Results 11 to 20 of about 41,455 (313)
Nucleophilic Benzoylation Using a Mandelic Acid Dioxolanone as a Synthetic Equivalent of the Benzoyl Carbanion. Oxidative Decarboxylation of α-Hydroxyacids [PDF]
Molecules, 2004 The synthesis of alkyl aryl ketones using a mandelic acid dioxolanone as a synthetic equivalent (Umpolung) of the benzoyl carbanion is reported. The methodology involves alkylation of the mandelic acid dioxolanone, hydrolysis of the dioxolanone moiety in
José R. Pedro +3 more
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THE OXIDATIVE DECARBOXYLATION OF MALATE BY ASCARIS LUMBRICOIDES [PDF]
Journal of Biological Chemistry, 1957 Howard J. Saz, Jeanette A. Hubbard
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Oxidative decarboxylation of glycollate and glyoxylate by leaf peroxisomes [PDF]
Biochemical Journal, 1974 1. The conditions under which peroxisomal preparations from leaves of spinach beet and spinach catalyse the release of 14CO2 from [1-14C]glycollate and [1-14C]glyoxylate were investigated. 2. At pH8, 14CO2 production from [1-14C]glyoxylate was accompanied by equivalent quantities of formate.
Barry Halliwell, Vernon S. Butt
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Oxidative Decarboxylation : Partial Synthesis of Aegiceradienol (nor Echinocystadienol) [PDF]
Chemischer Informationsdienst, 1982 AbstractDie oxidative Decarboxylierung der pentacyclischen Acetoxycarbonsäure (I) liefert ein Gemisch der isomeren Diene (II), die säurekatalysiert zum konjugierten Dien (IIIa) isomerisiert und weiter zum im Titel genannten Dienalkohol (IIIb) hydrolysiert ′werden.
T. SUNDARARAMAIAH, V. VISHWANATH RAO
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Antioxidants, 2021 This study aimed to obtain and characterize extracted hemp oil enriched in cannabidiol (CBD) by decarboxylation of cannabidiolic acid (CBDA) and to give new insights into its antioxidant and anticancer effects.
Anca Roxana Petrovici +5 more
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Overcoming Challenges in Small-Ring Transfer: Direct Decarboxylative Hydroalkylation of Alkenes via Iron-Thiol Catalysis. [PDF]
Angew Chem Int Ed EnglHerein, we present a catalytic approach for the direct decarboxylation of challenging CF3‐cyclopropyl and cyclobutyl carboxylic acids using cooperative iron‐thiol catalysis. This strategy enables the efficient generation of valuable radicals that can be incorporated into activated and unactivated alkenes, offering access to elusive chemical space ...
Giri R +5 more
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Frontiers in Bioengineering and Biotechnology, 2022 The oxidative decarboxylation of coproheme to form heme b by coproheme decarboxylase is a stereospecific two-step reaction. In the first step, the propionate at position two (p2) is cleaved off the pyrrole ring A to form a vinyl group at this position ...
Hanna Michlits +3 more
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Journal of Analytical Science and Technology, 2022 Decarboxylation of cannabidiolic acid (CBDA) is an important step for efficient production of the active pharmaceutical component cannabidiol (CBD) in Cannabis species.
Chaeyoung Seo +7 more
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Visible light-promoted transition metal-free direct C3-carbamoylation of 2H-Indazoles
Frontiers in Chemistry, 2022 We reported a general transition metal-free transformation to access C3-carbamoylated 2H-indazoles via visible light-induced oxidative decarboxylation coupling, in the presence of oxamic acids as the coupling sources, 4CzIPN as the photocatalyst, and ...
Chunhua Ma +7 more
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Encapsulation of ascorbic acid promotes the reduction of Maillard reaction products in UHT milk [PDF]
, 2016 The presence of amino groups and carbonyls renders fortified milk with ascorbic acid particularly susceptible to the reduction of available lysine and to the formation of Maillard reaction products (MRPs), as Nε-(Carboxyethyl)-L-lysine (CEL), Nε ...
Ahmed +36 more
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