Results 51 to 60 of about 507 (132)
Synthesis of spiroketal and 3-ketotetrahydrofuran motifs from natural products using singlet oxygen [PDF]
The synthesis of the [6,6,5]-bispiroketal skeleton of the natural product salinomycin is described in this thesis. A cascade sequence initiated by a [4+2]-cycloaddition of singlet oxygen (1O2) to a furylic ketone followed by two sequential cyclizations ...
Τοφή, Μαρία, Tofi, Maria
core +2 more sources
Abstract Objective The dinoflagellate Alexandrium monilatum forms blooms during summer in tributaries of the lower Chesapeake Bay. Questions persist about the potential for A. monilatum to negatively affect aquatic organisms. Its main toxin, goniodomin A (GDA), a polyketide macrolide, has been shown to have adverse effects on animals, for example ...
Sylvain Gaillard +7 more
wiley +1 more source
Field monitoring of copepodamides using a new application for solid phase adsorption toxin tracking
Abstract Chemical signaling is ubiquitous in the marine environment. Plankton rely on chemical signals to find mates, hunt prey, and respond to threats, and these small‐scale interactions can propagate into community‐wide cascades and large‐scale ecological changes. The chemical signaling exchange in the open ocean is poorly understood, and fundamental
Aubrey Trapp +3 more
wiley +1 more source
Abstract Dinophysis is an obligate mixotroph that relies on consumption of the ciliate, Mesodinium rubrum, to grow and form harmful algal blooms (HABs). In this study, blooms of Dinophysis acuminata in two NY, USA, estuaries were studied over the course of 3 yr (2019–2021) using discrete samples and an Imaging FlowCytobot (IFCB) to capture images of ...
Megan Ladds +2 more
wiley +1 more source
Scientific opinion on marine biotoxins in shellfish in the Republic of Croatia
Summary Marine biotoxins are thermostable, mostly non‐protein molecules with different chemical components. According to solubility, they are divided into water‐soluble (hydrophilic) and fat‐soluble (lipophilic). The regulations of the EU and the Republic of Croatia regarding the maximum limits (ML) in live shellfish cover several groups: azaspiracids (
Brigita Hengl +7 more
wiley +1 more source
Pectenotoxins - an issue for public health - A review of their comparative toxicology and metabolism
Pectenotoxins (PTXs) are a group of toxins associated with diarrhetic shellfish poisoning (DSP) and isolated from DSP toxin-producing dinoflagellate algae.
Shaw, G +5 more
core +1 more source
Synthesis of the ABC spiroketal motif of pectenotoxins 2c,8 ,9 and 11c. [PDF]
Στην παρούσα εργασία παρουσιάζεται η σύνθεση του ABC [6,6]-σπειροκεταλικού σκελετού των φυσικών προϊόντων Pectenotoxins 2c, 8, 9, και 11c. Στάδιο κλειδί είναι μια διπλή [4+2] κυκλοπροσθήκη μεταξύ του διεγερμένου οξυγόνου απλής κατάστασης (1O2) και ...
Αλεξοπούλου, Ιωάννα Αχιλλέα +1 more
core
Enzymatic hydrolysis of the esterfied diarrhetic shellfish poisoning toxins and pectenotoxins
Okadaic acid (OA) and dinophysistoxins-1 and -2 (DTX1, DTX2), the toxins responsible for incidents of diarrhetic shellfish poisoning (DSP), can occur as complex mixtures of ester derivatives in both plankton and shellfish.
Quilliam, Michael A. +2 more
core +1 more source
Access to Both Anomers of Pectenotoxin Spiroketals by Kinetic Spiroketalization
A concise synthesis of both AB ring spiroisomers of the pectenotoxins is described. The nonanomeric AB spiroketal ring system of the pectenotoxins-1, -2, -3, and -6 is formed under very mild, kinetic spiroketalization conditions, along with the anomeric ...
Jatta E. Aho (2416474) +1 more
core +1 more source
Kleptoplastic mixotrophic species of the genus Dinophysis are cultured by feeding with the ciliate Mesodinium rubrum, itself a kleptoplastic mixotroph, that in turn feeds on cryptophytes of the Teleaulax/Plagioselmis/Geminigera (TPG) clade.
Jorge Hernández-Urcera +7 more
doaj +1 more source

