Reactions of 2,6‐dipicolinoylbis(N,N‐diethylthiourea) (H2LEt) with common tellurium(IV) starting materials such as PhTeBr3 or TeBr4 yield various tellurium(IV) and tellurium(II) compounds depending on the conditions applied.
S. S. dos Santos +6 more
semanticscholar +2 more sources
Synthesis, antimicrobial activity, computational and modeling studies of some new organotellurium compounds containing azo moities [PDF]
A new series of organonotellurium compounds containing azo groups were prepared by new and convenient methods. Reaction of 1-(4-mercuric chloride-2,3-dichlorophenyl)-2-chloro diazine (4) with 8-hydroxyquinoline (5) gave the new organomercury compound 6 ...
Al-Asadi, Rafid Hmedan +3 more
core +2 more sources
Molecular structure, vibrational spectroscopic and HOMO/LUMO studies of some organotellurium compounds by quantum chemical investigations [PDF]
Quantum mechanical calculations of geometries, energies and vibrational frequencies of organic mercury and tellurium compounds containing azomethine group, molecules a1-a5 and containing azo group, molecules a6-a10 have been undertaken using density ...
Al-Asadi, Rafid Hmedan +2 more
core +2 more sources
Cytotoxic, Genotoxic, and Mutagenic Effects of Organotellurane RF07 in Female Swiss Mice (Mus musculus). [PDF]
ABSTRACT The organotellurane RF07 (RF07) is an organic compound containing tellurium, a rare semi‐metal, and its leishmanicidal and antimalarial activity has already been reported in previous studies. This study evaluated the toxic effects of RF07 at 0.42, 21.37, and 42.75 mg/kg using comet assay, micronucleus test, and hematological/biochemical tests ...
de Jesus FEA +16 more
europepmc +2 more sources
Chalcogen-Guided Control of Azoarene Photoswitching: Tuning Excited-State Energies Through Electronic Property Modulation. [PDF]
Photophysical properties of ortho‐tellurium‐substituted azoarenes are tunable via aryl substituent electronics and tellurium oxidation state. Electron‐donating groups destabilize the excited state three‐electron σ bond, enhancing photoisomerization.
Scheller ZN +3 more
europepmc +2 more sources
The aim of the current study is to prepare organomercury and organotellurium compounds containing amino groups such as [1,1'-biphenyl]-4-amine and their derivatives by a mercuriation reaction.
Gofran Safi Mokhtar +1 more
doaj +1 more source
Dihalogens Binding and Activation by Imidazoline-2-Chalcogenone Model Derivatives: Insight from a Computational Approach. [PDF]
1,3‐dimethyl‐4‐imidazoline‐2‐chalcogenones react with dihalogens, initially forming a charge‐transfer (CT) adduct, which may evolve to the most stable T‐shaped hypercoordinate (TY) species. However, in silico results show that the CT adduct is more stable than the corresponding TY species for the sulfur and iodine combination.
Zeppilli D +5 more
europepmc +2 more sources
Maleic Anhydride and Its Derivatives: A Brief Review of Reactivity and Properties in Radical (Co)Polymerizations. [PDF]
Maleic anhydride (MAnh) and its derivatives are underutilized monomer classes, each with unique reactivities and properties, which afford the synthesis of highly functional (co)polymers. This review explores the current understanding, opportunities, and limitations associated with maleic anhydride and its derivatives in conventional radical and ...
Smith MP, Klumperman B.
europepmc +2 more sources
The present study involved the preparation of organomercury and organotellurium compounds derived from camphor and (2-amino-5-methylphenyl) mercury (II) chloride and their derivatives by a condensation reaction.
N. Al-Saadawy
semanticscholar +1 more source
The Cellular Thioredoxin-1/Thioredoxin Reductase-1 Driven Oxidoreduction Represents a Chemotherapeutic Target for HIV-1 Entry Inhibition. [PDF]
BACKGROUND:The entry of HIV into its host cell is an interesting target for chemotherapeutic intervention in the life-cycle of the virus. During entry, reduction of disulfide bridges in the viral envelope glycoprotein gp120 by cellular oxidoreductases is
Kathrin Reiser +9 more
doaj +1 more source

