Results 41 to 50 of about 149,991 (265)

Kinetics for Oxidation of Squalene.

KAGAKU KOGAKU RONBUNSHU, 2000
スクアレンの酸化反応速度を気泡塔型反応器を用いて測定した. 酸化反応は, 過酸化物の生成速度が緩やかな誘導期とその生成速度が自触媒的に増加する加速期の二つの段階によって進行することがわかった. 過酸化物濃度は加速期の後半で最大となり, その後緩やかに減少した. 紫外/可視吸収および化学発光検出器を備えた高速液体クロマトグラフィーを用いてスクアレンおよび6種の過酸化物生成挙動を確認した. 酸化反応によって生成した過酸化物は高温で容易に分解され, 分解生成物の主成分はカルボニル化合物であることがわかった. 実験結果を脂質ラジカルを考慮した連鎖反応モデルに基づいて解析し, 酸化速度式を導出した.
SUN, WEI, SHIOMORI, KOICHIRO, KAWANO, YOSHINOBU, HATATE, YASUO   +3 more
openaire   +2 more sources

C2α‐carbanion‐protonating glutamate discloses tradeoffs between substrate accommodation and reaction rate in actinobacterial 2‐hydroxyacyl‐CoA lyase

FEBS Open Bio, EarlyView.
Enzymes of the 2‐hydroxyacyl‐CoA lyase group catalyze the condensation of formyl‐CoA with aldehydes or ketones. Thus, by structural adaptation of active sites, practically any pharmaceutically and industrially important 2‐hydroxyacid could be biotechnologically synthesized. Combining crystal structure analysis, active site mutations and kinetic assays,
Michael Zahn, Barbara Seroka, Ryszard Lazny, Zenon Lotowski, Thore Rohwerder   +4 more
wiley   +1 more source

Neural NetworkModeling of Oxidation Kinetics in Air of Steel-T21 Alloy Coated by Simultaneous Germanium-Doped Aluminizing-Silicon zing Process [PDF]

Engineering and Technology Journal, 2013
In this work a pack cementation of germanium-doped aluminum and silicon coatings on low alloy steel type-T21 has been applied. This gives significant improvement in the oxidation.
Abbas Khammas, Mohanned M. H.AL-Khafaji
doaj   +1 more source

Establishing an assay to evaluate d‐amino acid oxidase enzyme kinetics and inhibition using WST‐8 redox dye

FEBS Open Bio, EarlyView.
This study investigated a novel WST‐8‐based assay for evaluating d‐Amino acid oxidase (DAO) inhibitors. We confirmed its effectiveness using known inhibitors and found that uremic toxins possess relatively weak inhibitory activity compared to existing drugs.
Kahoko Miyake, Yuki Enoki, Yuka Nakazawa, Kazuaki Taguchi, Kazuaki Matsumoto   +4 more
wiley   +1 more source

Oxidation and Corrosion Mechanism of Steel Alloys and Inconel 600 Alloy in Liquid–Lead-Bismuth Eutectic [PDF]

Engineering and Technology Journal, 2008
The alloys used in this study were two types pf stainless steels (304SS and316 SS) , low alloy steel (Type T22-ASTM) and Inconel 600 alloy `(nickelbasesuperalloy).
Ahmed Moosa
doaj   +1 more source

Proteasomal degradation of intracellularly expressed Amblyomin‐X limits suicide gene therapy potential in melanoma cells

FEBS Open Bio, EarlyView.
This study explores the feasibility of expressing the antitumoral protein Amblyomin‐X through a suicide gene therapy approach and investigates its intracellular fate after gene delivery. Although the gene is efficiently expressed, melanoma cells rapidly degrade the Amblyomin‐X protein via proteasome activity.
Victor Dal Posolo Cinel, Carlos DeOcesano Pereira, Aline Ramos Maia Lobba, Melissa Regina Fessel, Ana Marisa Chudzinski‐Tavassi   +4 more
wiley   +1 more source

Spectroscopic and Kinetic Characterization of Peroxidase-Like π-Cation Radical Pinch-Porphyrin-Iron(III) Reaction Intermediate Models of Peroxidase Enzymes

Molecules, 2016
The spectroscopic and kinetic characterization of two intermediates from the H2O2 oxidation of three dimethyl ester [(proto), (meso), (deuteroporphyrinato) (picdien)]Fe(III) complexes ([FePPPic], [FeMPPic] and [FeDPPic], respectively) pinch-porphyrin ...
Samuel Hernández Anzaldo, Uriel Arroyo Abad, Armando León García, Daniel Ramírez Rosales, Rafael Zamorano Ulloa, Yasmi Reyes Ortega   +5 more
doaj   +1 more source

UiO‐66 metal–organic frameworks in biomedicine: From structural tunability to bioimaging, photodiagnostics, and photodynamic cancer therapy

FEBS Open Bio, EarlyView.
UiO‐66(Zr) metal–organic frameworks are chemically stable, biocompatible, and highly tunable nanomaterials. Their modular structure enables controlled drug delivery, multimodal bioimaging, and light‐activated photodynamic therapy, supporting integrated diagnostic and therapeutic (theranostic) applications in cancer and biomedical research.
Veronika Huntošová, Grigorii Rakhalskii, Miroslav Almáši   +2 more
wiley   +1 more source

Fat oxidation, hormonal and plasma metabolite kinetics during a submaximal incremental test in lean and obese adults. [PDF]

PLoS ONE, 2014
This study aimed to compare fat oxidation, hormonal and plasma metabolite kinetics during exercise in lean (L) and obese (O) men. Sixteen L and 16 O men [Body Mass Index (BMI): 22.9 ± 0.3 and 39.0 ± 1.4 kg · m(-2)] performed a submaximal incremental test
Stefano Lanzi, Franco Codecasa, Mauro Cornacchia, Sabrina Maestrini, Alberto Salvadori, Amelia Brunani, Davide Malatesta   +6 more
doaj   +1 more source

Emerging insights into CC and CXC chemokines and their receptors in Mycobacterium tuberculosis infection

FEBS Open Bio, EarlyView.
The dual roles of CC and CXC chemokines in distinguishing active, latent, and subclinical tuberculosis were reviewed, along with an evaluation of their potential as diagnostic biomarkers and therapeutic targets to advance precision medicine in tuberculosis management. The graphical abstract was generated with AI assistance (Gemini 3.0).
Xuying Yin, Dangsheng Xiao, Jiezuan Yang
wiley   +1 more source