Results 101 to 110 of about 2,950,856 (378)

2-pentanone production from hexanoic acid by Penicillium roqueforti from blue cheese:is this the pathway used in humans? [PDF]

open access: yes, 2014
Production of 2-pentanone, a methylketone, is increased in fasting ketotic humans. Its origin is unknown. We hypothesised that it is formed via β-oxidation of hexanoic acid by the peroxisomal pathway proposed for methylketone-producing fungi and yeasts ...
Mills, Graham A., Walker, Valerie
core   +2 more sources

Cascade Promotion of Gas Separation Performances in CMS Membranes: MOFs With Functional Groups and Loaded Noble Metals

open access: yesAdvanced Science, EarlyView.
Novel mixed‐matrix carbon molecular sieve (MMCMS) membranes are fabricated via employing palladium‐doped carboxyl‐functionalized UiO‐66 (Pd/UiO66‐COOH)/polyimide MMM as precursor. The synergistic effect of decarboxylation‐induced thermally cross‐linking and catalytic graphitization of Pd promoted the formation of more ordered Langmuir domains, thereby ...
Min Deng   +13 more
wiley   +1 more source

Iridium‐Catalyzed Enantioselective Intramolecular Hydroarylation of Allenes: Formal Synthesis of (+)‐Rhazinilam

open access: yesAngewandte Chemie, EarlyView.
A highly enantioselective iridium‐catalyzed hydroarylation of allene‐tethered pyrroles and indoles that provides access to relevant heterocyclic systems bearing vinyl‐substituted 3ry or 4ry stereocenters is reported. Its synthetic potential was exemplified with a very short, highly enantioselective formal synthesis of (+)‐Rhazinilam, whereas DFT ...
Andrés Arribas   +4 more
wiley   +2 more sources

Pre-symptomatic activation of antioxidant responses and alterations in glucose and pyruvate metabolism in Niemann-Pick Type C1-deficient murine brain. [PDF]

open access: yesPLoS ONE, 2013
Niemann-Pick Type C (NPC) disease is an autosomal recessive neurodegenerative disorder caused in most cases by mutations in the NPC1 gene. NPC1-deficiency is characterized by late endosomal accumulation of cholesterol, impaired cholesterol homeostasis ...
Barry E Kennedy   +6 more
doaj   +1 more source

Oxidative decarboxylative ammonium hypoiodite-catalysed dihydrobenzofuran synthesis

open access: yesOrganic & Biomolecular Chemistry, 2022
The catalytic use of quaternary ammonium iodides under oxidative conditions allows for the direct conversion of readily available β-ketolactones into dihydrobenzofurans.
Katharina Röser   +4 more
openaire   +3 more sources

PHOSPHO1 Suppresses Ferroptosis in Retinal Pigment Epithelial Cells by Reducing the Levels of Phosphatidylethanolamine Molecular Species

open access: yesAdvanced Science, EarlyView.
Iron‐induced lipid peroxidation of phosphatidylethanolamine (PE) species is the key driver of ferroptosis. The authors discovered that PHOSPHO1 lowers the level of PE in retinal pigment epithelial cells thus reducing the formation of lipid peroxides. Lowering PE levels can also prevent the creation of autolysosomes, reduce the production of free iron ...
Zhiyang Chen   +19 more
wiley   +1 more source

Use of superheated liquids for the extraction of non-volatile compounds from wood: HPLC studies [PDF]

open access: yes, 2004
A study of the extraction of oak wood compounds using superheated water-ethanol mixtures ranging from 10 to 60% ethanol is reported. Identification and characterization of the extracted compounds have been made by high performance liquid chromatography ...
Chatonnet   +12 more
core   +1 more source

Pore Sieving and Surficial Charge‐Driven Desolvation for High Spatial Charge Density Carbon Cathodes in Zinc‐Ion Hybrid Capacitors

open access: yesAdvanced Energy Materials, EarlyView.
A dual‐regulation strategy integrating pore architecting and surface charge modulation is engineered in multi‐channeled carbon nanofibers, enabling efficient electric double layer compacting and interfacial [Zn(H2O)6]2+ desolvation for high spatial density charge storage.
Guangjie Yang   +11 more
wiley   +1 more source

Electron bifurcation mechanism and homoacetogenesis explain products yields in mixed culture anaerobic fermentations [PDF]

open access: yes, 2017
Anaerobic fermentation of organic wastes using microbial mixed cultures is a promising avenue to treat residues and obtain added-value products. However, the process has some important limitations that prevented so far any industrial application.
González-Cabaleiro, R.   +4 more
core   +4 more sources

On/Off O2 switchable photocatalytic oxidative and proto decarboxylation of carboxylic acids.

open access: yesJournal of Organic Chemistry, 2019
Photoredox catalysis in recent years has manifested a powerful branch of science in organic synthesis. Although merging photoredox and metal catalysts have been widely used, switchable heterogeneous photoredox catalysis has rarely considered.
Zahra Bazyar, M. Hosseini‐Sarvari
semanticscholar   +1 more source

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