Results 81 to 90 of about 294,621 (346)
Palladium-Catalyzed Enantioselective Alkylative Ring Opening
Palladium-Catalyzed Enantioselective Alkylative Ring ...
Mark Lautens (1391935) +2 more
core +1 more source
Single‐cell multi‐omics reveals epigenetic heterogeneity across therapy‐adaptive tumor states, including quiescent/dormant, drug‐tolerant persister, and EMT‐like phenotypes. By linking regulatory features with state‐associated biomarkers, these approaches inform biomarker‐guided therapeutic strategies for evolving tumors.
Hee Jung Kim +3 more
wiley +1 more source
Palladium-Catalyzed Esterification of Carboxylic Acids with Aryl Iodides
The first palladium-catalyzed esterification of carboxylic acids with aryl iodides is described. A palladium-based catalytic system consisting of IBnF (1,3-bis((pentafluorophenyl)methyl)imidazole-2-ylidene) ligand was found to significantly accelerate
Hiroyuki Kitano (5058149) +2 more
core +1 more source
Unique biological samples, such as site‐specific mutant proteins, are available only in limited quantities. Here, we present a polarization‐resolved transient infrared spectroscopy setup with referencing to improve signal‐to‐noise tailored towards tracing small signals. We provide an overview of characterizing the excitation conditions for polarization‐
Clark Zahn, Karsten Heyne
wiley +1 more source
Palladium-Catalyzed α-Arylation of Ketones
Palladium-Catalyzed α-Arylation of ...
Michael Palucki (2265832) +1 more
core +1 more source
Enzymes of the 2‐hydroxyacyl‐CoA lyase group catalyze the condensation of formyl‐CoA with aldehydes or ketones. Thus, by structural adaptation of active sites, practically any pharmaceutically and industrially important 2‐hydroxyacid could be biotechnologically synthesized. Combining crystal structure analysis, active site mutations and kinetic assays,
Michael Zahn +4 more
wiley +1 more source
Palladium-Catalyzed Asymmetric Allylic Fluoroalkylation/Trifluoromethylation
The first palladium-catalyzed asymmetric allylic trifluoromethylation is disclosed. The methodology evokes a fundamental principle by which the synergistic interplay of a leaving group and its subsequent activation of the nucleophilic trifluoromethyl ...
Barry M. Trost (1309395) +2 more
core +2 more sources
Preparation and Property of Palladium/Alumina Composite
Palladium is often used as the preferred material for hydrogen isotope separation, but pure palladium tends to be pulverized due to internal stress after repeated hydrogen absorption and desorption cycles.
LONG Peihong;BAI Tianju;XIONG Liangyin;CHEN Demin;CHEN Wei
doaj
Composite palladium membranes with improved durability toward hydrogen embrittlement
Palladium membranes have advantages of high hydrogen flux and exclusive permselectivity for hydrogen due to the unique permeation mechanism. Pure palladium membranes are often damaged by hydrogen embrittlement which causes a fatal fracture of membrane ...
Suzuki, Toshishige M. +1 more
core
Palladium-Catalyzed Tandem Isomerization/Hydrothiolation of Allylarenes
Herein we report a tandem olefin migration/hydrothiolation of allyl benzenes facilitated by an in situ generated palladium hydride. A catalyst system composed of palladium acetate and bidentate ligand dtbpx (1,2-bis(di-tert-butylphosphinomethyl ...
Prasad M. Kathe (6457784) +1 more
core +1 more source

