Results 31 to 40 of about 147,621 (248)

«Platinum» from the collection of A.F. Keller in the State geological museum RAS

open access: yesИзвестия высших учебных заведений: Геология и разведка, 2017
The microprobe tests of the supposed platinum from the collection of F.A. Keller at the State geological museum of Russian Academy of Sciences have been carried out for the first time.
N. I. Braynchaninova   +2 more
doaj   +1 more source

Unusual DNA binding modes for metal anticancer complexes [PDF]

open access: yes, 2009
DNA is believed to be the primary target for many metal-based drugs. For example, platinum-based anticancer drugs can form specific lesions on DNA that induce apoptosis.
Pizarro, Ana M., Sadler, P. J.
core   +1 more source

Crystallographic and Theoretical Study of Osme Bonds in Nitrido-Osmium(VI) Complexes

open access: yesInorganics, 2022
Osme bonds have been recently defined as the attractive interaction between an element of group 8 acting as an electrophile and any atom or group of atoms acting as a nucleophile.
Rosa M. Gomila, Antonio Frontera
doaj   +1 more source

Half-Sandwich Ru(II) and Os(II) Bathophenanthroline Complexes Containing a Releasable Dichloroacetato Ligand

open access: yesMolecules, 2018
We report on the preparation and thorough characterization of cytotoxic half-sandwich complexes [Ru(η6-pcym)(bphen)(dca)]PF6 (Ru-dca) and [Os(η6-pcym)(bphen)(dca)]PF6 (Os-dca) containing dichloroacetate(1–) (dca) as the releasable O-donor ligand bearing ...
Pavel Štarha   +3 more
doaj   +1 more source

The First Homoleptic Complex of Seven-Coordinated Osmium: Synthesis and Crystallographical Evidence of Pentagonal Bipyramidal Polyhedron of Heptacyanoosmate(IV)

open access: yesCrystals, 2016
The ligand exchange in (n-Bu4N)2OsIVCl6 (n-Bu4N = tetra-n-butylammonium) leads to the formation of the osmium(IV) heptacyanide, the first fully inorganic homoleptic complex of heptacoordinated osmium.
Eugenia V. Peresypkina   +2 more
doaj   +1 more source

Thioxoethenylidene (CCS) as a bridging ligand [PDF]

open access: yes, 2015
The reaction of [Mo(≡CBr)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [Fe2(μ-SLi)2(CO)6] affords, inter alia, the unsymmetrical binuclear thioxoethenylidene complex [Mo2(μ,σ(C):η2(C′S)-CCS)(CO)4(Tp*)2], which may be more directly ...
Caldwell, Lorraine M.   +6 more
core   +1 more source

ASSESSMENT OF GOLD MELT INFLUENCE ON THE PLATINOID MICROINCLUSIONS IN ANCIENT GOLD PRODUCTS: A COMPARISON WITH EXPERIMENTAL DATA [PDF]

open access: yesМинералогия, 2017
The results of gold melt influence on platinoid microinclusions in ancient gold products from the burial mounds of the Urals and Phanagoria are compared with the experimental data.
V.V. Zaykov   +9 more
doaj  

Bis(flavonolato-κ2O,O′)dioxidoosmium(VI) dichloromethane disolvate

open access: yesIUCrData, 2017
In the crystal structure of the title solvated trans-dioxidoosmium(VI) flavonolate (flav) complex, [Os(C15H9O3)2O2]·2CH2Cl2 or [Os(flav)2O2]·2CH2Cl2, the two dichloromethane solvent molecules have nonclassical hydrogen-bonding contacts at or greater than
Will Lynch, Clifford Padgett
doaj   +1 more source

Potential super-hard Osmium di-nitride with fluorite structure: First-principles calculations

open access: yes, 2006
We have performed systematic first-principles calculations on di-carbide, -nitride, -oxide and -boride of platinum and osmium with the fluorite structure. It is found that only PtN$_{2}$, OsN$_{2}$ and OsO$_{2}$ are mechanically stable. In particular OsN$
C. Kittel   +15 more
core   +2 more sources

Local Moment Instability of Os in Honeycomb Li2.15Os0.85O3. [PDF]

open access: yes, 2018
Compounds with honeycomb structures occupied by strong spin orbit coupled (SOC) moments are considered to be candidate Kitaev quantum spin liquids. Here we present the first example of Os on a honeycomb structure, Li2.15(3)Os0.85(3)O3 (C2/c, a = 5.09 Å ...
Dessau, DS   +8 more
core   +2 more sources

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