Results 51 to 60 of about 741 (172)
Main Group Metals in Redox Catalysis
Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design and control of electronic structure. This review highlights recent advances, key design principles, and remaining challenges, positioning main group metals as
Olympia Mouriki +2 more
wiley +1 more source
The synthesis and spectral characterization of the novel organotin complexes [SnBu2(ten)] (1) and [SnBu2(Hten)(2)] (2) or the potent and widely used anti-inflammatory drug tenoxicam (H(2)ten) are reported. A crystal-structure determination of 1 showed that, in this complex, the ligand is doubly deprotonated at the hydroxy O-atom and the amide N atom ...
Demertzis, M. A. +4 more
openaire +2 more sources
ABSTRACT Organotin (IV) compounds are known to induce apoptosis via the intrinsic mitochondrial pathway, which is a key mechanism of effective anticancer therapy. Their ability to selectively promote apoptotic cell death highlights their potential as chemotherapeutic agents. In this study, the in vitro effects of two triorganotin compounds, tributyltin
Dana Strouhalova +3 more
wiley +1 more source
Enhanced Dehydrogenation and Hydrogenation Capacity of Poly(5‐Vinyl‐1‐Indanol) at Low Temperatures
ABSTRACT Redox‐active polymer‐based hydrogen carriers store hydrogen gas through chemical bonding. Although existing redox‐active polymers utilized as hydrogen storage units (e.g., fluorenone and fluorenol) demonstrate reversible hydrogenation in the presence of iridium complex catalysts, they are often hindered by low weight‐based hydrogen storage ...
Yusuke Kaiwa +3 more
wiley +1 more source
Imposex, an endocrine disruption phenomenon, is a biomarker of tributyltin (TBT) exposure in marine gastropod populations. The occurrence and intensity of the syndrome in populations of the neogastropod Stramonita haemastoma were ascertained at nine ...
Raquel Toste +4 more
doaj +1 more source
Additives' structures. ABSTRACT Poly(vinyl chloride) has been a key polymeric material since its commercial production in 1931, demonstrating versatility across numerous industries due to its compatibility with various additives. PVC's inherent properties, flame retardance, durability, and recyclability make it ideal for building and construction ...
Stefano Gardi +4 more
wiley +1 more source
Intramolecular (RO)2PO→Halogen interaction versus intermolecular (RO)2PO···HOH hydrogen bonds. Although the O···I distance is shorter than the sum of the van der Waals radii of the atoms involved, there is no covalency involved in this interaction.
David Mross +6 more
wiley +1 more source
Contamination status of coastal areas of Finland (northern Baltic Sea) markedly affected by anthropogenic activities (harbors, shipyards and maritime activity, industry, municipal and agricultural inputs, legacy contamination) was assessed for the first ...
Kari K. Lehtonen +6 more
doaj +1 more source
Durable Biofouling‐Resistant Coated Fabric Based on Aerogel/Polyurethane for Marine Applications
A multilayer composite protective fabric (PUC‐CME/KF) is developed by integrating carboxymethyl chitosan/coral extract aerogel and capsaicin‐loaded polyurethane onto a knitted substrate. The material exhibits exceptional extensibility (1963% elongation at break) and sustained capsaicin release.
Haoqiang Tian +10 more
wiley +1 more source
This review examines bio‐based polyurethanes from renewable feedstocks, focusing on structure‐property relationships governing mechanical performance. It analyzes reinforcement strategies, benchmarks against petrochemical counterparts, and explores future directions, including non‐isocyanate routes and circular economy integration for sustainable high ...
Khaled Chawraba +4 more
wiley +1 more source

