New Schiff bases 5-iodo-indol-2,3-dionehydrazinecarboxamide (L1H) and 5-iodo-indol-2,3-dionehydrazinecarbothioamide (L2H) and their organotin(IV) complexes have been synthesized. The biologically potent ligands interacted with the Sn(IV) metal ion in 1:1
Sharma Swati +3 more
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A novel compound of triphenyltin(IV) with N-tert-butoxycarbonyl-L-ornithine causes cancer cell death by inducing a p53-dependent activation of the mitochondrial pathway of apoptosis [PDF]
The triphenyltin(IV) compound with N-tert-butoxycarbonyl-L-ornithine (Boc-Orn-OH), [Ph3Sn(Boc-Orn-O)], was synthesized and characterized by elemental analysis, FT-IR, solution1H,13C and119Sn NMR and ESI mass spectrometry.
Attanzio, A. +8 more
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Amino acetate functionalized Schiff base organotin(IV) complexes as anticancer drugs: synthesis, structural characterization, and in vitro cytotoxicity studies [PDF]
Summary: Potassium 2-{[(2Z)-(3-hydroxy-1-methyl-2-butenylidene)]amino}-4-methyl-pentanoate (L1HK) and potassium 2-{[(E)-1-(2-hydroxyphenyl)alkylidene]amino}-4-methyl-pentanoates (L2HK-L3HK) underwent reactions with PhnSnCl4-n (n = 2 and 3) to give the ...
Basu Baul, Tushar +3 more
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Redox-active cytotoxic diorganotin(IV) cycloalkylhydroxamate complexes with different ring sizes: Reduction behaviour and theoretical interpretation [PDF]
Two series of new diorganotin(IV) cycloalkylhydroxamate complexes with different ring sizes (cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl), formulated as the mononuclear [R2Sn(HL)(2)] (1:2) (a, R=Bu-n and Ph) and the polymeric [R2SnL](n) (1:1) (b,
Alegria, Elisabete +5 more
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In this paper we report the metallization in situ of (E)-4-((4-nitrobenzylidene) amino) phenol (ENBA), an organotin compound of this radical with Sn(IV) ions electrogenerated from a sacrificial tin anode in an electrochemical cell. This metallization was
L.M. Blanco Jerez +4 more
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Structure of a seven-coordinated tin(IV)-hydrazone complex [PDF]
Dichloro[2,6-diacetylpyridine bis(picolinoylhydrazonato)] tin(IV) monohydrate, [Sn(C21-H17N7O2)Cl2].H2O, Mr= 607.02, monoclinic, P21/c, a = 8.485 (5), b = 14.476 (6), c = 19.533 (12) Å, β= 95.67 (8)°, V= 2387 (2)/Å3, Z = 4, Dx= 1.689g cm-3, Dm not ...
Delledonne, Daniele +2 more
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The quantum-chemical calculations based on density functional theory (DFT) have been performed on the diphenyltin(IV) derivative of glycyl-phenylalanine (H2L) at the B3LYP/6-31G(d,p)/LANL2DZ(Sn) level of theory without any symmetry constraint.
Pokharia Sandeep +4 more
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Synthesis and Antifungal Activity of Some Organotin(IV) Carboxylates
Six diorganotin(IV) carboxylates prepared by reacting diorganotin(IV) dichlorides with the respective silver carboxylate have been tested for antifungal activity against Aspergillus. niger, Aspergilluus flavus and Pencillium. citrinum in Sabourand dextrose broth. The compounds generally exhibit greater fungitoxicity than the diorganotin(IV) dichlorides
Bonire, Josiah J. +5 more
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Development of high-throughput yeast-cell-based bioreporter assays for specific monitoring of bisphenol A and chemical testing of endocrine disrupting compounds [PDF]
Chemicalization of the modern society has become a topic of debate in the past few decades. Especially chemicals that affect the human reproduction and hormonal system, the so-called endocrine disrupting compounds, have raised concern in public and ...
Rajasärkkä, Johanna
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Transcriptomes analysis of Aeromonas molluscorum Av27 cells exposed to tributyltin (TBT) : unravelling the effects from the molecular level to the organism [PDF]
This work was supported by FCOMP-01-0124-FEDER-010630 project, co-funded by FEDER, European Funds through COMPETE and FCT within project PEst-C/MAR/LA0017/2013.
Cruz, Andreia +3 more
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