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Dual Activities of Oxidation and Oxidative Decarboxylation by Flavoenzymes
ChemBioChem, 2022AbstractSpecific flavoenzyme oxidases catalyze oxidative decarboxylation in addition to their classical oxidation reactions in the same active sites. The mechanisms underlying oxidative decarboxylation by these enzymes and how they control their two activities are not clearly known.
Duangthip Trisrivirat +3 more
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Oxidative decarboxylation of naproxen
Journal of Pharmaceutical Sciences, 1992The decarboxylation of naproxen (1H) and its salt (1-) was achieved by means of chemical [Ce(IV) or S2O8(2-)] and electrochemical oxidation. The product patterns were compatible with mechanisms involving single-electron transfer from the pi-system or the carboxylate moiety.
Ramón Martínez-Máñez +5 more
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Mechanisms of Enzymatic Oxidative Decarboxylation [PDF]
Accounts of Chemical Research, 1999 AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
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Oxidative Decarboxylation of Carboxylic Acids
Russian Chemical Reviews, 1980The present state of studies on the decarboxylation of carboxylic acids by various oxidation systems is described and the dependence of the yield and composition of the reaction products on the structure of the carboxylic acid, the type of oxidant and its ligand environment, the nature of the solvent, and the reaction mechanism is considered.
Irina P. Beletskaya, Yu. A. Serguchev
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Oxidation and Decarboxylation of Citrate in the Presence of Ferrous Iron [PDF]
Nature, 1957 ALTHOUGH a paper by Wieland and Franke in 19281 described the induced oxidation of several hydroxy-acids in the presence of oxidizing ferrous iron, citric acid was not specifically mentioned, and its reaction under these conditions appears not to be well known.
Grau, F. H., Halliday, W. J.
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Oxidative decarboxylation of propiolic acids
The Journal of Organic Chemistry, 1984Oxydation des acides benzenepropiolique et hexyne-2oique avec I 2 et I 2 O 5 dans le ...
Edward McNelis, Mark J. Cohen
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Advances in Decarboxylative Oxidative Coupling Reaction
The Journal of Organic Chemistry, 2018Since carboxylic acid derivatives are commercially available, nontoxic, cheap, and normally stable to air and moisture, carboxylic acid derivatives are ideal reactants for synthetic strategy. In recent years, decarboxylative oxidative coupling reactions, which normally involve direct C-H bond activation, have attracted more and more interest from the ...
Tong Zhang, Nai-Xing Wang, Yalan Xing
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Oxidative decarboxylation of cyclohexanecarboxylic acid
Recueil des Travaux Chimiques des Pays-Bas, 1963AbstractCyclohexanecarboxylic acid is converted to a mixture of cyclohexanone and cyclohexene by reacting it at temperatures around 200° with an oxygen‐containing gas and steam in the presence of metal‐salt catalysts.
J. A. Bigot, P. L. Kerkhoffs
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Oxidative decarboxylation of diclofenac by manganese oxide bed filter
Water Research, 2013Diclofenac (DCF) was eliminated by fast chemical oxidation on natural manganese oxide in a column reactor. Identification of transformation by-products of DCF by HPLC-UV-MS(n) gave evidence of decarboxylation, iminoquinone formation and dimerization.
Huguet, M. +3 more
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