Results 71 to 80 of about 41,455 (313)
Nature Communications, 2023 Actinobacteria possess unique ways to regulate the oxoglutarate metabolic node. Contrary to most organisms in which three enzymes compose the 2-oxoglutarate dehydrogenase complex (ODH), actinobacteria rely on a two-in-one protein (OdhA) in which both the
Lu Yang +8 more
doaj +1 more source
Oxidative decarboxylative ammonium hypoiodite-catalysed dihydrobenzofuran synthesis
Organic & Biomolecular Chemistry, 2022 The catalytic use of quaternary ammonium iodides under oxidative conditions allows for the direct conversion of readily available β-ketolactones into dihydrobenzofurans.
Katharina Röser +4 more
openaire +3 more sources
Polycondensation as a Universal Method for Preparing High‐Density Single‐Atom Catalyst Libraries
Advanced Materials, EarlyView.This paper presents a universal bottom‐up polycondensation strategy for synthesizing high‐density single‐atom catalysts (HD‐SACs) with metal loadings up to 27.5 wt%. Using various metal monomers with 1,10‐phenanthroline‐5,6‐dione ligands, it generates atomically dispersed mono‐ and bimetallic HD‐SACs.
Jaques‐Christopher Schmidt +21 more
wiley +1 more source
Angewandte Chemie, EarlyView.Natural alcohol and sugar dehydrogenases that utilize the redox cofactor pyrroloquinoline quinone (PQQ) can be repurposed for enantioselective photoredox catalysis. Upon blue‐light irradiation, redox‐neutral radical cyclizations are catalyzed. This work adds a new class of enzymes to the toolbox of photobiocatalysis.
Srishti B. Bahukhandi +8 more
wiley +2 more sources
An Alternative Mechanistic Paradigm for the Electrochemical C‐Terminal Decarboxylation of Peptides
ChemElectroChemThe C‐terminal decarboxylation of peptides provides an important opportunity to synthesize modern peptide pharmaceuticals that contain C‐terminal amides.
Adam J. Sowers +2 more
doaj +1 more source
Prelog Lecture: Mechanism and Structure of Biosynthetic Enzymes. The Biosynthesis of Vitamin B6
CHIMIA, 2003 On Monday, November 11, 2002, the vice president, Prof. Dr. Gerhard Schmitt, presented the Prelog Medal 2002 to Prof. Dr. David E. Cane, Brown University, Providence, Rhode Island, USA.
David E. Cane
doaj +1 more source
Research Progress on Vanillin in Alcoholic Beverages
Shipin gongye ke-ji, 2022 Vanillin is a very important aroma compound in alcoholic beverages. It has been widely concerned because of its pleasant sweet aroma, vanilla aroma and physiological function.
Xinliang MO +4 more
doaj +1 more source
Photocatalytic Aqueous Reforming of Methyl Formate
Advanced Materials, EarlyView.A 3d‐metal Cu‐based atomically dispersed photocatalyst, supported on modified g‐C₃N₄, facilitates the photocatalytic selective hydrogen (7.5 mmol gcat−1 of hydrogen; nothing else than H2 and CO2) generation from methyl formate. This diverse system functions under mild conditions, providing high hydrogen yield, selectivity, and enduring stability ...
Dongxu Zuo +13 more
wiley +1 more source
Angewandte Chemie, EarlyView.Decarboxylative hydrazination of carboxylic acids is achieved using a 1:5:2 ratio of three metal salts, Ce(OtBu)4, Zr(OtBu)4, and Mn(OAc)3, as a catalyst under visible light irradiation, in which single cerium‐incorporated hexanuclear mixed‐metal clusters containing a [CeZr5O4(OH)4]12+ core are formed with association of manganese(II) species.
Sota Tamaki +7 more
wiley +2 more sources
Pre-symptomatic activation of antioxidant responses and alterations in glucose and pyruvate metabolism in Niemann-Pick Type C1-deficient murine brain. [PDF]
PLoS ONE, 2013 Niemann-Pick Type C (NPC) disease is an autosomal recessive neurodegenerative disorder caused in most cases by mutations in the NPC1 gene. NPC1-deficiency is characterized by late endosomal accumulation of cholesterol, impaired cholesterol homeostasis ...
Barry E Kennedy +6 more
doaj +1 more source