now clearly established in this area, applications of pnictogen and particularly tetrel bonding are only starting to emerge.
Dragana Jovanovic   +2 more
wiley   +1 more source

Diphenyl Ditelluride Intoxication Triggers Histological Changes in Liver, Kidney, and Lung of Mice

open access: yesAnalytical Cellular Pathology, 2015
Tellurium compounds may be cytotoxic to different cells types. Thus, this work evaluated the effect of diphenyl ditelluride ((PhTe)2), an organotellurium commonly used in organic synthesis, on the morphology of liver, kidney, and lung.
Sônia Cristina Almeida da Luz   +7 more
doaj   +1 more source

The Electrochemical Oxidation of Organic Selenides and Selenoxides [PDF]

open access: yes, 1997
The electrochemical oxidation of alkyl and aryl selenides was investigated in acetonitrile. The oxidation of diphenyl selenide and di(4‐methylphenyl) selenide led primarily to the formation of their respective selenoxides, which were identified by ...
Hack, Michael   +2 more
core   +1 more source

A Novel and General Method for the Formation of S-Aryl, Se-Aryl, and Te-Aryl Phosphorochalcogenoates [PDF]

open access: yes, 2009
A new and general method for the synthesis of S-, Se-, and Te-aryl phosphorochalcogenoates (chalcogenophosphates) has been developed. S-P, Se-P, and Te-P bonds were formed by the coupling of readily available dialkyl phosphites with diaryl ...
Cao, Yu   +4 more
core   +1 more source

A Highly Sterically Encumbered Boron Lewis Acid Enabled by an Organotellurium‐Based Ligand

open access: yesChemistry – A European Journal, Volume 30, Issue 36, June 25, 2024.
The new boron Lewis acid B[OTeF3(C6F5)2]3 combines one of the most sterically encumbered boron centres with a Lewis acidity comparable to that of B(C6F5)3. It additionally provides ligand transfer reactivity towards fluoride compounds as shown in the synthesis of an Au(III) complex and a hypervalent iodine species. Abstract Lewis acidic boron compounds
Daniel Wegener   +5 more
wiley   +1 more source

The limits of precision monomer placement in chain growth polymerization [PDF]

open access: yes, 2016
Precise control over the location of monomers in a polymer chain has been described as the ‘Holy Grail’ of polymer synthesis. Controlled chain growth polymerization techniques have brought this goal closer, allowing the preparation of multiblock ...
Gody, Guillaume   +3 more
core   +1 more source

Aggregation‐induced emission polymers via reversible‐deactivation radical polymerization

open access: yesAggregate, Volume 5, Issue 1, February 2024.
Aggregation‐induced emission (AIE) active polymers have a wide range of practical applications, and one of the important methods for the design and synthesis of AIE polymers is the use of reversible‐deactivation radical polymerization (RDRP) techniques.
Nicholas Kai Shiang Teo   +3 more
wiley   +1 more source

Laser Photolysis and Thermolysis of Organic Selenides and Tellurides for Chemical Gas-phase Deposition of Nanostructured Materials

open access: yesMolecules, 2009
Laser radiation-induced decomposition of gaseous organic selenides and tellurides resulting in chemical deposition of nanostructured materials on cold surfaces is reviewed with regard to the mechanism of the gas-phase decomposition and properties of the ...
Josef Pola, Akihiko Ouchi
doaj   +1 more source

Suspension Photopolymerization of Methyl Methacrylate and ATRP Grafting of Thermo‐Responsive Polymers Using a Perylediimide Derivative Photoinitiator

open access: yesMacromolecular Materials and Engineering, Volume 309, Issue 2, February 2024.
A perylene diimide derivative is synthesized and used as photoinitiator for atom transfer radical polymerization of methyl methacrylate. Surface‐initiated polymerization confirms the controlled characteristic by exploiting the presence of terminal bromine on the surface of the particles obtained by suspension.
Aurel Diacon   +7 more
wiley   +1 more source

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