Results 21 to 30 of about 18,453,470 (125)

Tg Confinement Effect of Random Copolymers of 4-tert-Butylstyrene and 4-Acetoxystyrene with Different Compositions

open access: yes, 2019
We observe that the Tg confinement effect of polymer films can saturate with polymer-substrate interaction. Thickness dependences of the glass transition temperature, Tg(h0), of random copolymer films of 4-tert-butylstyrene (TBS) and 4-acetoxystyrene (AS)
Lv, Chao   +8 more
core   +1 more source

Melt Grafting of Geometry‐Tailored Voltage Stabilizers for High‐Performance Polypropylene Insulation

open access: yesAdvanced Functional Materials, Volume 36, Issue 30, 13 April 2026.
A scalable one‐step melt grafting strategy is developed to enhance the dielectric properties of isotactic polypropylene by covalently incorporating thermally stable aromatic voltage stabilizers. This solvent‐free approach improves volume resistivity and DC breakdown strength through deep trap formation and charge localization, offering a sustainable ...
Nazirul Mubin bin Normansah   +9 more
wiley   +1 more source

Synthesis of triblock and random copolymers of 4- acetoxystyrene and styrene by living atom transfer radical polymerization

open access: yes, 1997
Triblock copolymers containing polystyrene (PSt) and poly(4-acetoxystyrene) (PAcOSt) segments have been prepared by atom transfer radical polymerization (ATRP). In the first step one of the two monomers was polymerized in bulk using the initiating system
Chen, Xianyi   +4 more
core   +1 more source

trans-Ethylenedi-p-phenylene diacetate

open access: yes, 2009
The centrosymmetric title compound, C18H26O4, was prepared in high yield from 4-acetoxystyrene via Ru-catalysed homo-olefin metathesis. Exclusive formation of the E-configurated isomer was observed.
Stefanie Ritter   +3 more
core   +1 more source

Highly Conjugated Molecules from Dibromonaphthyl Derivatives and 4-Vinylpyridine or 4-Acetoxystyrene by the Heck Reaction

open access: yes, 2009
Palladium-catalyzed coupling of 1,6- and 2,6-dibromonaphthyl derivatives with 4-vinylpyridine or 4-acetoxystyrene resulted in mono- and bis-arylvinylation depending on the choice of reaction conditions.
Chang, C. C.; Chen, K. J.; 余良杰; Yu, L. J.
core   +1 more source

Highly Conjugated Molecules from Dibromonaphthyl Derivatives and 4-Vinylpyridine or 4-Acetoxystyrene by the Heck Reaction

open access: yes, 2016
Palladium-catalyzed coupling of 1,6- and 2,6-dibromonaphthyl derivatives with 4-vinylpyridine or 4-acetoxystyrene resulted in mono- and bis-arylvinylation depending on the choice of reaction conditions.
L. J. Yu (2519929)   +2 more
core   +1 more source

Improved high‐temperature electrical properties of polypropylene insulation material by grafting styrene

open access: yesHigh Voltage, Volume 10, Issue 3, Page 603-614, June 2025.
Abstract The electrical properties of polypropylene (PP) insulation material decrease dramatically at high temperature, which limits its application in harsh environments. This study investigates how grafting styrene (St) improves the high‐temperature electrical properties of PP.
Xinhua Dong   +9 more
wiley   +1 more source

Tg Confinement Effect of Random Copolymers of 4-tert-Butylstyrene and 4‑Acetoxystyrene with Different Compositions

open access: yes, 2019
We observe that the Tg confinement effect of polymer films can saturate with polymer–substrate interaction. Thickness dependences of the glass transition temperature, Tg(h0), of random copolymer films of 4-tert-butylstyrene (TBS) and 4-acetoxystyrene (AS)
Chao Lv (335727)   +17 more
core   +1 more source

Achieving Less Than 100 ppb Total Metal Ion Concentration in ESCAP Resins Synthesized by Atom Transfer Radical Polymerization

open access: yesMacromolecular Materials and Engineering, Volume 309, Issue 4, April 2024.
The environmentally stable chemical amplified photoresist resin is synthesized via atom transfer radical polymerization achieving polydispersity index as low as 1.25. It is then purified by ion exchange with two different resins, IRC747 and A15, which are effective at removing Cu and other metal ions.
Yingchao Liu, Jinshan Wang, Weimin Li
wiley   +1 more source

PECVD and PEALD on polymer substrates (part II): Understanding and tuning of barrier and membrane properties of thin films

open access: yesPlasma Processes and Polymers, Volume 21, Issue 3, March 2024.
Recent results on the analysis of plasma/polymer interactions and the nucleation of ultrathin plasma films by plasma‐enhanced chemical vapor deposition and plasma‐enhanced atomic layer deposition on polymeric substrates are shown. The adjustment of deposition parameters and substrate selection leads to either effective diffusion barriers or films with ...
Teresa de los Arcos   +21 more
wiley   +1 more source

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