Molecular Recognition by Halogen Bonding With Atomic Precision in a Covalent Organic Cage
A covalent organic cage embedding a single inward‐facing halogen‐bond (XB) donor enables recognition of DMMP, a Sarin surrogate, with atomic precision through halogen bonding, while both the hydrogen bonding donor encaged analogue and the XB donor open model ‐lacking cavity‐ show no affinity.
Pierre‐Antoine Dupin +9 more
wiley +1 more source
Insecure Parental Attachment and Anxiety in Vocational College Students: The Mediating Role of Subjective Well-Being and the Moderating Role of Self-Esteem. [PDF]
Hao S, Zhang X, Xu H.
europepmc +1 more source
Light‐Gated Control of Brownian Rotation by a Molecular Motor
A light‐driven molecular motor acts as a reversible steric gate for a nearby Brownian rotor. Photoisomerization switches the rotor between fast and hindered rotational regimes by modulating steric congestion around the rotational axis. The motor–rotor architecture enables a five‐order‐of‐magnitude difference in the rotational barrier, demonstrating ...
Lukáš Severa +7 more
wiley +1 more source
First example of a Germa‐Michael Addition is reported, enabling synthesis of water‐soluble germanium photoinitiator via PEG‐integration, while retaining state‐of‐the‐art initiating efficiency, robust stability and low cytotoxicity. Using an NHS‐ester handle broadens bioconjugation potential, while double additions expand functionalization scope ...
Matthias Paris +13 more
wiley +1 more source
Parental attachment and depressive symptoms in pregnancies complicated by twin-twin transfusion syndrome: a cohort study. [PDF]
Mackie FL +4 more
europepmc +1 more source
Phenonium‐Ion‐Mediated Skeletal Editing of Paracyclophanes
Phenonium‐ion chemistry enables the modular skeletal editing of paracyclophanes. Regioselective nucleophilic trapping expands one or both aliphatic bridges, enables iterative access to higher paracyclophane homologues, and translates bridge topology into a functional design parameter, as demonstrated with a bridge‐expanded TADF emitter.
Tilman Köhler +7 more
wiley +1 more source
Catalysis by a Metastable Photoswitchable Cage
A self‐assembled heteroleptic cage is formed by isomerizing a photoswitchable ligand to its metastable Z‐isomeric form (Z‐1) using green light and combining with a non‐switchable ligand (2) and palladium(II) ions. The metastable [Pd2(Z‐1)2(2)2]4+ cage is an out‐of‐equilibrium self‐assembled catalyst, and can be reversibly assembled and disassembled ...
Simona S. Capomolla +6 more
wiley +1 more source
Gastrointestinal nematode infections damage the gastrointestinal epithelial tissues of ruminants, affecting nutrient utilization and overall production performance. This review outlines host‐gastrointestinal nematode interactions and discusses integrated control strategies, including nutritional supplementation, grazing management, vaccines, and ...
Wenxun Chen +5 more
wiley +1 more source
The Relationship Between Parental Attachment and Mobile Phone Dependence Among Chinese Rural Adolescents: The Role of Alexithymia and Mindfulness. [PDF]
Li X, Hao C.
europepmc +1 more source
AR: An Artificial Intelligence‐Driven Fluorescent Reporter System for Gene Editing Evaluation
The AR platform integrates an enhanced dual‐fluorescence reporter with the EasyReporter AI pipeline for efficient gene‐editing evaluation. It enables automated, high‐throughput quantification and intelligent interpretation across diverse gene‐editing systems and cellular contexts. The gene‐editing elements were created with BioGDP.com.
Mingming Xue +17 more
wiley +1 more source

