Results 121 to 130 of about 762 (245)

Redox‐Active Bisphosphines Based on a W(II)‐Propargyl Complex Backbone

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Three bisphosphine ligands based on tungsten(II) propargyl‐type alkyne complexes were synthesized and characterized. The methanolate derivative was used as a metalla‐ligand for the preparation of a binuclear bisphosphine‐κ2‐PdCl2 complex. In both cases, IR spectroelectrochemistry (IR‐SEC) measurements revealed a successive process following oxidation ...
Friederike M. Hamann   +7 more
wiley   +1 more source

Actinide 4,4′‐Bipyridine‐N,N′‐Dioxide Coordination Polymers: Cationic Framework Structures Templated by Dicyanoaurate and Tetracyanoaurate Counterions

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Th4+ or UO22+ actinides, neutral bipyridine‐N,N’‐dioxide ligands, and anionic cyanoaurate linkers are combined to generate a family of four coordination polymers. ‘Truss bridge’ and square grid cationic frameworks are yielded when using [Au(CN)2]− or [Au(CN)4]−, respectively, indicating a templating effect guided by either aurophilic interactions ...
Sylvain St. Louis   +2 more
wiley   +1 more source

Iminodirhodium‐ and Iminocopper‐Catalyzed CH Activation: Chemoselective Oxidation of Alcohols and Aldehydes via Intermolecular Hydride Abstraction

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Chemoselective hydride abstractor iminometalloids, derived from O‐mesylacetoxime (MAO) using Rh2(II/II) or Cu(I) catalysts, can activate the C–Hα bonds of alcohols and aldehydes ultimately forming ketones, carboxylic acids, and esters even in the presence of C–H bonds with comparable bond strengths.
Raghunath Reddy Anugu   +2 more
wiley   +1 more source

Dual hydration of oceanic lithosphere. [PDF]

open access: yesNatl Sci Rev, 2023
Zhang F   +5 more
europepmc   +1 more source

Enantiospecific Acid‐Catalysed Hydroperoxidation of Scalemic Tertiary Benzylic Alcohols Facilitating a Concise Asymmetric Synthesis of Yingzhaosu C

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Asymmetric synthesis of antimalarial yingzhaosu C was achieved in 4–5 steps by asymmetric Grignard synthesis of (R)‐gossonorol followed by novel enantiospecific hydroperoxidation. We report a concise asymmetric synthesis of antimalarial yingzhaosu C in 59% ee.
Saranna E. Kavanagh   +2 more
wiley   +1 more source

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