Results 91 to 100 of about 41,455 (313)

Cascade Promotion of Gas Separation Performances in CMS Membranes: MOFs With Functional Groups and Loaded Noble Metals

open access: yesAdvanced Science, EarlyView.
Novel mixed‐matrix carbon molecular sieve (MMCMS) membranes are fabricated via employing palladium‐doped carboxyl‐functionalized UiO‐66 (Pd/UiO66‐COOH)/polyimide MMM as precursor. The synergistic effect of decarboxylation‐induced thermally cross‐linking and catalytic graphitization of Pd promoted the formation of more ordered Langmuir domains, thereby ...
Min Deng   +13 more
wiley   +1 more source

Unraveling the Photocatalytic Mechanisms on TiO2 Surfaces Using the Oxygen-18 Isotopic Label Technique

open access: yesMolecules, 2014
During the last several decades TiO2 photocatalytic oxidation using the molecular oxygen in air has emerged as a promising method for the degradation of recalcitrant organic pollutants and selective transformations of valuable organic chemicals.
Xibin Pang   +5 more
doaj   +1 more source

The oxygen-independent coproporphyrinogen III oxidase HemN utilizes harderoporphyrinogen as a reaction intermediate during conversion of coproporphyrinogen III to protoporphyrinogen IX [PDF]

open access: yes, 2010
During heme biosynthesis the oxygen-independent coproporphyrinogen III oxidase HemN catalyzes the oxidative decarboxylation of the two propionate side chains on rings A and B of coproporphyrinogen III to the corresponding vinyl groups to yield ...
Dülcks, Thomas   +7 more
core   +2 more sources

Rational Design of Advanced Functional Catalysts for Photo‐Reforming Glucose into Bio‐Derived Fuels and Chemicals

open access: yesAdvanced Science, EarlyView.
This review systematically summarizes the fundamental mechanisms of photocatalytic glucose conversion, catalyst design strategies, key reaction pathways, structure‐activity relationships, influence of reaction parameter adjustments, and current challenges in the field.
Qiong Yan   +7 more
wiley   +1 more source

Biochemical Characterization and Phylogenetic Analysis of the Virulence Factor Lysine Decarboxylase From Vibrio vulnificus

open access: yesFrontiers in Microbiology, 2018
Cadaverine is produced in organisms from the amino acid lysine in a decarboxylation reaction catalyzed by lysine decarboxylase (EC 4.1.1.18). The inducible lysine decarboxylase CadA plays a vital role in acid stress response for enteric bacteria.
Lifen Han   +10 more
doaj   +1 more source

ECUT: Energy Conversion and utilization Technologies program biocatalysis research activity. Generation of chemical intermediates by catalytic oxidative decarboxylation of dilute organic acids [PDF]

open access: yes
A rhodium-based catalyst was prepared and preliminary experiments were completed where the catalyst appeared to decarboxylate dilute acids at concentrations of 1 to 10 vol%.
Distefano, S., Gupta, A., Ingham, J. D.
core   +1 more source

Pore Sieving and Surficial Charge‐Driven Desolvation for High Spatial Charge Density Carbon Cathodes in Zinc‐Ion Hybrid Capacitors

open access: yesAdvanced Energy Materials, EarlyView.
A dual‐regulation strategy integrating pore architecting and surface charge modulation is engineered in multi‐channeled carbon nanofibers, enabling efficient electric double layer compacting and interfacial [Zn(H2O)6]2+ desolvation for high spatial density charge storage.
Guangjie Yang   +11 more
wiley   +1 more source

Anorectal Melanoma [PDF]

open access: yes, 2018
Anorectal melanoma (AM) is a rare malignancy, characterized by aggressive behavior and a poor prognosis. AM is more frequent in female patients aged over 50 years.
Dario Didona   +4 more
core   +1 more source

A Smart Ru‐Locked Chemiluminescence Probe via Bioorthogonal Activation for Highly Selective, Real‐Time and Noninvasive In Vivo Imaging of Thiol Dysregulation

open access: yesAggregate, EarlyView.
A smart Ru‐catalyzed chemiluminescence probe based on phenoxy‐adamantyl‐1,2‐dioxetane (PAD) scaffolds is developed for highly sensitive, real‐time in vivo imaging. Featuring a Ru‐locked activation mechanism and a chemiluminophore synthesized via an optimized route, this noninvasive probe enables selective, light‐independent detection of H₂S and thiol ...
Dongnan Guo   +11 more
wiley   +1 more source

The signaling pathways and therapeutic potential of itaconate to alleviate inflammation and oxidative stress in inflammatory diseases

open access: yesRedox Biology, 2022
Endogenous small molecules are metabolic regulators of cell function. Itaconate is a key molecule that accumulates in cells when the Krebs cycle is disrupted.
Xuan Shi   +5 more
doaj  

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