Results 31 to 40 of about 147,621 (248)
«Platinum» from the collection of A.F. Keller in the State geological museum RAS
The microprobe tests of the supposed platinum from the collection of F.A. Keller at the State geological museum of Russian Academy of Sciences have been carried out for the first time.
N. I. Braynchaninova +2 more
doaj +1 more source
Unusual DNA binding modes for metal anticancer complexes [PDF]
DNA is believed to be the primary target for many metal-based drugs. For example, platinum-based anticancer drugs can form specific lesions on DNA that induce apoptosis.
Pizarro, Ana M., Sadler, P. J.
core +1 more source
Crystallographic and Theoretical Study of Osme Bonds in Nitrido-Osmium(VI) Complexes
Osme bonds have been recently defined as the attractive interaction between an element of group 8 acting as an electrophile and any atom or group of atoms acting as a nucleophile.
Rosa M. Gomila, Antonio Frontera
doaj +1 more source
We report on the preparation and thorough characterization of cytotoxic half-sandwich complexes [Ru(η6-pcym)(bphen)(dca)]PF6 (Ru-dca) and [Os(η6-pcym)(bphen)(dca)]PF6 (Os-dca) containing dichloroacetate(1–) (dca) as the releasable O-donor ligand bearing ...
Pavel Štarha +3 more
doaj +1 more source
The ligand exchange in (n-Bu4N)2OsIVCl6 (n-Bu4N = tetra-n-butylammonium) leads to the formation of the osmium(IV) heptacyanide, the first fully inorganic homoleptic complex of heptacoordinated osmium.
Eugenia V. Peresypkina +2 more
doaj +1 more source
Thioxoethenylidene (CCS) as a bridging ligand [PDF]
The reaction of [Mo(≡CBr)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [Fe2(μ-SLi)2(CO)6] affords, inter alia, the unsymmetrical binuclear thioxoethenylidene complex [Mo2(μ,σ(C):η2(C′S)-CCS)(CO)4(Tp*)2], which may be more directly ...
Caldwell, Lorraine M. +6 more
core +1 more source
ASSESSMENT OF GOLD MELT INFLUENCE ON THE PLATINOID MICROINCLUSIONS IN ANCIENT GOLD PRODUCTS: A COMPARISON WITH EXPERIMENTAL DATA [PDF]
The results of gold melt influence on platinoid microinclusions in ancient gold products from the burial mounds of the Urals and Phanagoria are compared with the experimental data.
V.V. Zaykov +9 more
doaj
Bis(flavonolato-κ2O,O′)dioxidoosmium(VI) dichloromethane disolvate
In the crystal structure of the title solvated trans-dioxidoosmium(VI) flavonolate (flav) complex, [Os(C15H9O3)2O2]·2CH2Cl2 or [Os(flav)2O2]·2CH2Cl2, the two dichloromethane solvent molecules have nonclassical hydrogen-bonding contacts at or greater than
Will Lynch, Clifford Padgett
doaj +1 more source
Potential super-hard Osmium di-nitride with fluorite structure: First-principles calculations
We have performed systematic first-principles calculations on di-carbide, -nitride, -oxide and -boride of platinum and osmium with the fluorite structure. It is found that only PtN$_{2}$, OsN$_{2}$ and OsO$_{2}$ are mechanically stable. In particular OsN$
C. Kittel +15 more
core +2 more sources
Local Moment Instability of Os in Honeycomb Li2.15Os0.85O3. [PDF]
Compounds with honeycomb structures occupied by strong spin orbit coupled (SOC) moments are considered to be candidate Kitaev quantum spin liquids. Here we present the first example of Os on a honeycomb structure, Li2.15(3)Os0.85(3)O3 (C2/c, a = 5.09 Å ...
Dessau, DS +8 more
core +2 more sources

